Non-equilibrium interphase heat and mass transfer during two-phase flow in porous media—Theoretical considerations and modeling

Mass and heat transfer occurring across phase-interfaces in multi-phase flow in porous media are mostly approximated using equilibrium relationships or empirical kinetic models. However, when the characteristic time of flow is smaller than that of mass or heat transfer, non-equilibrium situations may arise. Commonly, empirical approaches are used in such cases. There are only few works in the literature that use physically-based models for these transfer terms. In fact, one would expect physical approaches to modeling kinetic interphase mass and heat transfer to contain the interfacial area between the phases as a variable. Recently, a two-phase flow and solute transport model was developed that included interfacial area as a state variable [36]. In that model, interphase mass transfer was modeled as a kinetic process.     

Geochemical changes across the Ordovician-Silurian transition on the Yangtze Platform,South China

The trace element and rare earth element (REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform: the Nanbazi section, Guizhou Province, deposited in a shallow platform interior setting, and the Wangjiawan section, Hubei Province, deposited in a deeper basinal environment. Geochemical analysis of closely spaced samples through three intervals, the Wufeng, Guanyinqiao and Longmaxi, revealed vast palaeoceanographic changes. Some geochemical proxies, including Th/U, Ni/Co, V/Cr, and V/(V+Ni) ratios, together with sedimentary facies and biotic data, indicate that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals, but an oxic condition during the Guanyinqiao time. The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a global sea-level lowstand, in parallel with the global glaciation. The Longmaxian anoxic environment was a result of a global sea-level rise, which may be synchronized with a mainly catastrophic event in the latest Ordovician. Although the two sections generally show similar variation patterns of trace and REE concentrations and some element ratios, a minor difference occurs between the Wangjiawan and Nanbazi sections, likely reflecting a difference in depositional setting during the accumulation. Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of the latest Ordovician mass extinction. Supported by National Basic Research Program of China (Grant No. 2005CB422101)     

Quantitative assessment of gas washing of oils in the Tazhong area of the Tarim Basin,Northwest China

Gas washing has been known in the Tazhong area of the Tarim Basin, but its quantitative assessment has not yet been reported. Here the influence of gas washing fractionation in the area was discussed based on the gas chromatogram data of 68 oils and the results of the mixing experiments of a black oil and a condensate. The results show that the intensity of gas washing fractionation decreased generally from northern to southern part and vertically from deep reservoirs to shallow reservoirs. The gas washing fractionation was mainly controlled by fault systems in this area, with the increase of n-alkane mass depletion positively correlated to the number and scale of faults. Gas washing fractionation appears to have affected the hydrocarbon property, and as a result the diversity of the crude oils is markedly controlled by gas washing. In addition, the occurrence of waxy oil in this area may be resulted from multiple factors including gas washing, mixed filling and migration fractionation. Supported by National Basic Research Program of China (Grant No. 2006CB202303) and the National Natural Science Foundation of China (Grant No. 40672091)     

关于结构振型参与系数和振型贡献的分析

采用振型分解反应谱法求解多自由度弹性体系的地震反应时,为了在满足所需计算精度的前提下减少工作量,需要对振型数量进行合理的选择,而振型数的确定主要取决于结构各阶振型对总体反应的贡献。通过数学推导,对振型贡献及振型数量的选择问题进行了研究。首先,讨论了振型参与系数的性质,在此基础上给出了能够反映结构振型贡献参数的数学表达式,对这些参数的力学含义进行了解释,并给出了相关证明;其次,对有效质量法、振型位移控制法等基于不同振型贡献标准的确定振型数的方法进行了分析比较,指出了其合理性和不足。本文研究对进一步理解结构振型贡献和振型数的选择问题具有一定的理论意义。     

高精度测量岩石样品Ce同位素组成的TIMS方法

介绍了对岩石样品的Ce同位素组成进行高精度测量的TIMS方法.采用α-羟基异丁酸(α-HIBA) 离子交换法分离和纯化岩石样品中的La、Ce元素, Ce同位素组成和La、Ce含量测定在Triton热电离质谱仪上完成.质谱标样JMC304的138Ce/142Ce比值统计值为0.0225762±0.0000015, 与大部分文献值一致.应用该方法对USGS玄武岩标样BCR-2和峨眉山玄武岩EQB的138Ce/142Ce比值和La、Ce含量进行了分析, 其结果分别为: 0.0225572±0.0000010、25.2±0.3μg/g、55.8±0.9μg/g和0.0225755±0.0000003、54.2±0.4μg/g、117.4±1.3μg/g.BCR-2的La、Ce含量测定结果与其证书值在误差范围内一致, 其分析精度为0.001%~0.005%.所有样品的140Ce/142Ce比值测定结果统计值为7.9439±0.0002, 介于文献最低值7.941与最高值7.947之间, 可能代表了该比值的最佳估计值.      

秦皇岛市空气污染与气象要素的关系

利用多因子分析和多元回归模型,对1998—2004年秦皇岛市城区空气污染物浓度逐日监测数据及气象要素进行分析,并调查污染源,得出主要污染物与气象要素的关系,建立当地空气质量预报。结果表明：上游西北地区是对秦皇岛市空气质量影响最大的污染源地;空气质量首要污染物PM10的峰值出现在4月,SO2的峰值出现在采暖季,NO2浓度全年稳定少变; SO2和PM10的浓度受风场影响较大,NO2最小;春季“南高北低”型气压场造成PM10污染指数全年最高;大于等于1 mm的降水对空气净化作用效果较小于1 mm的降水显著;春季气旋控制下,5级以上西风可形成中度以上污染,而非气旋控制下,6级以上西风才可形成中度以上污染。     

修正SMR法在红层软岩边坡中的应用

在前人大量研究的基础上,针对传统的SMR法（边坡岩体质量方法）没有考虑软弱互层对边坡岩体评价结果的影响的不足之处,增加了强度差异调整权值项。对西南地区80个红层软岩边坡的评价分析结果表明,采用岩性差异修正后的SMR法比直接使用SMR法更加符合野外实际情况,运用修正后的SMR法对红层软岩边坡评价更加合理。     

古构造应力场数值模拟及危险性预测研究

在精确确定构造序列与构造格架的基础上,探索出一套从建立构造模型、确定边界条件、选取岩体力学参数与危险性判断准则、计算古构造应力值、预测危险区与安全岛的基本思路与方法。采用有限元法,建立了矿区平面应力与三维构造模型,从加载方式和加载大小两方面模拟历史时期作用于成庄煤矿上的古构造应力。根据地表岩体和深部煤层中的节理,计算其内摩擦角和岩体抵抗变形破坏的能力,获得了古构造应力作用下地表表层、3#煤层的临界区、危险区与安全区。结合研究区节理、断层、褶皱、陷落柱等构造形迹特征,对危险性分区进行综合预测。预测结果揭示,山西晋城成庄煤矿区存在先南北向、后东西向的两期大的古构造运动,即先东西向加载60 MPa,再南北向加载110～180 MPa,可能的危险区分东、西两带,该结论对煤层岩体应力集中带和瓦斯突出区的预测具有重要的意义。     

节理网络分形在隧道超前地质预报中的应用

分形几何是20世纪70年代以来发展起来的研究非线性现象的理论和方法,这一理论的诞生为揭示隐藏于混乱复杂现象的精细结构和定量地描述它们提供了理论基础。将分形的方法引入到隧道的超前地质预报,通过岩体结构面网络的分维值来预测岩体的质量。结合工程实例可以看出,岩体结构具有良好的分形特征,其分形描述可作为评价结构岩体质量的标准之一。分形方法是评价岩体性质的一个有效的方法,具有广泛的应用前景。     

经济危机背景下对我国专业化产业区的反思——重温意大利式产业区的价值

在该文中,产业区是指从事同一生产过程不同阶段的生产和服务活动的专业化的中小企业组成特色的地方系统.在过去的10年中,我国专业化产业区和意大利式产业区的相似性已经被广泛关注.但是,我国的大量产业区因其非创新性的大批量制造而难以走出"低端道路"的困局,遭受经济危机的冲击.该文重温了意大利产业区模式.以新的视角探讨其核心价值,指出产业社区的文化根基以及持续创新的工业设计是其发展的动力源泉.在危机影响下变化的市场环境中,将大规模定制的生产模式引入产业区研究,并通过对比我国产业区与意大利式产业区,提出以设计为中心、加强技术创新与服务创新的产业区发展战略.