Spatio‐temporal variability of the isotopic input signal in a partly forested catchment: Implications for hydrograph separation

The isotopic composition of precipitation (D and ¹⁸O) has been widely used as an input signal in water tracer studies. Whereas much recent effort has been put into developing methodologies to improve our understanding and modelling of hydrological processes (e.g., transit‐time distributions or young water fractions), less attention has been paid to the spatio‐temporal variability of the isotopic composition of precipitation, used as input signal in these studies. Here, we investigated the uncertainty in isotope‐based hydrograph separation due to the spatio‐temporal variability of the isotopic composition of precipitation. The study was carried out in a Mediterranean headwater catchment (0.56 km²). Rainfall and throughfall samples were collected at three locations across this relatively small catchment, and stream water samples were collected at the outlet. Results showed that throughout an event, the spatial variability of the input signal had a higher impact on hydrograph separation results than its temporal variability. However, differences in isotope‐based hydrograph separation determined preevent water due to the spatio‐temporal variability were different between events and ranged between 1 and 14%. Based on catchment‐scale isoscapes, the most representative sampling location could also be identified. This study confirms that even in small headwater catchments, spatio‐temporal variability can be significant. Therefore, it is important to characterize this variability and identify the best sampling strategy to reduce the uncertainty in our understanding of catchment hydrological processes.     

厚碳酸盐岩覆盖区RVSP三维地震勘探应用效果分析

该文以中国南方一厚碳酸盐岩覆盖区的RVSP三维地震勘探实例,对RVSP三维地震勘探观测系统和数据采集参数的确定、地面等效处理和波场分离等关键处理技术及地质效果进行了阐述和分析,说明了RVSP在克服表浅层复杂地质条件及环境条件对资料的影响及提高地震资料的分辨率有其特定的优势,同时也提出了RVSP三维地震在采集和处理过程中的难点。     

Assessing the ‘two water worlds’ hypothesis and water sources for native and exotic evergreen species in south‐central Chile

Recent studies using water‐stable isotopes (δ¹⁸O and δ²H) have suggested an ecohydrological separation of water flowing to streams or recharging groundwater and water used by trees, known as the ‘two water worlds’ (TWW) hypothesis. In this study, we measured water isotopic composition in precipitation [open field and throughfall, i.e. local meteoric water line (LMWL)] and the mobile water compartment (i.e. stream and soil solution), bulk soil water and xylem water over a period of 1.5 years in two headwater catchments: NF, covered with old growth native evergreen forest (Aetoxicon punctatum, Laureliopsis philippiana and Eucriphya cordifolia), and EP, covered with 4 and 16‐year‐old Eucalyptus nitens stands. Our results show that precipitation, stream and soil solution plot approximately along the LMWL, while xylem waters from all studied tree species plot below the LMWL, supporting the TWW hypothesis. However, we also found evidence of ecohydrological connectivity during the wet season, likely controlled by the amount of antecedent precipitation. These observations hold for all investigated tree species. On both sites, a different precipitation source for stream and xylem water was observed. However, in EP, bulk soil showed a similar precipitation source as xylem water from both E. nitens stands. This suggests that E. nitens may use water that is recharging the bulk soil compartment. We conclude that under a rainy temperate climate, the TWW hypothesis is temporal and does not apply during wet seasons. Copyright © 2016 John Wiley & Sons, Ltd.     

泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。     

A Loop Current experiment: Field and remote measurements

An overview of a new comprehensive observational study of the Loop Current (LC) in the eastern Gulf of Mexico that encompassed full-depth and near-bottom moorings, pressure-equipped inverted echo sounders (PIES) and remote sensing is presented. The study array was designed to encompass the LC from the Campeche Bank to the west Florida escarpment. This overview centers about principal findings as they pertain to mesoscale dynamics. Two companion papers provide in-depth analyses. Three LC anticyclonic eddy separation events were observed with good 3D spatial coverage over the 2½ year extent of the field study; the three separations exhibited similar processes after the LC had extended into the eastern Gulf. Large scale (∼300 km wavelength, 40–60 day periods) southward propagating meanders developed on the eastern side of the LC over deep (∼3000 m) water that were the result of baroclinic instability between the upper layer meandering jet and lower layer cyclones and anticyclones. The lower layer was only highly energetic during relatively short (∼2–3 months) intervals just prior to or during eddy detachments because of baroclinic instability. The steepening of the meanders lead to a pinch-off of LC eddies. The deep lower-layer eddies, constrained by the closed topography of the southeastern Gulf, propagated westward across the detachment zone and appear to assist in achieving separation. Small scale (∼50–100 km, periods ∼10 days) frontal eddies, observed on the western side of the LC along the Campeche Bank slope, decay over the deep water of the northern part of an extended LC, and have little influence on lower layer eddies, the east side meanders and the eddy detachment processes.     

