二氧化碳生物地球化学循环研究的进展

综述了对二氧化碳生物地球化学循环的研究现状，着重介绍了大气二氧化碳的源和汇的研究资料，并简要介绍了有关碳循环模式。     

高温地热生产井碳酸钙结垢定量评价：两相流动——以西藏羊八井为例

高温地热生产井碳酸钙结垢定量评价涉及到复杂的物理和化学过程,其中井筒中的两相流研究是评价的基础.本文首先基于质量守恒、能量守恒和动量守恒方程,建立了CO₂-H₂O体系井筒两相相变稳定流动模型,提出了稳健的求解方法,并验证了其计算结果的可靠性.然后,在西藏羊八井地热田典型井开展了静止和放喷状态下的井筒中的温度和压力测试,并结合放喷试验,采用开发的模型成功评价了高温地热生产井筒两相流动过程.结果显示：气相和液相之间的速度差对井筒中温度和压力的分布有决定性的影响,不考虑气相和液体之间的速度差,会使模型计算结果远远偏离测量值.在开采速率19.10 kg/s的条件下,计算的井口温度和压力分别约为128℃和2.6 bar;井口的气相质量分数在6%～7%之间,对应的井口气相饱和度约为0.84;从闪蒸点往上大概20～30 m气相和液相中CO₂质量分数变化较为剧烈,也是碳酸钙结垢严重井段.     

土壤中的CO2及其对岩溶作用的驱动

作者以桂林岩溶试验场和陕西鱼洞河两个观测站为例,分析了我国南、北方土壤ＣＯ２的动态、差异及其对岩溶作用的驱动规律,进一步结合气候条件（气温、降水）等的分析,揭示了南、北方岩溶发育差异的根源。     

二氧化碳洗井中相关问题的探讨

二氧化碳洗井方法具有设备简单、用时少,效果好的特点,但随着钻孔深度和孔径加大,井管材料的更新换代,有时也会难以出现壮观的井喷场面,达不到理想的洗井效果,使用范围受到限制的问题。总结多年的洗井经验,依据二氧化碳洗井原理,运用洗井过程中起动压力和用气量的计算公式,进而对洗井深度和影响用气量的因素进行了分析,结果表明:1该方法比较适用于井深300m左右、孔径Φ325mm以内、泥浆相对密度小于1.1g/cm3的新打水井,对大于300m的深井,可采用分层洗井法或压风机引喷法进行洗井。2井喷形成时的二氧化碳气体用量,与瓶内气体的压力、钻杆的下入深度、环空体积、地面管路的长度与直径、钻杆内径、钻井液的密度等成正比,而与水温、气温等成反比;当井的含水层的水柱高度低于70m时,一般不易形成井喷。3二氧化碳洗井适用于井内下入钢管、铸铁管等抗压强度较高的井。对水泥管、塑料管等强度较低的井管则要视情况具体分析。     

基性、超基性岩: 二氧化碳地质封存的新途径

CO₂地质封存是控制全球CO₂净排放量的有效手段.自然界存在大量基性、超基性岩石的碳酸盐风化作用, 与CO₂反应生成稳定的碳酸盐矿物.影响基性、超基性岩石与CO₂反应速率的因素有温度、压力、pH值、流体流动速率以及与矿物接触的表面积等.矿物在反应过程中放热可以使碳酸盐化体系进入自我加热的良性循环, 同时控制流体的流动速率可以保持最佳温度并使反应速率最大化.蛇绿岩中的橄榄岩、大陆玄武岩和深海玄武岩在地球表层广泛分布, 可贮存大量CO₂.目前研究表明此方法在技术上可行, 经济成本上有优势.因此, 基性、超基性岩石具有封存CO₂的巨大潜力, 可以作为地质封存CO₂的新途径.      

Research on fluid inclusions of the Yinshan polymetallic deposit, Jiangxi Province, China

In this paper some new advances in the study of fluid inclusions of the Yinshan deposit in Jiangxi Province,China,are presented.The fluid inclusions of the deposit can be divided into four types:1) gas-rich inclusions;2)liquid-rich inclusions;3)salt-saturated H2O inclusions;and 4)single-phase or multiphase CO2-rich inclusions.Homogenization temperatures of the fluid inclusions range from 100 to 520℃,aminly in the range 120-400℃.The daughter crystal-bearing multiphase inclusions present in quartz porphyries(including Nos.13 and 4 dikes)have been observed.In ore veins,some daughter crystal-bearing multiphase inclusions have been observed.too.On the basis of the results of fluid inclusion research,the authors suggest that the ore-forming fluid must have a close genetic relation to magmatic hydrothermal solution.The ore-forming fluid was dominantly originated from the depth and the mixing of magmatic solution with meteoric water was enhanced during ascending of the fluid,accompanying immiscibility and boiling of fluid.Teher may be a conceales igneous body at the depth of the Yinshan deposity,which furnishes the scientific basis for metallogenic prognosis at th depth of the Yinshan deposit.     

Experimental Study on Hydrocarbon Formation Due to Reactions Between Carbonates and Water or Water—Bearing Minerals in Deep Earth

In order to investigate the mechanism of formation of abiogenetic hydrocarbons at the depth of the Earth,experimental research on reactions between carbonates and water or waterbearing minerals was carried out at the pressure of about 1GPa and the temperature range of 800-1500℃.The reactions took place in an open and nonequilibrium state.Chromatographic analyses of the gas products indicate that in the experiments there were generated CH4-dominated hydrocarbons,along with some CO2 and CO.Accordingly,we think there is no essential distinction between free-state water and hydroxy in the minerals in the process of hydrocarbon formation.This study indicates that reactions between carbonates and water or water-bearing minerals should be an important factor leading to the formation of abiogenetic hydrocarbons at the Earth‘s depth.