地幔不均一性与地幔循环的多维表征和原因思考

地幔早先经核- 幔- 壳分异形成,后受不同尺度对流和循环的影响,因而具有不均一性特征。近三十年来,地幔化学通过研究大洋玄武岩发现了多样地幔端元和非放射性同位素证据并证明了地幔不均一性,逐渐建全了地幔地球化学体系。然而,地幔不均一性如何对应于时空尺度的地幔循环,以及地球演化如何影响地幔不均一性等,仍不清楚。此外,地球物理研究显示,岩石圈厚度差异、中下地幔的波速异常体以及俯冲板片形态的观测为纵横向对流系统提供了空间不均一性证据支持。联合地球化学和地球物理手段对研究地幔不均一性至关重要,用好透视地幔成分与结构的“双目镜”已成为共识。本文从地幔不均一性结合地球化学场、地球物理的不同表现形式,以及现今及历史时期的洋陆格局的对比,多维度联系地幔循环和演化,思考了超大陆旋回与地幔不均一化的内在逻辑。强调了从全球演化角度看地幔不均一性的重要性和提出多手段联合建立地幔循环驱动模型的展望。     

内蒙古地区四季和年降水量趋势分析

利用1970—2019年内蒙古地区110个国家站降水量资料,采用经验正交函数(EOF）分析、重标极差分析(R/S)和非周期循环分析,统计四季和年降水量时间序列的Hurst指数(H)、分维数(D)和非周期循环的平均循环长度,分析降水量变化趋势和记忆周期。结果表明：(1)内蒙古地区年降水量变化呈增多趋势,其中在东部的偏东地区增多最显著,变化趋势具有持续性特征,持续时间为8 a,但在内蒙古西部的偏南地区和东部的局地区域年降水量呈减少趋势;(2)春季、秋季和冬季年降水量的年代变化呈增多趋势,夏季呈减少趋势,特别是冬季在东部的偏北地区的个别区域Hurst指数H=1,呈现完全预测特征,降水量未来趋势为增多趋势且通过95%的显著性检验;(3)四季降水量过去的增量与未来的增量都呈正相关,夏季降水量减少趋势的持续性最弱,冬季降水量增多趋势的持续性最强,春季、夏季、秋季和冬季的记忆长度分别为8 a、8 a、9 a和10 a。     

提高矿产资源综合利用效率促进循环经济可持续发展

矿产资源是人类社会赖以生存和发展的重要物质基础,但绝大多数矿产资源是不可再生的耗竭性资源。在我省,90％以上的能源、80％以上的工业原料、70％以上的农业生产资料均来自矿产资源,在当前资源紧缺、环境压力增大的情况下,采取切实有效的措施提高矿产资源综合利用效率,对于经济可持续发展是十分重要的。[第一段]     

壳聚糖及其衍生物在水处理中的应用

壳聚糖(Chitosan)是甲壳素(Chitin)的脱乙酰化产物,本身为线型分子,分子链中含有反应性基团羟基(-OH)和氨基(-NH2)。在酸性溶液中,由于-OH和-NH2的存在,壳聚糖可形成高电荷密度的阳离子聚电解质,能够凝聚溶液中带负电的悬浊液、有机物     

辽宁省海岸带水资源可持续发展模糊迭代分区研究

给出一种模糊聚类循环迭代模型以及通过模糊二元对比赋权与迭代赋权相融合的组合赋权方法,采用交叉循环迭代的方法确定聚类中心矩阵,通过判断聚类准则函数获得最终聚类矩阵.该模型兼顾了主观决策与客观决策,使聚类分析具有很大的柔性,最后将模型应用到辽宁省海岸带30个县(市)区的水资源可持续发展分区研究中,按照水资源可持续发展评价的9个指标分为4个类别,结果表明,模型聚类分区结果比较合理.     

Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

Natural thermoluminescence of fossil foraminiferals as a potential proxy for deep-sea temperature changes

Foraminiferal shells from two piston cores separately located at the Ninetyeast Ridge and the Bengal Fan of the Indian Ocean were selected and purified for measurements of natural thermoluminescence （NTL） intensity by a high precision thermoluminescence meter （RGD-3）. Variations of the NTL intensity along the two core sequences both spanning the last two glacial--interglacial cycles displayed a strong, identical signal of the global ice volume cycles, which matched well with their corresponding oxygen isotope data. As higher NTL intensity occurred within interglacial periods and changes in an NTL signal were most likely influenced by the temperature of ambient seawater in which the planktonic foraminiferal shells long existed, the NTL signal could be considered as a potential proxy for orbital scale temperature changes of bottom seawater in the tropical Indian Ocean.     

Wind impact on pollutant transport in a shallow estuary

A three-dimensional numerical model, EFDC （ environmental fluid dynamics code） is applied to the Pamlico River Estuary （PRE） in eastern North Carolina of the United States to examine the wind impact on pollutant age distributions and residence time. A series of model experiments representing base case, remote-wind-induced water level set-up and local winds cases are conducted. Model results indicate that the pollutant mean age and the system residence time are functions of gravitational circulation in the PRE. The system responses to remote-wind-induced water level set-up are different in different portions of the PRE. Under such condition, dissolved substances in the upstream portion of the PRE have a younger age and shorter residence time （compared with the base case） , by contrast, they have a older age and longer residence time in the downstream portion of the PRE. Upriver and downriver local winds appear to have opposite impacts on pollutant age distributions. The substances are retained much longer within the PRE under upriver wind than those under downriver wind. The model results also suggest that across - river winds may lead to longer residence time through enhanced turbulence mixing, which slows down the gravitational circulation in the PRE.     

热带太平洋次表层三维海温距平场的EOF分析

应用太平洋次表层海温距平资料构造了一个立体的西低东高的四级阶梯模型,使用EOF方法对此模型进行时空分解,重点讨论了分解结果与ENSO循环的关系,并对Nino 3距平指数进行试预报,结果表明,用 EOF分解的第一主分量代表暖池-厄尔尼诺(拉尼娜)模态,第二主分量代表次表层温度距平的东西运移模态,厄尔尼诺事件正是东西运移模态突变的结果.时滞相关分析估算,一次ENSO循环的平均周期约为41个月,厄尔尼诺、拉尼娜模态与温度距平的东西运移模态的位相差平均约为9.7个月.应用逐步回归方法得到超前Nino 3距平指数3、6和12个月的3个预报方程.预报结果表明,第一、第二时间系数对Nino 3距平指数均具有一定的预报价值,预报时效可达1 a左右.     

PVDF管式超滤膜在低渗油田水处理中的研究及应用——以江苏台兴油田为例

根据低渗油田和特低渗油田的特点,研制出PVDF管式超滤膜,开展室内基础研究,并在江苏台兴油田进行中试和大规模的现场试验。经过处理后,水质标准达到油田回注水A1标准（SY／T5329-1994）,满足了低渗油田和特低渗油田的注水要求。