Evaluating the mobility of137Cs,239+240Pu and210Pb from their distributions in laminated lake sediments

Post-depositional mobility of¹³⁷Cs,^239+240Pu and²¹⁰Pb was assessed in six small lake basins by comparing sedimentary nuclide profiles with their known fallout history. Laminae couplets, when present, were determined to be varves because the¹³⁷Cs and^239+240Pu 1963 fallout peaks are present in laminae couplets corresponding to years 1962–1964. There is no evidence of mobility of²¹⁰Pb, because 1) mass accumulation rates based on²¹⁰Pb agree with those based on¹³⁷Cs and^239+240Pu peak depths and with those based on varve counts, and 2)²¹⁰Pb ages agree with varve ages. Significant mobility of¹³⁷Cs is evident from the penetration of¹³⁷Cs to depths 15–20 cm deeper than^239+240Pu. Deep penetration of¹³⁷Cs in spite of a sharp gradient below the peak is interpreted by a numerical model to suggest that¹³⁷Cs is present in two distinct forms in these sediments, 67–82% as an immobile form and 18–33% reversibly adsorbed with a K _d of approximately 5000. The profiles can be interpreted equally well assuming a small portionof the total¹³⁷Cs was present as an extremely mobile phase (K _d 5000) in the months to years following peak fallout, slowly becoming more strongly adsorbed. High NH ₄ ⁺ concentrations in porewaters may enhance diffusion of the mobile form of¹³⁷Cs, but not of the immobile form of¹³⁷Cs that defines the sharp gradient. Mobility of¹³⁷Cs is likely also enhanced by the low clay content and the high porosity of these sediments. Thus the first detection of¹³⁷Cs in the sediments cannot automatically be assumed to correspond to a date of 1952 (initial testing of thermonuclear weapons), although the depth of the peak can be assumed to correspond to 1963 (the year of maximum fallout from testing of thermonuclear weapons).^239+240Pu is a more reliable sediment chronometer than¹³⁷Cs because it is significantly less mobile.This is the sixth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P.G. Appleby is guest editing this series.     

WORLD DELTAS AND THEIR EVOLUTION

In August 1998, an international symposium on the world deltas was held in New Orleans, Louisiana, USA. This symposium attracted discussion about more than 25 deltas from around the world with emphasis placed on those that are most densely populated and impacted by humans. Keynote papers printed details about the physical, biological, engineering and socioeconomic aspects of six deltas including the Mississippi, Nile, Ganges-Brahmaputra, Rhine-Meuse, Changjiang and Po. The main purpose of this symposium was to inform scientists, engineers and decision-makers about information that is currently available and to provide them a basis for working in such environments.     

How reliable is the210Pb dating method? Old and new results from Switzerland

We present a historical overview of applications of²¹⁰Pb dating in Switzerland with a special emphasis on the work performed at the University of Bern. It is demonstrated that the average specific activity of²¹⁰Pb in the lower atmosphere is very constant and does not show seasonal variations. We then concentrate on new results from Lobsigensee, a very small lake, and on published and new data from Lake Zurich. Several²¹⁰Pb profiles from these lakes show obvious disturbances and a disagreement of the resulting sedimentation rate when compared to that for the 23 years defined by¹³⁷Cs peaks of 1986 (Chernobyl) and 1963 (bomb fallout).A mean sedimentation rate of about 0.14 g cm^–2 y^–1 is found in the oxic and suboxic center part of Lake Zurich. In the oxic locations, the²¹⁰Pb flux to the sediments was close to the atmospheric input of about 1/60 Bq cm^–2 y^–1. In other parts of the lake a significant deficit in the inventory of²¹⁰Pb was found in the sediments. This could be due to a chemical redissolution of²¹⁰Pb together with Mn under reducing conditions. In contrast, in the suboxic part of the lake (135 m depth) the flux of²¹⁰Pb was about twice the atmospheric input. This excess is not caused by allochthonous contributions and is tentatively explained by the transport of sediment material resulting from small slides at the very steep lake shores or more probably by reprecipitation of²¹⁰Pb together with Mn when the conditions in the lake water become locally and seasonally more oxidizing. Dissolved²¹⁰Pb may migrate from locations with reducing conditions and reprecipitate under more oxic conditions. Indeed, a correlation of Mn and²¹⁰Pb in sediments of Lake Zurich was found.This is the first of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Meteorological Observations 2002 at the Arctic Station,Qeqertarsuaq (69°15'N), Central West Greenland

An automatic meteorological station has been operating at the Arctic Station (69°15'N, 53°31'W) in West Greenland since 1990. This paper summarises meteorological parameters during 2002, including snow cover, ground temperatures and active layer development, and air temperatures at the Station during the last 12 years are compared to large scale trends during the last century.

A compilation of 93 sedimentation rate determinations based on ²¹⁰Pb dating has been carried out for the North Sea-Baltic Sea transition area from a database containing 165 determinations carried out by Danish institutions. In the depositional parts of the area sedimentation rates generally range 25–6403 g m^?2 y^?1. An extreme rate of 13351 g m^?2 y^?1 is observed on a station in the Skagerrak. Sedimentation rates significantly increase with depth indicating that the Skagerrak and northern parts of the Kattegat as well as the deep basins in the Baltic Sea act as depocentres for fine-grained sediments. Apparently, sedimentation rates have increased in recent years.     

Distribution coefficients of210Pb and210Po in laboratory and natural aquatic systems

We have measured the distribution coefficient (Kd) of²¹⁰Po and²¹⁰Pb in laboratory systems and in natural freshwater systems. In the laboratory systems, an inverse relationship was observed between the particle concentration of sand or lake sediment, and the distribution coefficients of²¹⁰Po and²¹⁰Pb. The slope of the log-linearK _d vs particle concentration relation is consistent with existingK _d-particle concentration theories. These laboratory observations are consistent with similar measurements in two lakes. TheK _d values of Po and Pb for the bottom sediment-pore water system with a high particle concentration were 10 to 100 times lower than those for dilute concentrations of particles suspended in the lake water. TheK _d of²¹⁰Pb in the sediments was >10⁴ so that the diffusive transport of²¹⁰Pb has only a small influence on the interpretation of²¹⁰Pb concentration-depth profiles and the²¹⁰Pb dating of these sediments.This is the second of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing.     

Sedimentation rates in the Wanggang salt marshes, Jiangsu

1 IntroductionLand-ocean interaction in coastalzone is one of the key m atters of the International G eosphereand Biosphere Program (IG BP). The key problem s of the second phase in the next decadeinclude the m aterial cycle, the system evolution process …     

Drainage ditch erosion history as recorded in the varved sediment of a small lake in East Finland

Short core stratigraphy of total N, P, Zn, Hg and diatoms were investigated in the varved sediment of Lake Heinälampi, a small 8 m deep pond in East Finland. The sediment has recently changed from organic mud to minerogenic silt. The presence of varved sediment offers independent control for ²¹⁰Pb and ¹³⁷Cs dates and these are in good agreement: the sediment quality initially changed around the year 1930 due to increaed field erosion, and the inflow of mineral matter was further increased by ditching of paludified forests in 1980.Diatom analysis reveals that eutrophication has occurred before and concurrent with the sedimentary change. The causes of eutrophication and the increased levels of Zn and Hg are discussed.     

Magnetic properties of recent sediments in Lake Baikal, Siberia

Mineral magnetic measurements of six ²¹⁰Pb-dated surface cores from different basins of Lake Baikal, Siberia, show temporal records controlled by a range of internal and external processes. With the exception of sediments on the Academician Ridge, there is clear evidence for widespread reductive diagenesis effects on the ferrimagnetic component coupled with neo-formation of paramagnetic iron minerals. Greigite formation, bacterial magnetosome accumulation and turbidite layers may affect the properties of some sediment levels. Concentrations of canted antiferromagnetic minerals (eg. haematite) appear to increase from the 19th century onwards. These minerals are less affected by dissolution processes and probably represent detrital minerals delivered by catchment fluvial processes. The magnetic evidence for recent atmospheric pollution by fossil-fuel combustion processes is weak in all the cores, and supports the findings from studies of spherical carbonaceous particles (SCPs) and heavy metals that pollution is largely restricted to the southern basin. Correlations between recent sediments based on magnetic data may be insecure over long distances or between basins.     

Distribution of As, Cr and V species in the Po-Adriatic mixing area, (Italy)

The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.     

Pb and Th in settling particles in the western Northwest Pacific Ocean: Particle flux and scavenging

A mooring of three conical time-series sediment traps was deployed at two sites in the western Northwest Pacific Ocean for 9 months. Total mass fluxes and activities of ²¹⁰Pb and ²³⁰Th were determined for the settling particles to elucidate their scavenging and transport processes. Sediment samples also were analyzed for ²¹⁰Pb activities. Total mass fluxes, ²¹⁰Pb fluxes and ²³⁰Th fluxes showed large seasonal variations and their weighted mean fluxes tended to increase with depth, with an especially large increase near-bottom. The ratios of the observed ²¹⁰Pb fluxes to the ²¹⁰Pb deficiency fluxes in the upper traps at the two sites were only 0.02 and 0.12, and were attributable to advective export of ²¹⁰Pb from the surface waters. Those ratios in the near-bottom traps ranged between 1.22 and 2.63. This suggests that these high ratios are due to effective particle scavenging, large lateral ²¹⁰Pb import and input of resuspended particles that have not become incorporated into the sediments. The mean total ²³⁰Th fluxes at the near-bottom traps were 4.2–6.7 times higher than that expected from production in the overlying water column. The ²¹⁰Pb activities in the surficial sediments were much lower than those in the near-bottom traps. The ²¹⁰Pb accumulation rates estimated from the excess ²¹⁰Pb inventory in the sediment column were 40–70% higher than the mean ²¹⁰Pb fluxes at the near-bottom traps. The ratios of the ²¹⁰Pb accumulation rates to the ²¹⁰Pb deficiency fluxes at the near-bottom traps ranged between 2.0 and 3.7. The high fluxes of particulate ²¹⁰Pb and ²³⁰Th at the near-bottom traps reflected a combination of enhanced scavenging of dissolved nuclides and the lateral redistribution of particulate matter by downslope and alongshore transports. However, it was not possible to discriminate among the various processes contributing to high nuclide fluxes.