2004欧洲X射线光谱分析会议

介绍了2004欧洲X射线光谱分析会议的简况和会议所讨论的热点问题。利用聚合毛细管X射线透镜进行微区分析是近期X射线领域最受关注的热点。     

论非均匀断层滑动弱化速率的标定

尝试用二维断层模型来描述断层在不稳定开始时滑动弱化速率的定标律。断层由一系列受滑动摩擦力作用变弱的片区组成，这些片区被牢固的障碍体所分隔。第一组断层包含不同尺度总滑动长度相同的片区的平均分布，而第二组断层由各种分形康托尔集合组成。破裂的整体活动性质由指数增长率λ来描述。对无限均匀的断层，系数λ由摩擦定律的弱化速率控制。在非均匀断层系中我们估算每一个断层的弱化速率，因为一个断层系的指数增长率λ与均匀断层是一致的。利用这种均匀断层的破裂过程，我们根据不同尺度均匀性断层和给定的系数λ来计算弱片区上的弱化速率。对于大尺度的破裂，弱化速率与尺度无关，长片区的开始过程类似于无限断层的破裂情况。本文考虑的是小尺度和所有不同几何形状的破裂，弱化速率记为α=β0^*／a，其中a为破裂尺度或者单个断层长度的一半，β0^*≈1．158。本文计算了滑动弱化距离Dc的值，在此基础上讨论了计算结果的物理含义，并给出了这个参数与尺度相关的可能解释。     

Application of the Wavelet Packet Method in Discrimination Between Nuclear Explosion and Earthquake

Although the CTBT (Comprehensive Nuclear Test-Ban Treaty) was passed in 1996, it is still necessary to develop new and highly efficient methods (Wu Zhongliang, Chen Yuntai, et al.,1993 ; Xu Shaoxie, et al. 1994; Richard L. Garwin, 1994) to monitor possible events. Many discrimination criteria (Xu Shaoxie, et al., 1994 ; Institute of Geophysics, Chinese Academy of Sciences, 1976; Richard L. Garwin, 1994) have been put forward since the 1950s. The results show that each of the existing criteria has its own limitation, but the seismological method is an important and efficient method in the discrimination between nuclear explosion and earthquake. Especially in recent years, because of the little and little equivalent as well as the increasing hiding steps used in the test, a number of more efficient seismological methods have been worked out. In this paper, a new discrimination method, the Wavelet Packet Component Ratio (WPCR) method, is put forward. This method makes full use of the difference in variation with time between the spectra of nuclear explosions and earthquakes. Its discrimination efficiency is rather high.     

高倍稀释熔融制样X射线荧光光谱测定钨砂和铬铁矿中主含量

用X射线荧光光谱测定钨砂中WO3和铬铁矿中Cr2O3,通过高倍稀释熔融玻璃片制样法,采用高纯WO3或Cr2O3作单一标准样测量X射线荧光强度计数,然后同未知样品测量所得X射线荧光强度计数相比,即可计算出WO3和Cr2O3的测量值.方法用于钨砂矿和铬铁矿中WO3和Cr2O3的测定,结果与标准值相符.     

峨嵋玄武岩流体包裹体中铂钯的测定方法研究

峨嵋玄武岩同生流体包裹体在800℃爆裂后，2．0g／L NH4Cl溶液提取流体中Pt、Pd，C-410树脂富集-电感耦合等离子体质谱测定，方法相对误差小于25％。激光拉曼光谱与四级质谱测定包裹体的气液成分结果表明：流体中存在一定量的有机组分，这对Pt、Pd以有机螯合态形式进入流体提供了可能。     

偏振激发能量色散X荧光法在地球化学分析中应用及其与波长色散X荧光法的比较

偏振激发能量色散X射线荧光光谱(P-EDXRF)技术是20世纪末出现的新分析技术。国内采用X-Lab2000型仪器的初步研究表明，在总计数时间为600秒时，可以对近30种元素进行定量，检出限为0．5-30μg／g，与国际上发表的文献值基本一致。本工作通过约100个实际样品分析，并与波长色散X射线荧光法(WDXRF)分析结果的比较，对P-EDXRF的分析性能进行了评价。与WDXRF相比，P-EDXRF法具有分析速度快、设备购置费用低、运行成本低、全谱同时采集(有利于发现元素含量异常)等优点，因此特别适合地球化学填图样品的快速分析。而WDXRF在精度要求较高的分析中更具竞争力。     

“Three-Component” Digital Prospecting Method：A New Approach for Mineral Resources Quantitative Prediction and Assessment

“Three-component” method consists of three clase-connected aspects: geological anomaly,diversity of mineralization and mineral deposit spectrum. All these three concepts are not new separately, but it is a new approach to combine these three aspects in one single concept for quantitative mineral resources prediction and assessment and it is also the first time to conduct a more detailed study in each aspect. Investigation and clarification of geological anomalies, diversity of mineralization and spectrum of mineral deposits are realized by digitization and quantification of ore forming controlling factors, oreexisting symbols or marks, characteristics of mineralization and regulation of ore-genesis and laws of distribution. These procedures lead to construction of a “digital model“ for mineral resources prediction andassessment.     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

IMD法在多光谱图像分类中的应用

数学形态学着重于分析和处理图像的几何结构信息。根据这一原理，在图像分类预处理过程中，对各种地物区域的几何结构特点进行分析，构造相应的结构元素，然后对图像进行形态迭代分解法(IMD，Iterative Morphological Decompostion)变换。在变换结果中，地物区域的灰度信息进行了归一化处理，同时区域的几何结构特点和独立地物得到了有效保留。将多光谱图像的IMD变换结果进行分类实验的结果表明，该方法可以有效提高多光谱图像分类的精度和效率，具有较强的适用性。     

基于光谱空间密度分析的边缘提取

针对传统的边缘提取方法大部分不适应高光谱数据的特点，提出了基于光谱空间密度分析边缘提取的思想。在分组主分量变换提取第一主分量作为特征维的基础上，采用面向对象的二次判别边缘的方法，通过立体判决将光谱空间中低密度超椭球体集群视为真实边缘点集群。试验表明，此方法是合理可行的。