藻碳酸酐酶胞外酶活性对过渡金属响应的实验研究

Mn2+、Fe2+、Co2+、Ni2+、Cu2+、Zn2+、Cd2+对衣藻Chlamydomonas reinhardtii碳酸酐酶胞外酶(CAe)活性的影响研究表明,CAe活性对过渡金属的响应因金属种类的不同而不同;这些过渡金属影响CAe主要通过两个途径直接与CAe作用和间接影响藻细胞内CAe的新陈代谢.     

蓝藻的卫星遥感研究进展

蓝藻在水体中分布广泛，对水体中碳、氮循环起到重要作用。蓝藻体内的藻蓝和藻红蛋白具有特征性光谱，通过这些光谱可以对蓝藻进行卫星遥感监测。本文主要从海洋、内陆水体中蓝藻的卫星遥感和国内水体生物光学研究状况等方面进行阐述，并对未来的研究趋势进行了展望。     

Six thousand years of records of metal mining and utilization from lake sediments in central China

A sediment core from the Liangzhi Lake, Hubei Province in central China, was used to assess metal usage and accumulation in the past 6000＋ years in China. The concentrations of trace metals, including Cr, Cu, Pb, Ni and Zn, and major elements, Ca, Fe and Mg, in the ^14C-dated sediment core were analyzed. Historical trends of metal inputs to the Liangzhi Lake from 5000 B.C. to the present were recorded in the sediments, representing over 6000 years of metal mining and utilization history in China. The concentrations of Cu, Ni, Pb and Zn have increased gradually since 3000 B.C., indicating the start of the Bronze Age era in ancient China, until the period 467-76 B.C. During the period of 467-76 B.C., there had been a rapid increase in the concentrations of these metals in the sediments, indicating the enormous inputs of these metals at that time. This era corresponded well with the Warring States Period （475-221 B.C.） and early Hart Dynasty （206 B.C.-220 A.D.） of China, during which copper and lead were extensively used in making bronze articles, such as vessels, tools and weapons. During 1876 A.D. to the early 1900s, there was also a significant increase in the metal concentrations, such as Cu, Ni and Pb, which could probably reflect the impact of metal emissions during the early industrial development and wars in China. The Pb isotopic analysis showed that the surface and subsurface sediments had lower ^206Pb/^207Pb, and ^208Pb/^207Pb ratios than the deeper layers, affected by mining activities both during the Bronze Age era and modem times.     

Fine-particle Mn and other metals linked to the introduction of MMT into gasoline in Sydney, Australia： Results of a natural experiment

PM2.5 particulates were analyzed using accelerator-based ion beam methods for a suite of 21 species （H, C, Na, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Br, Pb） to evaluate the contribution to Sydney air associated with the introduction of MMT as a replacement for Pb. MMT was discontinued in 2004. Teflon filters continuously sampled for 7 years from 1998 to 2004 were analyzed from two sites： a suburb （Mascot） close to the Central Business District [CBD （n=718）] and a high trafficked area, and a relatively rural （background） setting, ～20 km west of the CBD （n=730）. Mean Mn concentrations in air at the background site increased from 1.5- 1.6 ng/m^3 to 〈2 ng/m^3 at the time of the greatest MMT use whereas those at Mascot increased from about 2 to 5 ng/m^3. From the maximum values, the Mn showed a steady decrease at both sites concomitant with the decreasing use of MMT. Lead concentrations in air at both sites decreased from 1998 onwards, concomitant with the phase out of leaded gasoline in 2002. A high correlation was obtained for the relationship between Mn in air and lead replacement gasoline （LRG） use （R2 0.83） and an improved correlation for Mn/Al＋Si＋K and LRG use （R2 0.93）. With Mn concentrations normalized to background values of Al＋Si＋K to account for the lithogenically-derived Mn, the proportion of anthropogenic Mn was -70%. Changes for Mn and Pb in the particulates are attributed to the before-during-after use of MMT and decreasing use of Pb in gasoline.     

金属矿产成矿控矿条件研究与找矿实践

通过对陕西秦岭、云南滇东北等地区铅锌矿、金矿的二十多年勘查研究找矿经验的分析,论述了该区金属矿产的控矿条件调查与找矿、热水沉积成矿作用与找矿、矿床成矿模式研究与找矿、区域成矿规律研究与找矿.     

河北围场发现金多金属成矿带

河北围场朝阳湾金矿，1：1万地质填图发现金矿点20处、矿化点40处。金矿最高品位达每吨18克。     

用改进的增量方法计算硫化物中硫的同位素分馏系数

增量方法已成功地应用到硅酸盐矿物、金属氧化物、碳酸盐矿物和硫酸盐矿物氧同位素分馏系数的计算中。本文在对硫化物晶体结构与矿物学特点分析的基础上,通过详细分析前人对硅酸盐矿物和金属氧化物中氧同位素分馏的增量计算方法,将氧化物和硫化物的晶体特征加以对比,提出了计算硫化物中硫同位素分馏的增量计算方法。修正的增量方法根据硫化物的晶体化学结构特征,引入了一个重要的参数,即Madelung常数,用于指示不同结构的硫化物对~(34)S的富集能力。本文利用这一修正的增量方法计算出了0℃到1000℃温度范围内,磁黄铁矿、方铅矿、闪锌矿、黄铜矿、硫镉矿的10~3Inβ和它们之间的分馏系数10~3Inα。并给出这五种矿物间的~(34)S富集顺序：磁黄铁矿＞硫镉矿＞闪锌矿＞黄铜矿＞方铅矿。与前人的实验结果对比表明,本次计算结果与实验结果基本吻合。同时,增量计算方法成功地再现了任意硫化物中~(32)S、~(33)S、~(34)S和~(36)S这四种同位素之间确实存在一定的分馏比例关系。这说明尽管增量方法存在一定的局限性,但将其扩展到硫化物间硫同位素分馏的理论计算是可行的。     

金堆城钼矿固体废物对水环境的污染

本文通过对陕西华县金堆城钼矿区西川河流经废石堆的入口处和出口处采取的水样进行了常量组分、微量组分的测定,分析其污染特征,确定出金堆城钼矿废石堆对水环境的污染指标.