光催化氧化法处理难降解废水的研究进展

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。     

陕北新庄地区延长组长2油层组储层特征

一般河道砂体的正粒序性决定了其下部物性条件优于上部，但新庄地区长2油层组河道砂体的物性特征截然相反，而是中上部物性条件好，下部物性条件普遍差。在储层岩石学特征、孔隙类型等研究的基础上，对此进行了探讨，认为造成其特殊性的原因主要是由于压实、胶结、次生加大等作用。指出河道边滩砂体中上部储层为该区的主力储层。     

利用高铁钾长石粉合成13X沸石分子筛的实验研究

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。     

PowerBuilder 8.0中C/S模式应用过渡到B/S模式应用的实现技术

简要分析了PowerBuilder 8．0中各种B/S解决方案的优劣，探讨了适用于已有C／S模式应用过渡到B／S模式应用的实现方法，以及利用ASP技术实现对不同类型的客户测览器隐藏底层实现方法的技术，并给出了C／S模式应用过渡到B／S模式应用的一个实例。     

A comparison of the evolution of diamondiferous quartz-rich rocks from the Saxonian Erzgebirge and the Kokchetav Massif: are so-called diamondiferous gneisses magmatic rocks?

The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.     

深圳市东湖矿泉水形成机理探讨

深圳市东湖矿泉水是自然界十分稀少的锶—锌—偏硅酸碳酸复合型矿泉水，通过对矿泉水赋存地的地质与水文地质条件的分析，并结合其水文地球化学特征，认为东湖矿泉水形成的主要控制性因素是构造作用和变质作用；在特定的水文地质条件下，深部碳酸盐类岩石受热硅化变质而产生大量CO2气体，使得各种化学元素在含有大量CO2的地下水的溶滤作用下不断迁移和富集而形成该区地下水中良好的元素组合。在其特征成分中，偏硅酸来自裂隙渗透水的溶滤和岩浆期后热液水的作用，微量元素锶主要来源于钾长石、钙长石，锌则主要来自岩浆活动以及岩脉中的黑云母、角闪石、辉石等铁镁硅酸盐矿物；并认为目前矿泉水含水层仍处于良好的地质环境保护下。     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).     

Photochemistry of N2O4 Adsorbed on Ice Surfaces at 193 nm

A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO₂ was adsorbed as N₂O₄ approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO₂, NO, O₂ and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO₂, NO and O₂ were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO₂ was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N₂O₄. NO was supposed to be a predissociation product from the electronically excited NO₂ prepared through the photodissociation of N₂O₄.     

二维波动方程约束反演的大范围收敛广义脉冲谱方法

针对二维波动方程，将大范围收敛的同伦 方法引入算子参数识别反演的过程，并结合求解不适定问题的Tikhonov正则化方法，设计了二维波动方程反演的大范围收敛广义脉冲谱方法，并利用测井资料进行了约束反演. 大量 的数值模拟结果以及抗噪实验均表明了方法的有效性.