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11.
龙须菜和扁江篱多糖的组成及其抗肿瘤效果 总被引:22,自引:0,他引:22
于1985-1987年期间用冷水和热水对采集于青岛的龙须菜和扁江篱的琼胶型多糖进行提取。两海藻的热水提取多糖都通过DEAE-SephadexA50色谱桩用热水和不同浓度NaCl深液前后进行洗脱分级。龙须菜和扁江篱多糖的主要级分分别为0.5mol/L和1.0mol/LNaCl洗脱级分。对各级分做化学分析及IR和^13CNMR光谱分析。结果表明,龙须菜多糖由琼二糖、琼胶糖前体和6-OCH3-琼二糖组成 相似文献
12.
GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea 总被引:4,自引:1,他引:3
The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric
electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those
due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference
ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent
scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric
structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D
ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography
reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters
at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large
increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which
is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde
observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward
electric field, and are not associated with the increase of the O/N2 ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not
caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical
ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically
coupled upward to generate ionospheric perturbations and oscillations. 相似文献
13.
A preliminary study of the carbon-isotopic content of ambient formic acid and two selected sources: Automobile exhaust and formicine ants 总被引:2,自引:0,他引:2
Relatively large quantities (1 mg) of formic acid have been collected from the atmosphere and subjected to carbon-isotopic analysis, as a means of source discrimination. Ambient formic acid was captured on Ca(OH)2-treated filters using a high-volume sampler. The collection method was not only efficient (>96%), but also appears to have low artifact production.Most of the samples (36 out of 52) were collected over a two-year period at the summit of Mount Lemmon, Arizona, where a strong seasonality in HCOOH mixing ratio was observed (0.2 ppb during winter months to 1.5 ppb in the summer). Other collection sites included the Oregon coast, Colorado Rockies, urban Tucson, and the North Dakota prairie. The carbon-13 content of atmospheric HCOOH was found to be have little variation (–18 to –25), regardless of location or season. This is consistent with a single dominant source of formic acid. The carbon-14 measurements of 6 Mount Lemmon samples showed high levels of modern carbon (93–113% modern).The emissions from formicine ants and automobile combustion were selected as two other potential sources for isotopic analysis. The HCOOH collected from auto exhaust was much more depleted in13C than the atmospheric samples, with a 13C of –28.0 and –48.6 from a leaded and unleaded automobile, respectively. Formicine ants, on the other hand, ranged from –17.2 to –20.6. 相似文献
14.
This study employed Slack-based measure (SBM), Meta-frontier analysis, and Malmquist–Luenberger index (MLI) approaches to measure energy efficiency (EE), production technology heterogeneity, and energy productivity variation and its main determinants in developed and developing G20 countries for the period 1995–2020. The study's findings are: (i) Average EE for G20 countries is 0.8577, but still has an improvement potential of 14.23 percent. (ii) Developed countries have a higher average EE than developing (0.8927 > 0.8290). Results further revealed that energy efficiency scores in Argentina, Australia, Brazil, France, Saudi Arabia, South Africa, the US, the UK, and Korea are>1. (iii) Technology gap ratio (TGR) value in developed countries is higher than in developing (0.9869 > 0.6801), indicating that developed countries have advanced energy technologies superiority. The average MLI is less than one, showing a decline in energy productivity mainly due to a decline in technical efficiency, as EC < TC. (iv) Developed G20 countries get 0.64 percent aggregate growth in energy productivity as their MLI score is 1.0064, mainly due to technological growth (TC = 1.0161). Developing G20 countries, on the other hand, witnessed a decline in their energy productivity during 1995–2020, as MLI = 0.9925 > 1, designating that, on average, there is a 0.75 % decline in MLI. 相似文献
15.
Diagenesis of vascular plant organic matter components during burial in lake sediments 总被引:12,自引:0,他引:12
Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither 13C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components. 相似文献
16.
A. B. Kuznetsov M. A. Semikhatov A. V. Maslov I. M. Gorokhov E. M. Prasolov M. T. Krupenin I. V. Kislova 《Stratigraphy and Geological Correlation》2006,14(6):602-628
New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ13C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ13C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the 87Sr/86Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation. 相似文献
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Anton VaksMiryam Bar-Matthews Avner AyalonBettina Schilman Mabs GilmourChris J Hawkesworth Amos FrumkinAaron Kaufman Alan Matthews 《Quaternary Research》2003,59(2):182-193
High-resolution 230Th/234U ages and δ18O and δ13C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ18O and δ13C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods. 相似文献