满洲里—西旗斑岩铜多金属成矿系列REE地球化学特征及应用

对该区燕山期斑岩铜多金属成矿系列进行了REE地球化学研究,并结合岩石化学、包体、微量元素、氢氧同位素综合分析。各(蚀变)岩体REE分布模式可分为三种类型。在乌山矿床Q-Kf、Q-Ser、I-H三个蚀变带中REE分别呈氯化物、F~-络合物、F~-、CO_3~(2-)络合物形式。蚀变是两期叠加的,REE的淋滤、沉淀伴随成矿元素的再活化、再富集。首次发现铕亏损对矿化具有指示意义,蚀变岩δEu愈小,矿化愈好。提出了斑岩体含矿性的五条判别标志,据此对外围岩体含矿性进行了判别排队。     

深海多金属结核照片的图象复原和图象处理技术研究

本文报导了关于深海洋底多金属结核照片的图象复原和图象处理方法技术研究结果。海底照片存在的主要问题是:光照分布不均匀、有时聚焦欠佳、常有铁丝影象、有时有泥浆局部干扰等。本文剖析了光照分布的数学模型,推导了倾斜相机系统和水平相机系统条件下的光照分布及感光光强分布公式。本工作利用图象处理系统研究成功了一套适用于海底照片的图象复原和图象处理技术,给出了详细流程图。做为实例本文附有六幅图片,说明所研究的方法在去除光照不均匀、铁丝干扰、提高反差、增强分辨率、自动分类、科学统计覆盖率等的显著效果,以及通过局部放大研究结核的结构和形态方面的可能性。本文所报导的方法是改善和研究珍贵海底照片的重要工具。     

Electronic Structures of Square Planar Coordinated Transition Metal Ions in Compounds with Gillespite Structure

Electronic structures of square planar coordinated transition metal ions in BaCuSi₄O₁₀ and CaCrSi₄O₁₀ are investigated using the ligand-field theory (LFT), angular overlap model (AOM) and iterative extended Hückel molecular orbital theory (IET). The electronic energy levels of the natural mineral dioptase are also investigated, in which the Cu²⁺ ions occupy the sites of pseudo D_4h symmetry. Both LFT and AOM predict that the crystal-field levels of transition metal ions in these compounds follow such an order that E (²B_1g <E(²B_2g <E(²A_1g )<E(²E_g ), and the frequencies of the crystal-field transitions obtained from point charge calculations are in good agreement with those observed. However, the energy-level order cannot be determined unambiguously from the IET calculation because it depends on the values of parameters chosen for the calculation.