溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

水声学方法对黄河口水下底坡失稳现象研究

对黄河三角洲东北部地区的高分辨率水声学资料进行了综合研究。根据所记录的破坏土体变形程度、运动产生的平面形状和地貌特征形态,对土体失稳过程进行分类：浅表土体变形、塌陷凹坑、滑坡和沉积物重力流。结果表明：（１）浅表土体形变的变形程度最低,出现在研究区斜坡上部平滑海底,主要为绳网状泄水构造和表层拉张裂隙。（２）塌陷凹坑在研究区内广泛出现,是局部土体液化后发生了垂直沉降的结果。（３）滑坡多发生在水下斜坡的中上部,由弧形塌陷区、狭窄的冲沟通道和负地形沉积物堆积区组成。滑坡陡坎后缘发现拉张裂隙。（４）沉积物重力流是土体发生变形程度最大,搬运距离最长的土体破坏变形形式。局部区域多次受到沉积物重力流切割和充填作用。     

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.     

细菌反硝化法测试硝酸盐氮、氧同位素的研究与应用

为了验证细菌反硝化法对水体中硝酸盐氮、氧同位素组成测定的适用性、重现性及准确性, 在不同时间(2019年7月28日、8月19日、8月26日)利用反硝化细菌分别将海水、湖水和自来水样品中的硝酸盐转化为氧化亚氮（N₂O）, 并进行氮、氧同位素测定。结果表明, 不同时间段3个批次实验的硝酸盐氮同位素校准曲线斜率都接近理论值1, 相关性系数均高于0.999, 说明反硝化细菌在将样品中的硝酸盐全部还原为N₂O的过程中氮同位素分馏效应很小; 同一样品3个批次测定的硝酸盐的氮同位素值基本相同, 表明细菌反硝化法对硝酸盐氮同位素的测定在长时间周期内具有很好的重现性和准确性。3个批次氧同位素校准曲线斜率稳定在0.61～0.63之间, 相关性系数均高于0.99, 单批次内海水、湖水和自来水3类样品中硝酸盐氧同位素比值的标准偏差范围在0.18‰～0.69‰之间, 表明经过氧同位素校准曲线的校正, 可以准确反映样品中硝酸盐氧同位素组成; 同一样品3个批次测定的氧同位素值差异较大, 其变化范围为1.33‰～16.38‰, 可能是由于样品储存过程中硝酸盐与水之间发生的氧同位素交换作用所致。     

黄精复方治疗气阴两虚型2型糖尿病32例临床观察

目的：探讨黄精复方治疗气阴两虚型2型糖尿病的临床疗效。方法：将气阴两虚型2型糖尿病患者64 例随机分为治疗组和对照组,每组各32 例。所有患者均采取饮食、运动等生活方式干预,对照组口服二甲双胍片治疗,治疗组在对照组基础上加用黄精复方治疗,疗程均为12周。观察2组综合疗效及治疗前后中医证候积分、体质量指数（BMI）、空腹血糖（FBG）、餐后2 h血糖（2hPG）、糖化血红蛋白（HbA1c）、空腹胰岛素（FINS）、胰岛素抵抗指数（HOMA-IR）、总胆固醇（TC）、三酰甘油（TG）、高密度脂蛋白胆固醇（HDL-C）、低密度脂蛋白胆固醇（LDL-C）的变化,记录2组不良反应。结果：总有效率治疗组为87.50%（28/32）,高于对照组的59.37%（19/32）,差异有统计学意义（P＜0.05）。2组中医证候积分、BMI、FBG、2hPG、HbA1c、FINS、HOMA-IR、TC、TG、LDL-C、HDL-C治疗前后组内比较及治疗后组间比较,差异均有统计学意义（均P＜0.05）。结论：黄精复方治疗气阴两虚型2型糖尿病可以缓解患者的中医证候,降低血糖、血脂,改善胰岛功能,从而提高临床疗效。     

海水循环水系统中环境因子对大西洋鲑体内土腥味物质含量的影响

为获知不同时期封闭式海水循环水养殖系统中水质因子、浮游植物和细菌群落结构对大西洋鲑(Salmo salar)体内土腥味物质含量变化的影响,于2018—2019年4次采集封闭式海水循环水养殖系统的水样和大西洋鲑。测定水体的氨氮、亚硝氮、硝氮、活性磷酸盐等指标,分析水体浮游植物群落结构并通过16S高通量测序测定水体中细菌群落结构,通过微波蒸馏-固相微萃取-气相色谱-质谱联用(MD-SPME-GC-MS)方法,分析大西洋鲑背肌中土臭素(Geosmin,GSM)和二甲基异冰片(2-methylisoborneol,MIB)的含量。研究发现:测定水质指标中温度、溶解氧、盐度、pH、氨氮、亚硝氮、硝氮、活性磷酸盐、总氮、总磷、总悬浮物和溶解性总有机碳在不同时期差异显著。共鉴定出浮游植物7门、13目、26属,蓝藻门(Cyanophyta)、硅藻门(Bacillariophyta)和绿藻门(Chlorophyta)为优势门;不同时期细菌群落中的优势菌门均为变形菌门(Proteobacteria)和拟杆菌门(Bacteroidetes),但细菌群落结构存在差异,这主要是由水质差异引起的。在不同时期,鱼体MIB含量均高于GSM含量,MIB为鱼体中主要的土腥味物质,在7和10月MIB含量较高。鱼体土腥味物质含量受浮游植物和细菌群落影响,而水质因子可能通过影响浮游植物和细菌群落的结构,来影响养殖鱼体内土腥味物质的含量。     

