层序界面及其附近的地质特征与地质过程的表现

本文探讨了层序界面及其附近的地质特征及其构型,建立了三型(Ⅰ,Ⅱ,Ⅲ型)八类层序界面分类方案;Ⅰ型界面包括暴露侵蚀削截面、古土壤面、古喀斯特面和暴露侵蚀界面;Ⅱ型界面包括海平面下降结构转换面和海侵上超界面;Ⅲ型界面包括海底侵蚀成岩间断面和事件界面。运用岩石地层学、生物地层学、磁性地层学及碳氧同位素等多学科,对二叠纪和三叠纪中,二叠与前二叠系之间、二叠与三叠系之间和中下三叠统之间3个主要层序界面进行了探讨,这3个界面分别属于Ⅰ型、Ⅲ型和Ⅰ型界面。提出了层序界面及其附近的地质特征及其地质过程的表现。     

New Chinese National Reference Materials for Hydrogen and Oxygen Isotopes in Water

The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences recently prepared four certified reference materials for hydrogen and oxygen stable isotopes in water, which are called ‘China Standard Water' (CSW)‐HO1–HO4 (hereafter referred to as HO1–HO4). These reference materials are intended for calibration purposes and provide reference values of their relative difference in ²H/¹H and ¹⁸O/¹⁶O isotope‐amount ratios expressed in delta notation, normalised to the VSMOW–SLAP scale. The certified values of the reference materials were determined by an interlaboratory comparison of results from eleven participating laboratories. This paper describes in detail the production and certification procedure of the four reference materials. The first analytical data for the reference materials are also provided using a variety of analytical techniques, namely CO₂–H₂O equilibration and laser spectroscopy for δ¹⁸O and Cr reduction, as well as H₂–H₂O equilibration, laser spectroscopy, and high‐temperature conversion for δ²H. The reference values for materials HO1–HO4 and their associated uncertainties are assigned.     

基于随机森林模型的城市不透水面提取研究 ——以呼和浩特市为例

城市不透水面信息对于城市生态环境动态演化过程研究具有重要意义。以Landsat 8遥感影像为数据源,以呼和浩特市为实证区域,进行了随机森林模型应用于城市不透水面的提取研究,并与目前应用广泛的支持向量机模型进行了对比分析。研究表明：在不同的抽样比例训练样本条件下,随机森林模型对于城市不透水面的提取精度均优于支持向量机的提取精度;对于随机森林模型和支持向量机模型,70%的训练样本比例均为最佳训练样本抽样比例。在该抽样比例下,随机森林模型提取城市不透水面的总体分类精度为93.29%,Kappa系数为0.9051,支持向量机模型的总体分类精度为91.26%,Kappa系数为0.8757;随机森林模型对于城市裸土的识别度较高,能更好地将城市裸土和不透水面进行区分,而支持向量机模型对于城市裸土、不透水面和绿地的区分能力均弱于随机森林模型。综合而言,随机森林模型对城市不透水面的提取精度优于支持向量机模型,随机森林模型可以有效应用于城市不透水面提取领域,进一步丰富了城市不透水面提取方法体系构成。     

DCS－偶氮胂光度法测定钛酸锶烧结物中游离的氧化锶

ＤＣＳ－偶氮胂光度法测定钛酸锶烧结物中游离的氧化锶胡浩，周宏实江苏海安磷肥厂２２６６００ＤＣＳ－偶氮肿［２－（２－胂酸基苯偶氮）－７－（２，６－二氯－４－磺酸基苯偶氮）－１，８－二羟基－３，６－二磺酸萘］属双偶氮变色酸类显色剂，主要用于稀土元素的高灵...     

Determination of Carbon,Hydrogen, Nitrogen and Sulfur in Geological Materials Using Elemental Analysers

This article describes a series of methods developed for the determination of total carbon (C_Total), organic carbon (C_org), hydrogen, nitrogen and sulfur. The following elemental analysers were used: LECO model RC‐412 for the determination of organic carbon, total carbon and hydrogen; LECO model CS‐200 for the determination of total carbon and sulfur; LECO model TN‐400 for the determination of nitrogen; and LECO model TruSpec CHNS for the determination of organic carbon, total carbon, hydrogen, nitrogen and sulfur. Uncertainty and limits of detection and quantification were calculated for each method, as well as the running costs to define the most effective instrument for each material and each analyte. Accuracy was checked by the application of the Sutarno–Steger test. Finally, a compilation of the results obtained in the determination of C_Total, C_org, H, N and S in forty‐nine reference materials is presented.     

