椒江河口沉积物As、Hg黄铁矿矿化程度及其生物有效性

本文利用取自浙江椒江河口3个未扰动柱状沉积物样,进行了孔隙水化学测试、固相沉积物的活性分量与黄铁矿分量的分级提取和测试,结果表明：Hg主要以黄铁矿态形式存在于沉积物中。As在有机碳较高的河口区潮上带和沉积速率较慢的潮下带主要以黄铁矿形态存在[DTMP（degree of trace metal pyritization,痕量元素黄铁矿矿化程度）〉50%）],而在中潮带As的黄铁矿矿化程度略低（DTMP均值为40.99%）,研究区DOP（Fe的黄铁矿矿化程度）值普遍较低（〈35%）,Mn-DTMP低于3.32%。从而揭示了浙江椒江河口沉积物在数厘米以下,毒性痕量元素Hg和As被高度黄铁矿矿化的规律性,并指出在遇有海事活动或风暴潮事件对海底沉积物进行扰动时,河口沉积物与充氧的海水反应,高度黄铁矿矿化的痕量元素会转变成活性态,从而导致近海生态系统的毒性事件。     

DRY-SEASON VARIABILITY IN SUSPENDED SEDIMENT CONCENTRATIONS IN THE SOUTH PASSAGE OF THE CHANGJIANG ESTUARY

This paper reports the results of continuous monitoring of turbidity, water depth, salinity (using an Optical Backscatter Sensor (OBS)), and current velocity (using a Current meter (SLC9-2)) in the South Passage of the Changjiang Estuary over a spring–neap period in February 2003 (dry season). The turbidity measured via OBS was closely correlated with the suspended sediment concentration (SSC), which was highly variable. Over the study period, the SSC in the middle layer ranged from 110 to 1400 mg/l. The minimum SSC occurred during a late ebb tide, and the maximum SSC occurred during a late flood tide. On average, the SSC was 1.5 times higher during flood tide than during ebb tide. Vertically within the water column, SSC increased downward, with the ratio of SSC measured near the bed to that measured at the surface ranging from 1.90 to 18.3. The temporal variability in SSC is jointly governed by tides and wind-induced waves, whereas the vertical variability in SSC is attributed to the effect of gravity and vertical water circulation.     

攀西水系沉积物铂、钯异常及对找寻铂、钯矿的启示

利用攀枝花幅（永仁幅）、会理幅、盐边幅、米易幅、盐源幅和西昌幅共6个1：20万图幅的区域铂、钯地球化学资料,运用了数据滤波处理方法圈定铂族元素异常.讨论了水系沉积物中铂、钯地球化学背景和异常与峨眉山玄武岩、基性-超基性岩等地质体的空间关系,并做了该地区铂族矿产的找矿远景预测.     

台风“巴威”对威海楮岛沙滩的侵蚀研究

为进一步探究台风作用下滨海沙滩滩面变化过程,揭示台风过程对滨海沙滩的影响,本文通过分析楮岛沙滩台风影响前后9个剖面的高程测量数据以及采集的滩面沉积物样本,对比研究台风前后海滩剖面冲淤特征和滩面沉积物粒径变化,探讨台风“巴威”对楮岛沙滩影响。结果表明：在台风“巴威”影响下楮岛沙滩表现出中间淤积、两边侵蚀的特征,由于沙滩西南侧滩肩宽、坡度缓等特点,侵蚀程度明显弱于沙滩东北侧。在台风浪的冲击之下,沙滩状态朝更消散的方向发展,滩面沉积物粒径变粗、分选性变差。     

深圳湾海域表层和柱样沉积物中的重金属分布特征

分析深圳湾表层沉积物中锌、铬、镉、镍、铅、铜等6种重金属元素的含量发现它们的浓度均值已全部超过广东省海岸带沉积物背景值。根据潜在生态危害法,在6种重金属中镉造成的污染最严重,从潜在的生态危害指数评价看镉的含量已达到很高的污染水平。从面状分布看,重金属污染危害指数值在深圳河口区最低,在蛇口段居中等水平,在深圳湾内侧的近岸水域最大。柱样沉积物的浓度变化以1950年为界划分为两部分:1950年以来的现代沉积物中有较强的人类活动干扰痕迹,表现为重金属元素的浓度增长幅度大,且浓度很高,其均值全部大于广东省海岸带的背景值;1950年以前的近代沉积物中有稍弱的人类活动干扰痕迹。研究认为沉积物粒度特征、沉积速率、人类活动与重金属在沉积物中的浓度高低有直接相关关系,并直接影响到重金属在沉积物中的污染水平。     

Heavy metals,polycyclic aromatic hydrocarbons and organochlorine pesticides in the surface sediments of mangrove swamps from coastal sites along the Leizhou Peninsula, South China

