量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

瞬变电磁法在断层含水性评价中的应用

本文介绍了瞬变电磁法在煤矿水文地质勘探中的具体应用效果.采用瞬变电磁法对落差较大断层的含(导)水性进行测量,不仅可有效地控制断层的空间位置,而且可定性地判断断层的富水性,其测量结果与已知水文地质资料吻合较好.     

海洋科技人才与成果的摇篮——青岛海洋大学

青岛海洋大学是一所以海洋和水产学科为特色的重点综合大学。1999年11月，经国家批准，成为“九五”期间“211工程”重点建设高校。数年来，青岛海大致力于“211工程”建设，在物理海洋学、水产养殖学、海洋药物学和海洋化学学科4个重点学科建设中取得丰硕成果。     

Silicon limitation on primary production and its destiny in Jiaozhou Bay, China——Ⅳ：Study on cross-bay transect from estuary to ocean

The authors analyzed the data collected in the Ecological Station Jiaozhou Bay from May 1991 to November 1994, including 12 seasonal investigations, to determine the characteristics, dynamic cycles and variation trends of the silicate in the bay. The results indicated that the rivers around Jiaozhou Bay provided abundant supply of silicate to the bay. The silicate concentration there depended on river flow variation. The horizontal variation of silicate concentration on the transect showed that the silicate concentration decreased with distance from shorelines. The vertical variation of it showed that silicate sank and deposited on the sea bottom by phytoplankton uptake and death, and zooplankton excretion. In this way, silicon would endlessly be transferred from terrestrial sources to the sea bottom. The silicon took up by phytoplankton and by other biogeochemical processes led to insufficient silicon supply for phytoplankton growth. In this paper, a 2D dynamic model of river flow versus silicate concentration was established by which silicate concentrations of 0.028–0.062 μmol/L in seawater was yielded by inputting certain seasonal unit river flows (m³/s), or in other words, the silicate supply rate; and when the unit river flow was set to zero, meaning no river input, the silicate concentrations were between 0.05–0.69 μmol/L in the bay. In terms of the silicate supply rate, Jiaozhou Bay was divided into three parts. The division shows a given river flow could generate several different silicon levels in corresponding regions, so as to the silicon-limitation levels to the phytoplankton in these regions. Another dynamic model of river flow versus primary production was set up by which the phytoplankton primary production of 5.21–15.55 (mgC/m²·d)/(m³/s) were obtained in our case at unit river flow values via silicate concentration or primary production conversion rate. Similarly, the values of primary production of 121.98–195.33 (mgC/m²·d) were achieved at zero unit river flow condition. A primary production conversion rate reflects the sensitivity to silicon depletion so as to different phytoplankton primary production and silicon requirements by different phytoplankton assemblages in different marine areas. In addition, the authors differentiated two equations (Eqs. 1 and 2) in the models to obtain the river flow variation that determines the silicate concentration variation, and in turn, the variation of primary production. These results proved further that nutrient silicon is a limiting factor for phytoplankton growth. This study was funded by NSFC (No. 40036010), and the Director's Fund of the Beihai Sea Monitoring Center, the State Oceanic Administration.     

经纬仪大尺寸工业测量系统定向法及精度分析

根据工业测量系统的基本原理,通过对系统定向方法及精度的分析与评定,阐述了系统定向方法,保证系统测量结果的精度性及可靠性。     

宁波商帮的海洋文化情结

宁波商帮是我国十大商帮之一 ,百年经久不衰 ,究其原因是宁波商帮受到独特的宁波城市文化熏陶。宁波得天独厚的海洋优势 ,造就了有悠久历史凝结和中外文化交融的宁波海洋文化。海洋文化是一种先进的文化 ,具有大海的许多秉性 :大度、创新、包容。宁波城市文化把中国传统的儒家文化和宁波海洋文化很好地结合起来。正是这种独特的宁波城市文化 ,才哺育出顽强开拓、勇于创新 ,克勤克俭、脚踏实地 ,注重团队、和衷共济的“宁波商帮精神”。     

Statistical analysis of surface hydrography and circulation variations in northern South China Sea

1 INTRODUCTIONThe South China Sea (SCS) is a semi-enclosedmarginal sea in western North Pacific Ocean withvery complex topography and is the important pas-sage connecting the Pacific and Indian Oceans. Ithas great impact to the global climate and a greatinterest of many oceanography researchers. Twodominant surface hydrographic and circulation fea-tures in the northern SCS are a strong fresh waterexpansion and a warm and high-salinity seawaterintrusion such as the SCS Diluted Water…