二价铜离子的经验径向波函数及其应用——某些铜络合物和含铜矿物晶场谱的计算

一、问题的提出 J.H.范·佛里克-贝蒂(Van Vleck-Bethe)的晶场理论在物理、化学、矿物学等各个领域中取得了很大的成就。这个理论的特点是:当多电子体系的彻底量子力学计算难于进行时,把某些待算出的量作为由实验确定的经验参量处理,然后根据分子的点群对称性,用群论的方法以较少的参量把实验数据系统化,并且预测某些实验结果。 有人提出是不是可以用某种合理的近似波函从理论上把晶场参量计算出来呢?看来     

粤东塌山含锡花岗斑岩原生铝质矿物特征和成因

粤东塌山含锡花岗斑岩以岩脉产出，侵位年龄１３８Ｍａ，含不等数量的原生铝质矿物，如红柱石、铁铝榴石、铁叶云母和白云母等。根据产出特征，红柱石被区分为两个世代，石榴子石分为三个结晶时期。结合全岩为过铝质（Ａ／ＮＫＣ＝１．２３４），高的Ｋ２Ｏ／Ｎａ２Ｏ（２．１５）、Ｒｂ／Ｓｒ（３．１０）、Ｋ／Ｒｂ（２１５）比和ＩＳｒ值（０．７１３１），低的εＮｄ（Ｔ）值（－７．４）和长石铅同位素组成相似于造山带铅演化模     

Are assemblages of the fireworm Hermodice carunculata enhanced in sediments beneath offshore fish cages?

Abundances of the fireworm Hermodice carunculata were counted through a monitoring assessment study of fish cages in Barranco Hondo（NE Tenerife）. Seven campaigns were conducted from November 2007 to June 2010 and temporal variations were found, as well as differences among sampling stations. The polychaete H. carunculata obtained its highest abundance in sediments beneath fish cages throughout the study period. Thus, the assemblages of this omnivorous species were favoured by the presence of fish cages.     

Distribution Characteristics of Effective Source Rocks and Their Control on Hydrocarbon Accumulation: A Case Study from the Dongying Sag, Eastern China

The exploration conducted in the Bohai Bay basin, eastern China has demonstrated that the abundant petroleum resources have close affinities to the hydrocarbon kitchen with rich organic matter. A number of oil-generating associations with various characteristics of organic geochemistry and assemblages of multiple reservoir facies are developed due to the multi-center sedimentation, multi-source supply and multi-cycle evolution of filling, which have resulted in the formation of multiple oil and gas accumulation zones of various layers and trap styles. Among them the Paleogene Shahejie Formation is the most important hydrocarbon accumulation combination in the Dongying sag. Heretofore, its proved reserve has reached nearly 1.8×109t, which accounts for more than 90% of the total proved reserves of the Dongying sag. Based on previous studies, more than 600 source rock samples and 186 crude oil samples of the Shahejie Formation, collected from 30 oilfields, have been treated with organic geochemical testing     

绿色石化项目邻近海域表层沉积物PAHs分布及年际变化

为评估绿色石化项目运营前后的环境变化,于2018—2021年连续4年对项目所在地鱼山岛邻近海域的表层沉积物多环芳烃(PAHs)进行了调查。结果表明,PAHs含量为16.9～178.0μg·kg^-1,平均值为75.9±24.0～102.6±41.4μg·kg^-1,4年来整体呈下降趋势,与国内其他海区相比,总体含量较低;各组分平均值为4环PAHs>5环PAHs>3环PAHs>6环PAHs>2环PAHs。调查海域表层沉积物以粉砂为主,PAHs的空间分布受到多种因素的综合影响。调查海域PAHs来源相对稳定,年际差异较小,主要来源于石油、木柴、煤炭等燃烧产物的远距离迁移。依据沉积物质量基准法评价,调查海域沉积物PAHs生态风险水平较低。绿色石化项目在建设期及投产期未引起邻近海域沉积物PAHs的增加,但随着项目持续运营,其对周边生态环境的影响需持续关注。     

静水压力取样器冲击头冲击速度的理论与试验研究

介绍了一种用于海底沉积物取样的静水压力取样器,它能依次利用重力势能和静水压力能,将其转换为冲击动能,以冲击形式将取样管插入海底沉积物进行取样。结合既定取样器对其冲击头的冲击速度进行了理论推导,并提出相关经验公式。通过取样器冲击试验,验证了静水压力取样器冲击头冲击速度理论模型的正确性和合理性。在理论推导和实验验证的基础上,对影响取样器冲击头冲击速度三个主要因素进行了探讨,并提出了提高冲击头冲击速度的具体措施。     

南海北部海域表层沉积物底栖有孔虫分布特征及影响因素

有孔虫在海洋环境指示方面具有重要意义,对现代环境中有孔虫的分布及影响因素进行研究有助于利用有孔虫对地质历史时期的沉积环境进行还原。我国南海海域辽阔,南海有孔虫的相关研究很早便有报道。对我国南海北部海域表层沉积物中的底栖有孔虫分布特征进行了描述,研究区以玻璃质壳底栖有孔虫占主导,胶结壳其次,瓷质壳最少。根据底栖有孔虫的分布特征划分了4个底栖有孔虫组合,组合1为Heterolepa subpraecincta - Hanzawaia mantaensis - Rotalinoides gaimardii;组合2为Bulimina marginate - Lagena substriata;组合3为Elphidium advenum - Pararotalia nipponica;组合4 为Recurvoides contortus - Ammodisus cretaceous - Bulimina aculeata。对影响该区域底栖有孔虫分布的环境因素进行了探究,结果表明,温度、盐度、底质类型等对底栖有孔虫的分布均存在一定程度的影响,海流对研究区底栖有孔虫时空分布的影响值得进一步探究。