单柱式海上风能建筑结构物——环力作用下砂性土孔隙水压力的研究

单柱式海上风能结构物近年来引起各国的高度重视,德国制定了研究大型单柱式风能结构的计划.基于计划要求,通过对历年一些相关文献的研究分析,建立了新型的实验模型模拟单柱式海上风能结构,同时运用Fe程序进行了模拟,共同对砂土中单桩在循环力作用下土体中孔隙水压力变化进行了研究,并对不同渗透率砂土和不同频率的循环力条件下的土体孔隙水压力作了对比分析.得出了土体中孔隙水压力的存在和其存在的大小是受自身和周边条件影响的.此研究结果对于德国大型单柱式风能结构物的研究有一定价值.     

铁—磺基水杨酸—二甲氧基羟基苯基荧光酮—TritonX—100体系的光度研究 …

研究了在表面活性剂存在下,铁与新显色剂二甲氧基羟基苯基荧光酮（ＤＭＨＰＦ）的显色反应。在ｐＨ９．０～１０．５的氨性介质中,有磺基水杨酸（Ｓａｌ）存在下,形成Ｆｅ３＋ＳａｌＤＭＨＰＦＴｒｉｔｏｎＸ１００四元混配配合物,其最大吸收峰在５９０ｎｍ,测定波长选择６１０ｎｍ,表观摩尔吸光系数分别为１．３×１０５Ｌ·ｍｏｌ－１·ｃｍ－１和９．４×１０４Ｌ·ｍｏｌ－１·ｃｍ－１。配合物组成比ｎＦｅ３＋∶ｎＤＭＨＰＦ＝１∶２,Ｆｅ３＋的质量浓度为０～６００μｇ／Ｌ时符合比尔定律。以直接光度法测定工业硅和石灰石样品中微量铁,结果与标准值相符,５次测定的ＲＳＤ在０．６４％～２．４１％。     

东太平洋冷舌区海表面温度日变化特征的模拟研究

本文通过分辨太阳辐射日变化, 利用中国科学院大气物理研究所大气科学和地球流体力学数值模拟国家重点实验室 (LASG/IAP) 气候系统海洋环流模式 (LICOM), 模拟了东太平洋冷舌区海表面温度 (SST) 的日变化特征并研究了弱混合对其影响。采用理想的太阳辐射日变化强迫上层垂向分辨率为10 m的海洋模式LICOM, 模拟出了SST日变化一些特征, 同时海洋的上层流场也产生明显日变化。模拟的SST日变化振幅水平分布与观测接近, 且受太阳辐射日变化振幅水平分布调制。在赤道中东太平洋区, 模拟的SST日变化振幅 (约为0.3～0.4℃) 比观测偏小约0.1～0.2℃。模拟的SST日变化峰值出现在15～16 时 (当地标准时间), 落后于太阳辐射峰值2～3个小时, 接近观测。进一步减弱混合后, 模拟的日变化振幅增加约0.1℃, 更接近观测。这说明在东太平洋冷舌区SST日变化主要受太阳辐射日变化和垂直混合影响。此外, 混合减小后, 在太阳辐射日变化调制下, 平均态 (如混合层、温度和流场) 也出现明显变化。在赤道东太平洋冷舌区北侧, 弱混合导致混合层变浅, 变浅使热量堆积进而使平均SST升高约0.3℃; 在赤道东太平洋冷舌南侧, 经向平流加强导致平均SST降低约0.2℃。     

西秦岭关家沟组地层时代、物源及其构造响应

在西秦岭关家沟组贾昌沟砂板岩所夹的硅质岩层中发现晚石炭世和晚二叠世的古生物化石;在关家沟组砾岩中所采的花岗质和火山质砾石,利用氩-氩(40Ar/39Ar)法测年所获得的年龄为晚三叠世。对关家沟组物源及其古水流分析,其古水流方向230°~356°,其物源主要来自南东侧活动大陆边缘的碧口岛弧,且秦岭全面碰撞造山期为早中生代。由此,初步推测关家沟组形成时代可能与秦岭全面碰撞造山为同期——早中生代。     

X射线荧光光谱法同时测定土壤样品中的36种组分的探讨

采用粉末压片法制样,使用新型X射线荧光光谱仪,对土壤样品中的C、N、S、Cl、Na、Mg、Al、Si、K、Ca、Fe、As、Ba、Br、Ce、Co、Cr、Cu、Ga、Hf、La、Mn、Nb、Ni、P、Pb、Rb、Sc、Sr、Th、Ti、U、V、Y、Zn、Zr等36种组分的直接同时测试进行了探讨测试。研究了测试中各种分析条件及存在问题。结果表明,方法的检出限、精密度和准确度大多数满足多目标地球化学调查样品分析质量的要求,标准物质的测定值与其标准值相吻合,适合土壤样品中多组分的同时直接测定。     

熔融包裹体中水含量的测定方法

本文在对Ｎａｕｍｏｖ（１９７９）计算熔融包裹体中水含量计算模式作原则性修正的基础上建立了新的计算模式,其特点是充分考虑了熔体被捕获后在漫长地质时期内经历的各种变化对其中水含量计算精度的影响。通过加热使熔融包裹体均一,并在均一化过程中的每一个相变发生前后分别测量各相的相对体积百分比,可从本质上消除Ｎａｕｍｏｖ计算模式未曾考虑过的对水含量计算精度发生影响的因素,因此可较为准确地获得熔融包裹体中的水含量。计算实例表明,烙融包裹体中的水含量与其均一温度负相关,随均一温度的降低含水量增高。     

深圳市浴场用海定级研究

海域分等定级是制定海域使用金征收标准和开展海域资产价格评估的前提和依据。借鉴《海域定级技术指引(试行)》,遵循资源禀赋差异、收益差异、节约利用和生态用海的原则选取海域自然条件和海域区位条件2个定级因素及海水质量、海洋自然灾害等10个评价因子,构建深圳市浴场用海定级的评价指标体系。采用综合指数评价法计算出207个评价单元的得分情况,通过聚类分析方法和变异系数(CV)来校核级别,最终将浴场用海的海域划分为Ⅰ级(22.22%)、Ⅱ级(33.82%)和Ⅲ级(43.96%)3个级别。研究成果为海洋管理部门制定浴场用海不同级别的基准价格提供了依据。     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

小浪底水库运用对黄河下游河道水流阻力的影响

小浪底水库运用后,黄河下游河床冲刷粗化严重、水流阻力变化十分明显。为定量描述小浪底水库运用对水流阻力的影响,基于黄河下游水文站流速、河宽、床沙粒径、曼宁系数等实测数据分析,结合床面形态控制数理论及实测床面形态资料,建立了包含床面形态因子的动床阻力计算公式,计算精度得到了黄河下游水文站1 508组实测数据的验证。分析计算表明：黄河下游床沙粒径上段粗、下段细的特征更加突出,高村以上游荡型河段沙垄发育、动床阻力增加明显;高村以下河段,河床冲刷粗化程度明显减少,动床阻力变化相对较小,但河槽断面趋于窄深,洪水期岸壁阻力增大明显。小浪底水库运用促进了黄河下游床面形态的发育,增大了各河段的水流阻力。     

Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum

Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc.