Intercomparison of measurements of stratospheric hydrogen fluoride

Observations of the vertical profile of hydrogen fluoride (HF) vapor in the stratosphere and of the vertical column amounts of HF above certain altitudes were made using a variety of spectroscopic instruments in the 1982 and 1983 Balloon Intercomparison Campaigns. Both emission instruments working in the far infrared spectral region and absorption instruments using solar occultation in the 2.5m region were employed. No systematic differences were seen in results from the two spectral regions. A mean profile from 20–45 km is presented, with uncertainties ranging from 20% to 50%. Total columns measured from ground and from 12 km are consistent with the profile if the mixing ratio for HF is small in the tropophere and low stratosphere.     

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.     

微山湖流域高氟地下水的成因分析

依据2006—2016年间采集的区内475件地下水无机分析数据以及钻探岩心易溶盐测试数据,详细研究了微山湖流域高氟地下水的分布特征和富集机制。结果表明:微山湖流域高氟地下水的分布有明显的东西分区特征,湖西冲积、湖积平原区有大范围的高氟地下水,在深度0—40 m的浅层孔隙地下水中,氟含量以1~2 mg/L为主,仅现代黄河影响带地下水氟含量小于1 mg/L,金乡、单县、嘉祥局部超过3 mg/L,最大值9.5 mg/L;在深度150—400 m的深层孔隙地下水中,氟含量以1~1.5 mg/L为主,菏泽—单县条带氟含量超过2 mg/L,最大值3.5 mg/L。微山湖东冲积、洪积平原浅层孔隙地下水、深层岩溶地下水氟含量均小于1 mg/L。湖西冲积、湖积平原沉积物中可溶性氟含量随深度增加而降低。微山湖流域湖西高氟地下水形成受物质来源、淋滤和蒸发浓缩等三方面因素共同控制,CaF_2的溶解平衡是控制地下水F–含量的重要因素。     

Fluoride enrichment in aquifers of the Thar Desert: controlling factors and its geochemical modelling

The groundwater is the only source of drinking water in the Jaisalmer district of Rajasthan, India. The study area is a part of the Thar Desert. It has low and scattered population and no industries; hence, the possibility of anthropogenic input of fluoride is almost negligible. Thus, the enrichment of fluoride is only possible due to geochemical processes taking place in the groundwater of the region. A total of 100 groundwater samples, 34 samples from Jaisalmer and 66 samples from the Pokharan administrative blocks, were collected. It was observed that the concentration of fluoride ranged from 0.08 mg/l to 4.56 mg/l in the groundwater of Jaisalmer and from 0.56 mg/l to 6.60 mg/l in the samples of the Pokharan block. The alkaline condition (average pH, 7.7 ± 0.22 and 8.01 ± 0.25 in Jaisalmer and the Pokharan administrative block, respectively) in the region favours fluorite dissolution. Ion exchange, dissolution of calcite, semi‐arid climate, alkaline conditions and weathering are responsible for fluoride enrichment in the groundwater of the study area. Copyright © 2012 John Wiley & Sons, Ltd.     

钨、锡流-熔分配实验结果及其矿床成因意义

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。     

离子色谱法测定五氧化二铌和五氧化二钽中痕量氟氯和硫酸根离子的前处理方法

采用马弗炉将样品与NaOH混合进行熔融煅烧，热去离子水提取、离心、稀释后过OnGuard Ⅱ H柱和过滤膜进行前处理，抑制型电导离子色谱法检测，测定了Ta2O5和Nb2O5的氟离子、氯离子和硫酸根离子。该方法对三种被测阴离子的检测限（s／N=3）在0．15～0．70μg／g（以固体样品实际浓度计）或0．136～0．623μg／L（以溶液浓度计），标准曲线线性范围均在两个数量级以上，方法的精密度（RSD，n=7）小于5．46％，回收率为88％～106％，具有灵敏度高、选择性好、重现性佳、对环境友好等特点，用于实际样品的检测，结果令人满意。     

南大洋氟的生物地球化学研究——Ⅰ.南极磷虾富氟异常的研究

本文通过对南极磷虾不同部位中氟含量的测定,结合氟在测区环境中的分布特征及南极磷虾体中其它元素的分析资料,讨论了氟在磷虾体内的分布和赋存形式,并对其可能的富集机理及与环境的关系作了初步的探讨。     

内蒙古河套平原浅层高铁高氟地下水分布与成因

为了查明内蒙古河套平原高铁高氟地下水的分布与形成原因,通过实地调查、监测、资料分析和试验测试等方法手段,详细研究了地下水中铁、氟的分布、地球化学特征及其来源。结果表明:高铁水主要分布在平原中部的冲湖积平原,地势低洼和地下水的排泄地带含量最高;高氟水主要以条带状分布在山前的冲洪积扇地带;在调查研究区12510.83 km2的范围内,深度在10~40 m的浅层地下水中,分布有高铁水9310.66 km2,高氟水2308.35 km2,分别占调查研究区总面积的74.40%和18.45%;研究认为,河套平原高铁高氟地下水的形成主要是由自然地质环境所致,是不同地质环境条件下环境水文地球化学作用的结果;地下水中的铁主要来源于由黄河携带来的大量的第四系沉积物,而溶出的主要原因是地下氧化还原条件的变化;地下水中的氟主要来源于平原周边的山区,气候、地质构造、水文地质和水化学条件是氟富集的主要因素;研究表明河套平原高铁水与高氟水不存在正相关关系。