南海北部台西南盆地973-4岩芯碳的地球化学特征

对南海北部台西南盆地天然气水合物潜在区(973-4岩芯)碳的形态、含量和稳定同位素组成进行了分析,并探讨了成岩环境因素和细菌种群与碳地球化学行为的关系。结果显示:(1)TOC含量为0.4%~1.3%,δ~(13)CTOC为–26.7‰~–23.9‰,说明973-4岩芯主要为陆源有机质,能够满足微生物产甲烷的需要;DIC和δ~(13)CIC的垂向变异及其显著负相关,指示:973-4岩芯560~890 cm深度段有SO42–驱动的AOM反应。(2)p H、Eh、沉积物粒径等成岩环境参数与TOC、IC、δ~(13)CTOC、δ~(13)CIC等碳地化参数显著相关。(3)细菌种群与DIC、δ~(13)CIC显著相关。结论认为:(1)973-4岩芯碳的地化行为与天然气水合物成藏存在明显响应关系。(2)成岩环境参数的垂向变异与碳的地球化学特征密切相关。(3)细菌种群对碳的地化参数变异有着显著影响。     

碳中和视角下全球农业减排固碳政策措施及对中国的启示

碳中和是指人类活动造成的碳排放与全球人为碳吸收量在一定时期内达到平衡,也称为净零排放 [1].《巴黎协定》第四条提出采取减排增汇措施以实现21世纪后半叶人为温室气体排放量与汇的清除量达到平衡 [2].越来越多的国家正将其转化为战略和行动,目前已有100多个国家提出碳中和目标承诺,并明确了碳中和时间表.2020年9月第7...     

福建龙岩地区土壤有机碳储量特征及其影响因素

基于福建龙岩地区多目标区域地球化学调查所获得大量高精度和高密度有机碳数据,通过单位土壤碳储量计算方法,分别采用母质类型、地貌类型、生态系统、土地利用类型及土壤类型5种方式,按照0~1.4m,0~1.0m和0~0.2m等3种不同深度来初步探讨福建龙岩地区土壤有机碳储量特征及其影响因素。结果表明,不同类型土壤区的有机碳储量分布存在不均匀性,平均碳密度均存在较大差异,这可能不仅与成土母质、土壤理化性状(如土壤结构、质地、化学成分、土温等)、系统差异(如历史演变、稳定性等)等内在因素有关,还有可能与气候环境条件、海拔高度、水土流失程度、土壤微生物活动强度、植被状况(如植被类型、植被发育等)以及人类活动影响等外在因素有关。得出福建龙岩地区不同深度的有机碳储量: 0~0.2m为89254953.05t, 0~1.0m为283746254.26t和 0~1.4m为347294329.32t; 不同深度的平均碳密度: 0~0.2m为3980.33 t/km 2, 0~1.0m为12653.69 t/km 2和0~1.4m为15487.62 t/km 2,高于全国典型地区平均水平,显示出福建龙岩地区具较高的碳储量、较强的碳储能力和良好的碳富集环境。     

塔中地区奥陶系喜马拉雅山期S干气充注的证据

塔中地区奥陶系天然气成因多样;Ⅰ号坡折带中东部奥陶系天然气以高干燥系数、 甲烷同位素值重为特征;与塔深1井寒武系原油裂解气接近;应主要来自寒武系原油裂解气成因。寒武系贫H2S、 高成熟原油裂解气在喜马拉雅山期时;气侵奥陶系油气藏;得到了以下主要证据的支持: 1）天然气甲烷δ13C值大多比Chung et al.（1988）天然气模式甲烷δ13C值计算值高3‰以上;2）干燥系数与甲烷δ13C值大体上具有正相关关系;3）天然气干燥系数与H2S含量大体上具有负相关关系。这些特征表明;存在贫H2S、 相对富13C甲烷为主的干气与富H2S、 相对贫13C甲烷的湿气混合作用。奥陶系中H2S-δ34S 值为14‰～20‰;远低于中深1井寒武系原地热化学硫酸盐还原作用（TSR）成因的H2S（33‰）;支持了奥陶系中H2S并不是来源于寒武系古油气藏。于是提出;来自寒武系贫H2S的干气在喜马拉雅山期对良里塔格组和鹰山组油气藏发生了气洗;油气藏的气/油比值增大、 导致了原油蜡含量增高、 甲烷δ13C值发生正偏移。     

长江口悬沙颗粒的现场测量

我们利用自．行研制的“光学悬浮沙粒径谱仪”对长江口悬沙颗粒进行了现场测量,同时作了现场采样,经华东师范大学河口海岸国家重点实验室分析,分析结果与仪器现场测量结果进行了对比,结果表明,两种方法得到的平均粒径和悬沙浓度基本一致。     

锥直喷嘴淹没磨料射流场的数值模拟

利用计算流体力学(CFD)中的fluent软件对喷嘴淹没磨料射流进行数值模拟,研究锥直形喷嘴在不同射流靶距、不同磨料颗粒直径和颗粒浓度情况下液固两相射流场特性,给出水和磨料速度分布规律,考虑液固两相间的相互作用力.结果表明:液固两相速度在喷嘴收缩段迅速增加,水与磨料颗粒之间存在速度滑移;液固两相入口速度为170 m/s...     

烷烃碳同位素对页岩含气性的指示意义——以四川盆地及周缘龙马溪组为例

以四川盆地及周缘龙马溪组为例,分析了烷烃碳同位素平面分布特征以及倒转情况,定量研究了烷烃碳同位素值与热演化程度、埋藏深度及含气量之间的关系,并探讨了造成不同区块烷烃碳同位素倒转程度差异的主要原因。结果表明:(1)龙马溪组页岩气组分具有典型的干气特征:CH4含量介于95.32%～99.59%,平均为98.44%;C2H6含量较少,介于0.09%～0.74%,平均为0.52%;C3H8含量普遍很低。(2)烷烃碳同位素表现为自盆地边缘向盆地中心逐渐变轻的特征,δ13C1值介于-36.9‰～-26.7‰,平均为-30.27‰;δ13C2值介于-42.8‰～-31‰,平均为-34.9‰;δ13C3值介于-50.5‰～-33.1‰,平均为-37.28‰。(3)整体上,四川盆地及周缘龙马溪组页岩气烷烃碳同位素具有完全倒转(δ13C1δ13C2δ13C3)的特征,页岩气成藏过程中干酪根裂解气与滞留烃裂解气的混合可能是导致烷烃碳同位素发生倒转的主要原因。(4)同位素定量分馏模型显示滞留烃裂解气在页岩气中的占比多大于60%,指示两种裂解气混合比不同是造成烷烃碳同位素倒转程度差异的主要原因;整体上,随滞留烃裂解气含量的增多,δ13C2值减小,烷烃碳同位素倒转程度增大,页岩的含气量也逐渐增加。     

Land use effects on soil organic carbon,microbial biomass and microbial activity in Changbai Mountains of Northeast China

Land use changes are known to alter soil organic carbon （SOC） and microbial properties, however, information about how conversion of natural forest to agricultural land use as well as plantations affects SOC and microbial properties in the Changbai Moun- tains of Northeast China is meager. Soil carbon content, microbial biomass carbon （MBC）, basal respiration and soil carbon mineraliza- tion were studied in five selected types of land use： natural old-growth broad-leaved Korean pine mixed forest （NF）; spruce plantation （SP） established following clear-cutting of NF; cropland （CL）; ginseng farmland （GF） previously under NF; and a five-year Mongolian oak young forest （YF） reforested on an abandoned GF, in the Changbai Mountains of Northeast China in 2011. Results showed that SOC content was significantly lower in SP, CL, GF, and YF than in NF. MBC ranged from 304.4 mg/kg in CL to 1350.3 mg/kg in NF, which was significantly higher in the soil of NF than any soil of the other four land use types. The SOC and MBC contents were higher in SP soil than in CL, GF, and YF soils, yielding a significant difference between SP and CL. The value of basal respiration was also higher in NF than in SP, CL, GF, and YF. Simultaneously, higher values of the metabolic quotient were detected in CL, GF, and YF soils, indicat- ing low substrate utilization of the soil microbial community compared with that in NF and SP soil. The values of cumulative mineral- ized carbon and potentially mineralized carbon （Co） in NF were significantly higher than those in CL and GF, while no significant dif- ference was observed between NF and SP. In addition, YF had higher values of Co and C mineralization rate compared with GF. The results indicate that conversion from NF into agricultural land （CL and GF） uses and plantation may lead to a reduction in soil nutrients （SOC and MBC） and substrate utilization efficiency of the microbial community. By contrast, soils below SP were more conducive to the preservation of soil organic matter, which was reflected in the comparison of microbial indicators among CL, GF, and YF land uses. This study can provide data for evaluating soils nutrients under different land use types, and serve as references for the rational land use of natural forest in the study area.     

Damming of large river by debris flow: Dynamic process and particle composition

The frequency and extent of debris flows have increased tremendously due to the extreme weather and the Wenchuan earthquake on May 12, 2008. Previous studies focused on the debris flow from gullies damming the mountain streams. In this paper, an equation for the run-out distance of debris flow in the main river is proposed based on the dynamic equation of debris flow at different slopes given by Takahashi. By undertaking field investigations and flume experiments, a new calculation method of the volume of debris flow damming large river is obtained. Using the percolation theory and the renormalization group theory it was deduced that the large particles should comprise more than 50% for forming a stable debris flow dam. Hence, the criteria of damming large river by debris flow is presented in terms of run-out distance and grain composition which was then validated through the event of damming river by debris flow at Gaojia gully, the upper reaches of the Minjiang River, Sichuan, China, on July 3, 2011.     

龙水金矿区冷水冲构造蚀变带成矿分析

本文对龙水金矿区冷水冲构造蚀变带的成矿地质条件作了重点论述。冷水冲构造蚀变带是与目前正在开采的龙水1号脉带同归一构造体系的“潜伏”脉带。该“潜伏”脉带的金矿化限于寒武系以硅质岩为顶板的碳质页岩中,明显受成矿前产生的韧性剪切带控制。据已知矿区矿化元素分布的化探模式,提出利用元素组合的特征寻找该类矿体。