离子交换分离过程中铅同位素分馏评估及针对MC-ICPMS铅同位素测定的分离纯化方法的修正

本文对分离纯化样品过程中铅同位素的分馏进行了评估,并描述了适于MC-ICPMS同位素测定的分离纯化方法。利用AG1-X8阴离子交换树脂分离纯化样品中铅的过程确实导致了铅同位素的质量分馏。尽管分离纯化过程导致的铅同位素分馏程度较小(0.43‰amu-1),但明显超出了仪器的测试误差(0.23‰amu-1),如果样品中铅的回收率太低,会导致铅同位素测试值明显偏离真值。利用AG1-X8阴离子交换树脂,以0.2mL 1mol/L HBr溶液为上样介质,以5mL 1mol/L HBr和0.5mL 2mol/L HCl溶液为淋洗液,1.5mL 6mol/L HCl溶液为洗脱液,利用该分离流程可以保证获得样品中铅同位素的准确值。在本实验研究条件下,相对于过柱前样品,前期淋洗液富集铅的轻同位素(δ208Pb0),后期淋洗液富集铅的重同位素(δ208 Pb0),表明在该实验条件下,铅的重同位素组分比轻同位素更容易和树脂结合,AG1-X8阴离子交换树脂吸附铅的配分系数208 D/204 D大于1。解吸被树脂吸附铅的过程中,铅在不同络合形式间的交换反应可能导致了铅同位素的分馏效应,意味着无机络合物或者有机大分子参与反应的过程可能会导致铅同位素的分馏。     

LandSat8热红外遥感数据在甘肃临夏市地热资源调查中的应用

利用热红外遥感技术进行地热异常信息的提取可以为地热资源勘查评价提供重要的依据。本文以甘肃临夏市为研究区,选用2013年10月11日、2015年2月3日、2021年2月19日、2021年3月23日LandSat8数据,采用大气校正法进行地表温度反演,结合地形及地质构造等资料,去除传感器因子、时间因子、温度因子、构造因子等假的地热异常,判读出由于地热资源引起的地热异常可能区域有9个。其中,7号区域实地勘查出地热资源。研究表明,利用长时间跨度的秋冬季节LandSat8热红外数据可以有效提取临夏市地热异常信息;热红外遥感方式在地热调查中能减少外业工作量,但不能代替传统地热勘探方法;结合地形地质资料判读时,必须与专业知识相结合才能取得较好的应用效果。     

4,4′-二[(8-羟基喹啉)偶氮]-3,3′-二甲基联苯分光光度法测定锌

研究了新显色剂4,4,＇-二[(8-羟基喹啉)偶氮]-3.3＇-二甲基联苯(D-HQADMB)与Zn(Ⅱ)的显色反应条件。在CPC存在下的pH7.5～8.5缓冲介质中、Zn(Ⅱ)与D-HQADMB形成稳定的深红色配合物,组成比为Zn(Ⅱ):D-HQADMB=1:2,λ_(max)=550nm,表观摩尔吸光系数为7.19×10~4 L·mol~(-1)·cm~(-1),Zn量在0～1.25μg/ml范围内服从比尔定律。方法可用于测定矿样中的Zn。     

Performance of the stereoscopic system of the HEGRA imaging air erenkov telescopes: Monte Carlo simulations and observations

Based on the Monte Carlo simulations we have studied the performance of the HEGRA system of imaging air erenkov telescopes (IACTs) in its present configuration of 4 IACTs as well as in its future final configuration of 5 IACTs. Here we present the results on the basic characteristics of the IACT system which are used in the standard data analysis procedure, i.e., the collection areas, the detection rates, the angular resolution, the energy resolution, and the γ/hadron-separation efficiency. By comparing several key Monte Carlo predictions with experimental results it is possible to check the accuracy of the simulations. The Monte Carlo results concerning hadron-nuclear showers are tested with the recorded cosmic ray events and the results concerning photon-induced showers are tested with a large data sample of γ-rays observed from BL Lac object Mkn 501 during its high flaring activity in 1997. Summarizing the simulations and current observations we give the basic recommendations of using the instrument and the major values of its sensitivity.