A two-dimensional morphological model based on next generation circulation solver II: Application to Caofeidian, Bohai Bay, China

This paper is a companion of a two-part papers on the development of a two-dimensional morphological model—CurWaC2D-Sed, based on next generation circulation solver. In this paper, the model developed in paper I is applied to the large-scale construction of near-harbor industrial zone with deep water harbor by reclamation in Caofeidian, Bohai Bay, which is a typical sandbar-lagoon bay-type tidal inlet system. Characteristics of tides, currents, waves and sediments in Caofeidian are firstly analyzed with field data from comprehensive field observations carried out in 2008. These data are then used for model calibration and validation, showing a good agreement between simulated results and field measurements for tides, currents and suspended sediments. The verified model is applied to study the effects of the construction of Caofeidian embankment and the on-going engineering scheme on hydrodynamics and sediment transports as compared with no constructions under three representative tide conditions and their combinations with normal and strong waves as well as on morphology evolution. The simulated results indicate that the present scheme leads to morphological changes in Caofeidian with acceptable rates of erosion and sedimentation. However, some attentions should be paid to erosion at offshore wharf in front of Caofedian foreland which may lead to potentially increasing landslide risks due to steep slope and sedimentation in Laogonggou creek.     

基于新型高频声学多普勒流速剖面仪的河口近底部边界层观测初探

河口物质输运、能量交换与底边界层内的水动力过程密切相关,底边界层参数(如切应力、拖曳系数)的确定至关重要。挪威Nortek公司生产的新型声学多普勒流速剖面仪AD2CP相比传统ADCP具有高频、低噪的优点,可用于高频(16Hz)流速剖面观测,而被广泛应用于底边界层观测的ADV只能测量单点高频流速。本文采用AD2CP在长江口南槽最大浑浊带区域进行座底式观测,并与同步近底部三脚架上ADV的观测结果进行对比。结果表明,使用AD2CP测得的近底部平均流速与ADV的测量结果吻合良好;使用惯性耗散法计算了底切应力,基于ADV的单点高频流速数据计算结果为2.16×10~(-2)～5.69×10~(-1)N/m~2,基于AD2CP的结果为2.09×10~(-2)～4.26×10~(-1)N/m~2,二者范围大致相当。在此基础上,基于AD2CP数据计算出摩阻流速为4.55×10~(-3)～2.06×10~(-2)m/s、底拖曳系数范围为1.84×10~(-4)～2.49×10~(-3),与ADV的计算结果基本一致。此外,由于AD2CP可以获得高频的流速剖面数据,优于单点ADV,具备观测近底部边界层参数和边界层内湍流剖面的潜力。     

Properties of geogrid-reinforced marine slope due to the groundwater level changes

Evaluation of slope stability, especially in the absence of a proper bed such as marine soils, is one of the most important issues in geotechnical engineering. Using geogrid layers to enhance the strength and stability of embankments is regarded as a commendable stabilization method. On the other hand, groundwater level erratically fluctuates in coastal areas. Therefore, the aim of this research is to study the effects of groundwater level changes on stability of a geogrid-reinforced slope on loose marine soils in Qeshm Island, Iran. At first, geotechnical properties of the site were obtained by comprehensive series of geotechnical laboratory and in situ tests. Then, by simultaneous changes of groundwater level and several parameters such as embankment slope, loading, geogrid length, geogrid number, and tensile strength of geogrid, different characteristics such as embankment safety factor (SF), vertical and horizontal displacements at embankment top and embankment base were studied. It was observed that groundwater level had significant effects on behavior of the embankment. For most of the observations, by decreasing the groundwater level, the displacements decreased and consequently safety factor increased. Increasing the length, number, and tensile strength of geogrid led to the reduction of displacements and an increase in the safety factor.     

可见光下Li+/CNTS-TiO2光催化剂降解海洋柴油污染的研究

通过溶胶-凝胶法,以CNTS-TiO₂为前驱物制备了Li⁺掺杂CNTS-TiO₂的纳米复合光催化剂(以下均称为Li⁺/CNTS-TiO₂),采用X射线衍射(XRD)、扫描电镜(SEM)等测试手段对光催化剂进行表征,结果表明制得的催化剂为纳米材料且在TiO₂的基础上增大了比表面积。利用掺杂量为3%的Li⁺掺杂CNTS-TiO₂复合光催化剂(以下均称为3%Li⁺/CNTS-TiO₂)光催化降解海洋柴油污染,在可见光条件下考察了Li⁺掺杂量、煅烧温度、光催化剂投加量、柴油初始质量浓度、光催化反应时间、H₂O₂质量浓度等条件对光催化实验的影响。进行正交实验,确定最优化工艺条件为:Li⁺掺杂量为3%,光催化剂的煅烧温度为600 ℃,3%Li⁺/CNTS-TiO₂的投加量为0.1 g/L,降解柴油初始质量浓度为0.4 g/L,光催化反应时间为3 h,H₂O₂质量浓度为0.6 g/L,降解率可以达到95%以上。同时对此光催化剂进行应用试验,试验结果表明光催化剂去除效果优异,去除率可达91.87%。