基于载波相位的GPS周跳恢复方法研究

在GPS定位中,周跳的探测和修复是获得高精度定位结果的前提。针对载波相位周跳数据的探测和修复这一问题已经提出了很多方法,但都有各自的不足之处。文中针对恶劣环境下的载波相位定位问题,通过使用多个历元的数据构建方程,提出一种新的整周模糊度定义方法,并预期能够在仅有3颗可用卫星且周跳发生时实现快速、准确的定位。     

一种改进的基于 BDS 三频非差观测的周跳实时探测与修复模型

BDS三频观测条件下可以组合得到具有优良特性的虚拟载波观测量,有利于改善非差观测数据的周跳实时探测与修复。文中提出一种基于BDS三频非差数据的周跳实时探测与修复模型:首先,采用消电离层无几何HMW组合观测量探测和修复EWL周跳;然后,将经过修复的EWL观测量与WL组合消除几何相关项,忽略电离层延迟残差进而确定WL周跳;最后采用经过修复的WL观测量与NL组合形成无几何观测量,并通过优化载波相位组合确定电离层延迟的变化量以探测和计算NL周跳,并通过简单变换得到原始载波观测量的周跳值。通过实测BDS三频数据对模型可行性进行验证分析,结果表明,即使在30s的采样率以及电离层活动活跃条件下,该模型都可有效实时探测和修复各类周跳。     

Hydrogen sulfide measurements in air by passive/diffusive samplers and high-frequency analyzer: A critical comparison

In this study, hydrogen sulfide (H₂S) measurements in air carried out using (a) passive/diffusive samplers (Radiello^® traps) and (b) a high-frequency (60 s) real-time analyzer (Thermo^® 450i) were compared in order to evaluate advantages and limitations of the two techniques. Four different sites in urban environments (Florence, Italy) and two volcanic areas characterized by intense degassing of H₂S-rich fluids (Campi Flegrei and Vulcano Island, Italy) were selected for such measurements. The concentrations of H₂S generally varied over 5 orders of magnitude (from 10⁻¹–10³ μg/m³), the H₂S values measured with the Radiello^® traps (H₂S_R) being significantly higher than the average values measured by the Thermo^® 450i during the trap exposure (H₂S_Ta), especially when H₂S was <30 μg/m³. To test the reproducibility of the Radiello^® traps, 8 passive/diffusive samplers were contemporaneously deployed within an 0.2 m² area in an H₂S-contaminated site at Mt. Amiata (Tuscany, Italy), revealing that the precision of the H₂S_R values was ±49%. This large uncertainty, whose cause was not recognizable, is to be added to that related to the environmental conditions (wind speed and direction, humidity, temperature), which are known to strongly affect passive measurements. The Thermo^® 450i analyzer measurements highlighted the occurrence of short-term temporal variations of the H₂S concentrations, with peak values (up to 5732 μg/m³) potentially harmful to the human health. The Radiello^® traps were not able to detect such temporal variability due to their large exposure time. The disagreement between the H₂S_R and H₂S_Ta values poses severe concerns for the selection of an appropriate methodological approach aimed to provide an accurate measurement of this highly toxic air pollutant in compliance with the WHO air quality guidelines. Although passive samplers may offer the opportunity to carry out low-cost preliminary surveys, the use of the high-frequency H₂S analyzer is preferred when an accurate assessment of air quality is required. In fact, the latter provides precise real-time measurements for a reliable estimation of the effective exposure to hazardous H₂S concentrations, giving insights into the mechanisms regulating the dispersion of this air pollutant in relation to the meteorological parameters.     

冰盖下矩形河道的综合糙率

综合糙率是采用曼宁公式确定河道水位和流量关系的关键参数。在河道冰封期,冰盖的出现增加了流动的阻力,明流条件下确定的综合糙率不再适用,需要重新估算。基于Einstein阻力划分过流断面的原理,冰盖下矩形河道的过水断面可划分为冰盖区、河床区和边壁区。根据总流的连续性方程,在确定各分区糙率系数、水力半径和断面面积的基础上,提出了冰盖下矩形河道综合糙率的计算公式。采用已有的试验水槽测量数据和天然河道实测资料对公式进行了验证,结果表明:公式计算的综合糙率与实测值吻合较好,与Einstein公式和Sabaneev公式相比,计算精度更高;对于冰封水流,宽浅河道采用分区水深代替水力半径进行简化计算的条件有别于明渠水流,在宽深比大于20时,计算结果才满足精度要求。     

Analysis of interaction between ship bottom air cavity and boundary layer

The successful designs of hulls for ships employing drag reduction by air bottom cavitation have been based on solutions of inverse problems of the theory of ideal incompressible fluid. However, prediction of the drag reduction ratio, the air demand by ventilated cavities and the cavity impact on the hull–propeller interaction is impossible in the framework of this theory because all mentioned characteristics depend on interaction of air cavities with the ship boundary layers. Because the known CFD tools are not fitted to ventilated cavitation at low Froude numbers, an analysis of this interaction requires a novel flow model. This model includes the incompressible air flow in the ventilated cavity, the compressible flow of a water–air mixture in the boundary layer on cavities and downstream of them and the curl-free incompressible outer water flow. The provided 2D computations employing this model allows for explanations of the earlier observed effects and for prediction of the air demand by ventilated cavities. The computed velocity profiles downstream of cavities are in the accordance with the available experimental data.