The Solubility of Sulphur in Hydrous Rhyolitic Melts

Experiments performed at 2 kbar, in the temperature range 800–1000°C,with fO₂ between NNO–2·3 and NNO+2·9 (whereNNO is the nickel–nickel oxide buffer), and varying amountsof sulphur added to hydrous metaluminous rhyolite bulk compositions,were used to constrain the solubility of sulphur in rhyolitemelts. The results show that fS₂ exerts a dominant control onthe sulphur solubility in hydrous silicate melts and that, dependingon fO₂, a rhyolitic melt can reach sulphur contents close to1000 ppm at high fS₂. At fO₂ below NNO+1, the addition of ironto a sulphur-bearing rhyolite magma produces massive crystallizationof pyrrhotite and does not enhance the sulphur solubility ofthe melt. For a given fO₂, the melt-sulphur-content increaseswith fS₂. For fixed fO₂ and fS₂, temperature exerts a positivecontrol on sulphur solubilities, at least for fO₂ below NNO+1.The mole fraction of dissolved sulphur exhibits essentiallylinear dependence on fH₂S at low fO₂ and, although the experimentalevidence is less clear, on fSO₂ at high fO₂. The minimum insulphur solubility corresponds to the redox range where bothfH₂S and fSO₂ are approximately equal. A thermodynamic modelof sulphur solubility in hydrous rhyolite melts is derived assumingthat total dissolved sulphur results from the additive effectsof H₂S and SO₂ dissolution reactions. The model reproduces wellthe minimum of sulphur solubility at around NNO+1, in additionto the variation of the sulphide to sulphate ratio with fO₂.A simple empirical model of sulphur solubility in rhyoliticmelts is derived, and shows good correspondence between modeland observations for high-silica rhyolites. KEY WORDS: sulphur; solubility; rhyolite; thermodynamics; fO₂; fS₂     

内蒙古温带半干旱羊草草原N2O通量及其影响因素

利用静态箱 -气相色谱法于 2 0 0 1～ 2 0 0 3年对内蒙古锡林河流域羊草草原进行了连续 2年的野外定位试验 ,获得羊草草原原状群落与土壤N2 O年排放通量分别在 3 91～ 4 71μgm- 2h- 1以及 5 5 0～ 10 0 3μgm- 2 h- 1范围内变动 ,证明内蒙古温带半干旱羊草草原生态系统是大气中N2 O的源 ;系统分析了羊草草原N2 O通量的季节变化、源汇特征以及关键的环境因子对草地N2 O通量的影响等 ,建立了N2 O通量与环境因子间的回归方程 ;并利用两年连续完整的观测数据对羊草草原N2 O年排放量进行了估算     

Comparative study on CO_2 emissions from different types of alpine meadows during grass exuberance period

1IntroductionTherisingatmosphericgreenhousegaseswerebelievedtobetheprimarycauseofglobalclimatechange(Tettetal.,1999;Crowley,2000).Amongthegreenhousegases,theconcentrationofatmosphericcarbondioxidehasincreasedfrom280ppmsincepre-industrialtimestocurrent355ppm,whichaccountedfor50%ofthetotalgreenhouseeffect(Nefteletal.,1985;Friedlietal.,1986;Rodhe,1990;Fanetal.,1998).ElevatedCO2hasamarkedeffectonterrestrialecosystemprocesses(Melilloetal.,1996).TheQinghai-TibetPlateau,thelargestgeomorphologica…     

基于J2EE的分布式WebGIS研究

在对比分析传统的WebGIS各种实现模式优缺点的基础上，探讨了利用企业级J2EE技术实现分布式WebGIS的解决方案，使WebGIS更好地满足企业级应用的需要。     

MODIS 1B影像几何纠正方法研究及软件实现

MODIS影像是一种新型和重要的数据。对MODIS 1B影像几何畸变原因进行了深入分析，选择了一种合适的纠正方法。对于1km分辨率MODIS 1B影像，直接采用1km分辨率的空间坐标进行几何纠正；对于250m和500m分辨率的MODIS 1B影像，先用三次样条曲线对坐标进行插值生成同分辨率的坐标，然后利用坐标插值结果对其进行几何纠正。由于MODIS影像在空问分布上的特殊性，采用前向和后向映射相结合的方式确定纠正后某一像素点在原始影像中的位置。根据该位置的条带重叠度，可以确定参与计算像素个数、搜索窗口的大小以及窗口的精确位置；采用归一化反距离加权插值法计算纠正后像素点的属性值。上述优化算法不仅保证了纠正后影像的质量，而且提高了数据处理速度。作者在Visual C 6．0环境下开发实现了上述算法。从坐标插值和几何纠正结果分析，无论是数据处理速度还是纠正后的影像质量和精度均达到要求。     

基于二维直接线性变换的数字相机畸变模型的建立

提出并论证了基于二维直接线性变换的畸变的校正方法。本方法特别适用于各类固态摄像机(CCD、CID、PSD)的畸变模型的建立，以补偿各类像点系统误差。     

小波分析方法在提取井水位潮汐因子震前变化特征的初步应用

运用小波分析方法对1990年常熟、1995年苍山和1996年南黄海三个中强地震前江苏地区井水位固体潮的变化特征进行了研究，发现井水位M2波潮汐因子在地震前几个月几乎都出现一个幅度较大、周期为半月或一个月左右的异常信号，表明小波分析方法在处理和分析井水位潮汐资料方面可能是一种有效的方法。     

Inversions for MT data in 2D symmetrical anisotropic media

Introduction Ready and Renkin (1971) were the first to make the research on anisotropy problems in magnetotellurics (MT). The progress in the research is not evident because it is more complex and difficult than isotropic problems. Now, the one-dimensional (1D) anisotropy problems in MT have been well solved, while for the two-dimensional (2D) cases, the numerical solutions have only been obtained for some particular conditions (Ready and Renkin, 1975). As to the three-dimensional (3D) ani…     

Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).