Contents of heavy metals, polycyclic aromatic hydrocarbons （PA Hs）, dichlorodiphenyltrichloroethanes （DDTs） and hexachlorcy- clohexanes （HCHs） in surface sediments from mangrove areas of the Leizhou Peninsula were analyzed in July and November 2005. Risk assessment criteria applied by Long E R et al. （1995） and Long E D et al. （1995） （effects range low, ERL; effects range mean, ERM） of chemicals in sediments from the gulf or estuary were used to assess the potential ecological risks of heavy metals, PAHs, DDTs and HCHs to aquatic organisms in the studied area. The results indicated that the average contents of zinc, nickel, chromium, lead, copper, arsenic and mercury were （61.97 ± 55.87）, （59.99 ± 39.01 ）, （47.93 ± 28.37）, （26.64± 13.00） , （23.45 ± 41.96）, （9.32 ± 3.62）, （0.14 ± 0.18） mg/kg in dry weight in the sediment samples col- lected from five studied sites in the Leizhou Peninsula, respectively. Cadmium was not calculated due to its content being below the detection limit （ 〈 0.3 mg,/kg）. The average levels of Cr, Cu, Ni, Pb, Zn and Hg exceed their background values. The average contents of Ni were higher than ERM. The contents of PAHs in the sediments from the five studied sites were （79.78 ± 43.70） ng/g in dry weight, far lower than ERL（4 022 ng/g）. The contents of DDE, DDD and DDTs in the sediments from five studied sites were （2.60 ± 4.68）, （ 17.52 ± 27.25 ）, （27.78 ± 46.64） ng/g in dry weight respectively, clearly higher than ERL, and the average contents of DDT were （7.66 ± 15.93） ng/g in dry weight, much higher than ERM. HCHs could be detected in the sediments only from Gaoqiao sampling site, with the average contents （0.07 ± 0.08） ng/g in dry weight.     

Water, organic matter, nitrogen and phosphorus contents in sediment of a large-scale mariculture area in the Zhelin Bay of eastern Guangdong Province, China

The Zhelin Bay is one of the most important bays for large-scale mariculture in Guangdong Province, China. Owing to the increasing human population and the expanding mariculture in the last two decades, the ecological environment has greatly changed with frequent harmful algal blooms. A monthly survey of water content, organic matter （TOM）, and various forms of nitrogen and phosphorous in sediment from July 2002 to July 2003 in the bay was conducted. The results showed that the water content was correlated significantly with TOM and various forms of nitrogen and phosphorus and can be used as proxy for quick and rough estimate of these factors in the future surveys. TOM was also correlated significantly with various forms of nitrogen and phosphorus, indicating that it was one of the key factors affecting the concentrations and distributions of nitrogen and phosphorus in the investigated waters. Average total Kjeldhal nitrogen （TkN） content was（ 1 113.1 ± 382.5）μg/g and average total phosphorus （TP） content was（567.2± 223.3）μg/g, and both were much higher than those of similar estuaries in China and elsewhere. Average nitrogen and phosphorus tended to be higher inside than outside the bay, higher at aquaculture than non-aquaculture areas, and higher at fish-cage culture than oyster culture areas, suggesting that large-scale mariculture inside the bay played an important role in the eutrophication of the Zhelin Bay. Various forms of nitrogen and phosphorus concentrations were higher during the warm season （July--September）, which was due to the increased decomposition and concentration of organic matter resulted from the fast growth and high mortality of the cultured species. Compared with July 2002, TkN and TP contents were much higher in July 2003, in consonance with the eutrophication of the Zhelin Bay. Because exchangeable phosphorus （Ex-P）, iron-bounded phos- phorus （Fe-P） and organic phosphorus （OP） combined accounted for 34.3% of the TP and authigenic phosphorus （Au-P     

天然气水合物的声学探测模拟实验

在人工岩心中进行天然气水合物的生成和分解实验,同时获取了体系的温度、压力、声学特性(Vp和Vs、幅度和频率)及含水量等参数。经研究发现,温压法、超声探测法和TDR探测法都能灵敏探测沉积物中天然气水合物的形成和分解过程。分析认为,本次实验中水合物形成速率过快,只能宏观研究水合物对沉积物声学特性的影响,建议采用长岩心进一步研究沉积物中水合物的声学特性。     

三沙湾重矿物研究

三沙湾表层沉积物极细砂中的重矿物不下82种,除少量自生矿物外几乎全是陆源矿物,多数矿物含量变化很大.在岩性和潮流控制下,共形成了12区重矿物组合.     

南汇东滩沉积物粒度特征及其与水动力的关系

沉积物粒度参数可以用来反演沉积物沉积的水动力条件和沉积环境。根据对南汇边滩采集的表层沉积物粒度资料进行分析,结果表明:沉积物类型以黏土质粉砂为主;随着沉积物平均粒径Mz的减小,分选逐渐变好,偏态由极正偏向正偏转变,并向近对称接近。运用Pe- jurp的三角图式对沉积环境进行划分,结果表明南汇东滩的水动力条件总体上较强,沉积物粒径总体上偏粗,属于径流—潮流共同作用的河口浅滩沉积环境。对潮流底应力和沉积物临界起动切应力的计算进一步印证了该区水动力较强,对应沉积物颗粒偏粗的现象。