线翼截断方式对大气辐射计算的影响

在大气辐射传输计算方法中,有3种基本方法,即,逐线积分方法,k-分布方法和带模式方法。其中,逐线积分方法是最精确的计算大气透过率的方法,本文根据透过率计算方式的不同,将逐线积分方法分为追线积分法和追点积分法。由于逐线积分计算需要耗费大量的计算时间,在大气遥感和大气探测业务中使用时,必须减少计算成本,提高计算速度。本文在追线积分法的基础上,给出了简化的逐线积分的基本方法,在保证同样计算精度的同时,大大提高了计算速度。对在精确的和简化的逐线积分下,不同线翼截断方式(CUTOFF)对吸收系数、大气透过率和冷却率的影响进行了更详细的探讨。通过数值试验发现,对谱线线翼的截断方式是影响辐射计算精度和计算速度的重要因子。在不同压力下,用CUTOFF=2计算的吸收系数误差最大;对CUTOFF=1,在大多数取样点上误差都小于2%;对CUTOFF=3或4,对绝大多数取样点上计算的吸收系数误差都在5%以内,但所用的计算时间却明显减少。大气低层的透过率对不同的计算方法和不同的线翼截断方式不敏感;对大气高层,无论是对精确的还是简化的逐线积分方法,当CUTOFF=2时的透过率结果与其他线翼截断方式的结果差别较大。通过比较,本文给出线翼截断的优选方案。     

聚氨酯泡塑富集硫脲解脱-石墨炉原子吸收光谱法测定地质样品中金铂

泡沫塑料常用于富集常规地质样品中的铂族元素,而富集后往往用高温灰化法解脱,此法操作繁琐,温度过高易使铂配合物分解为王水难以提取的不溶性残渣,导致测试结果不稳定、效率低;单独使用20 g/L硫脲溶液解脱,测试结果的重现性差。本文对此方法进行改进,采用50%王水封闭溶解试样,氯化亚锡还原,聚氨酯泡塑富集,20 g/L硫脲-20%盐酸溶液解脱,石墨炉原子吸收光谱法测定金和铂。在盐酸-氯化亚锡体系中,吸附温度为20℃,振荡时间为30 min时,金和铂的回收率均在95%以上,金和铂的检出限分别为0.23 ng/g和0.39 ng/g,精密度(RSD,n=10)分别为1.8%～10.3%和1.3%～13.3%。经国家一级标准物质验证,测定值和标准值基本相符。该方法泡塑解脱时无需高温灰化,用王水多次提取,在100℃沸水浴中即可一次完成,样品处理快捷。与高温灰化法相比,提取温度大为降低,分析流程简单,显著提高了单次测样量,且干扰小、空白值低,可以满足除王水难溶的铂矿种外大部分地质样品快速测定的需要。     

中国地区边界层大气气溶胶辐射吸收特性

采用粒子采样法对中国２３个地区边界层气溶胶的吸收系数作了测量,研究了其分布特征。结果表明：中国地区边界层气溶胶的吸收系数在１０＾－６－１０＾－３ｍ＾－１之间,明显呈北高南低的趋势,四川盆地和贵州有一相对较高的中心,吸收系数与粒子含量之间的相关系数为０．７４,吸收系数与粒子含量的分布一致性较好。小颗粒的吸收性能好于大颗粒。     

地震波散射研究的新进展——第25届IASPEI大会S13专题报告会“地震波散射与衰减”简介

本文以IASPEI的“地震波的散射与衰减”专题报告会为主,评述了近几年在地震波散射方面的研究进展.述评所涉及的方面有:1.关于地震尾波的起源;2.大震前尾波包络的前兆性变化;3.地震尾波包络衰降的机理;4.区分散射和吸收的新方法;5.新领域的开拓和研究.     

原子吸收分光光度计测定银的两种工作曲线拟合方式的研究

原子吸收工作曲线的两种拟合方式的研究,采用国家一级标准物质GBW07209(矿石中金和银成分分析标准物质)、GBW07255(GAg1)(银矿石中银成分分析标准物质)、GBW07256(GAg2)(银矿石中银成分分析标准物质)、GBW07305a(水系沉积物成分分析标准物质)、GBW07307a(水系沉积物成分分析标准物质)、GBW07311(水系沉积物成分分析标准物质)、GBW07405(土壤成分分析标准物质-黄红壤)进行实验,得出两种拟合方式的使用条件以及在实际工作中如何取舍的结论。     

Spatial variability of phytoplankton absorption coefficients and pigments off Baja California during November 2002

We have estimated the spatial variability of phytoplankton specific absorption coefficients (a* _ph ) in the water column of the California Current System during November 2002, taking into account the variability in pigment composition and phytoplankton community structure and size. Oligotrophic conditions (surface Chl < 0.2 mg m⁻³) dominated offshore, while mesotrophic conditions (surface Chl 0.2 to 2.0 mg m⁻³) where found inshore. The specific absorption coefficient at 440 [a* _ph (440)] ranged from 0.025–0.281 m²mg⁻¹ while at 675 nm [a* _ph (675)] it varied between 0.014 and 0.087 m²mg⁻¹. The implementation of a size index based on HPLC data showed the community structure was dominated by picoplankton. This would reduce the package effect in the variability of a* _ph (675). Normalized a _ph curves were classified in two groups according to their shape, separating all spectra with peaks between 440 and 550 nm as the second group. Most samples in the first group were from surface layers, while the second group were from the deep chlorophyll maximum or deeper. Accessory photoprotective pigments (APP) tended to decrease with depth and accessory photosynthetic pigments (APS) to increase, indicating the importance of photoprotective mechanisms in surface layers and adaptation to low light at depth. Samples with higher ratios of APP:APS (>0.4) were considered as phytoplankton adapted to high irradiances, and lower ratios (<0.26) as adapted to low irradiances. We found a good relationship between APP:APS and a* _ph (440) for the deeper layer (DCM and below), but no clear evidence of the factors causing the variability of a* _ph (440) in the upper layer.     

Investigation of water signatures at gully-exposed sites on Mars by hyperspectral image analysis

High-resolution images from the Mars Obiter Camera (MOC) onboard the Mars Global Surveyor (MGS) show a variety of gully features on sloped surfaces of Mars. The mechanism of gully formation is still under debate, although a majority of studies tend to favor a mechanism related to liquid water flow based on geomorphology and fluid mechanics considerations. In this study, we examined four known gully sites using Visible and Infrared Mineralogical Mapping Spectrometer (OMEGA) imagery. In particular, we analyzed the absorption depths of the water-associated absorption bands and concluded that there are stronger water signatures at the gully-exposed sites than in the surrounding areas. This implies that the water signatures, most likely representing water ice, isolated water molecules, and/or hydroxyl molecules incorporated into minerals, are still present in the shallow unconsolidated soils. This study provides additional evidence that water was likely involved in the formation of the gully features and is still locally active on the Martian surface in the present time.     

Ecophysiology of atmospheric moisture in the Namib Desert

Although the Namib Desert is classified as hyperarid, with rainfall extremely rare, there are several other sources of atmospheric moisture, namely, humidity, dew and fog, which make it possible for organisms to live there. Methods to use these sources include locating moist micro-climates, drinking from wet surfaces, consuming moist food, collecting water on the body, and absorbing water vapour. In describing these mechanisms from published sources, we highlight the work of Professor Gideon Louw, to whom we dedicate this paper. Louw's pioneering work on water relations and economy, which includes osmoregulation in desert plants and animals such as grass, beetles, and springbok, established a foundation that inspired numerous studies by colleagues and students. Ecophysiology provides many more lessons that have potential to be mimicked and applied in the occult collection of water in arid regions.     

在线萃取－火焰原子吸收测定地质样品中的痕量金

利用流动注射在线萃取技术，以ＭＩＢＫ为萃取剂，用火焰原子吸收分析方法测定地质样品中的痕量金，取得了满意的效果。该法精密度好，无污染，操作简便，测定迅速，且样品不需分离。方法检出限Ａｕ为０．７８×１０－９，精密度为２．３０％。     

Using a Large-Aperture Scintillometer to Measure Absorption and Refractive Index Fluctuations

The contributions of refraction and absorption fluctuations to the measured scintillations are observed for a near-infrared absorption region using a NOAA designed large-aperture scintillometer. The logarithmic amplitude spectra are shown to decay with frequency as f^-8/3 for both the absorption and scattering mechanisms. For the absorption mechanism this is in line with similar observations made at microwave and infrared frequencies. However, for finite transmitting and receiving apertures, theory predicts a stronger decay of the scattering mechanism due to aperture averaging. The spectral shape is characterised by a region of low frequency absorption, higher frequency refraction and separated by a flattish transition zone. The upper observed corner frequency (f_C2) compares well with values calculated using the measured transverse windspeed (v) for a known aperture radius. The lower corner frequency (f_C1) position is shown to be sensitive to the ratio of the real and imaginary part of the refractive index structure parameter, (C _nR ² /C _nI ² )^3/8, and v. The part of the spectrum associated with the absorption scintillations is observed to be much less than that due to refraction through the day until evening, when decreasing C _nR ² causes C _nR ² /C _nI ² to decrease and absorption to become significant. If absorption is ignored, this may have consequences for calculating nocturnal surface fluxes. During unstable, daytime conditions the large aperture scintillometer is most sensitive to refractive scintillations despite having an infrared source transmitting in a lossy atmosphere. But also under these conditions, the low frequency absorption part of the spectrum is observable.