U–Pb dating of the end of the Pan-African orogeny in the Tuareg shield: the post-collisional syn-shear Tioueine pluton (Western Hoggar, Algeria)

The Tioueine pluton intrudes the Neoproterozoic series of the Iskel terrane, located in the Tuareg shield, western Hoggar. The consistency of the internal structures as well as the nature and organization of the associated microstructures demonstrate that the Tioueine pluton was emplaced syn-kinematically while N–S strike–slip shear zones were active. The syn-tectonic emplacement of the Tioueine massif implies that this pluton, although belatedly crystallized, entirely belongs to the concept of post-collisional magmatism. In order to date precisely the late Pan-African tectono-metamorphic event in the studied area, an U–Pb age of 523±1 Ma was obtained from abraded zircons of a late quartz–syenite from the Tioueine pluton. This early Cambrian age is younger than the other plutons of the Tuareg shield, which were mainly emplaced between 630 Ma and 580 Ma. This dating also shows that the Tuareg shield was not a single coherent block at 525 Ma, but rather an amalgam of active terranes moving each other along major shear zones. Finally, the Tioueine massif represents probably the final welding of the Tuareg shield assembly of terranes and consequently the end of the post-collisional orogenic episode in the whole Pan-African belt.     

浙江景宁鹤溪群斜长角闪岩变质新生锆石特征、离子探针(SHRIMP)U-Pb年龄及地质意义

景宁鹤溪群斜长角闪岩变质新生锆石特征是粒度均匀（约70μm）,晶体结晶和透明度极好,色调一致的淡粉红色,呈金刚光泽．未见裂隙、表面熔蚀、环带和核心构造。离子探针质谱GHRIMPⅡ）的206Pb／238U、207Pb／235U两组年龄在误差范围内基本谐和,206Pb／238U年龄的加权平均值（252±5Ma）为变质新生铁石的结晶年龄。锆石的精确定年（252±5Ma）为丽水—余姚断裂以东地区呈“天窗式”零星出露于中生代火山岩系中的鹤溪群提供了一个变质作用的确切年龄,也为印支运动在丽水—余姚断裂以东地区的存在提供了重要的年代学佐证。     

九江台震级偏差讨论与校正

通过选取大量震例,分析了九江台所产生的震级偏差的可能原因,并提出了校正意见。     

Mantle heat flow and geotherms for major tectonic units in central Europe

The results of seismic measurements along the deep seismic sounding profile VII and terrestrial heat flow measurements used for construction of heat generation models for the crust in the Paleozoic Platform region, the Sudetic Mountains (Variscan Internides) and the European Precambrian Platform show considerable differences in mantle heat flow and temperatures. At the base of the crust variations from 440–510°C in the models of Precambrian Platform to 700–820°C for the Paleozoic Platform and the Variscan Internides (Sudets) are found. These differences are associated with considerable mantle heat flow variations.The calculated models show mantle heat flow of about 8.4–12.6 mW m^–2 for the Precambrian Platform and 31 mW m^–2 to 40.2 mW m^–2 for Paleozoic orogenic areas. The heat flow contribution originating from crustal radioactivity is almost the same for the different tectonic units (from 33.5 mW m^–2 to 37.6 mW m^–2). Considerable physical differences in the lower crust and upper mantle between the Precambrian Platform and the adjacent areas, produced by lateral temperature variations, could be expected. On the basis of carbon ratio data it can be concluded that the Carboniferous paleogeothermal gradient was much lower in the Precambrian Platform area than in the Paleozoic Platform region.     

Delineating runoff processes and critical runoff source areas in a pasture hillslope of the Ozark Highlands

The identification of runoff contributing areas would provide the ideal focal points for water quality monitoring and Best Management Practice (BMP) implementation. The objective of this study was to use a field‐scale approach to delineate critical runoff source areas and to determine the runoff mechanisms in a pasture hillslope of the Ozark Highlands in the USA. Three adjacent hillslope plots located at the Savoy Experimental Watershed, north‐west Arkansas, were bermed to isolate runoff. Each plot was equipped with paired subsurface saturation and surface runoff sensors, shallow groundwater wells, H‐flumes and rain gauges to quantify runoff mechanisms and rainfall characteristics at continuous 5‐minute intervals. The spatial extent of runoff source areas was determined by incorporating sensor data into a geographic information‐based system and performing geostatistical computations (inverse distance weighting method). Results indicate that both infiltration excess runoff and saturation excess runoff mechanisms occur to varying extents (0–58% for infiltration excess and 0–26% for saturation excess) across the plots. Rainfall events that occurred 1–5 January 2005 are used to illustrate the spatial and temporal dynamics of the critical runoff source areas. The methodology presented can serve as a framework upon which critical runoff source areas can be identified and managed for water quality protection in other watersheds. Copyright © 2008 John Wiley & Sons, Ltd.     

Zircon U–Pb age and Hf isotope evidence for contrasting origin of bimodal protoliths for ultrahigh-pressure metamorphic rocks from the Chinese Continental Scientific Drilling project

A combined study of zircon morphology, U–Pb ages and Hf isotopes as well as whole‐rock major and trace elements was carried out for ultrahigh‐pressure (UHP) eclogite and felsic gneiss from the main hole (MH) of the Chinese Continental Scientific Drilling (CCSD) project in the Sulu orogen. The results show contrasting Hf isotope compositions for bimodal UHP metaigneous rocks, pointing to contrasting origins for their protoliths (thus dual‐bimodal compositions). The samples of interest were from two continuous core segments from CCSD MH at depths of 734.21–737.16 m (I) and 929.67–932.86 m (II) respectively. Zircon U–Pb dating for four samples from the two core segments yields two groups of ages at 784 ± 17 and 222 ± 3 Ma, respectively, corresponding to protolith formation during supercontinental rifting and metamorphic growth during continental collision. Although the Triassic UHP metamorphism significantly reset the zircon U–Pb system of UHP rocks, the Hf isotope compositions of igneous zircon can be used to trace their protolith origin. Contrasting types of initial Hf isotope ratios are, respectively, correlated with segments I and II, regardless of their lithochemistry. The first type shows positive ?_Hf(t) values of 7.8 ± 3.1 to 6.0 ± 3.0, with young Hf model age of 1.03 and 1.11 Ga. The second type exhibits negative ?_Hf(t) values of ?6.9 ± 1.6 to ?9.1 ± 1.1, with old Hf model ages of 2.11 and 2.25 Ga. It appears that the UHP rocks from the two segments have protoliths of contrasting origin. Consistent results are also obtained from their trace element compositions suggesting that mid‐Neoproterozoic protoliths of bimodal UHP metaigneous rocks formed during supercontinental rifting at the northern margin of the South China Block. Thus, the first type of bimodal magmatism formed by rapid reworking of juvenile crust, whereas the second type of bimodal magmatism was principally generated by rift anatexis of Paleoproterozoic crust. Melting of orogenic lithosphere has potential to bring about bimodal magmatism with contrasting origins. Because arc–continent collision zones are the best place to accumulate both juvenile and ancient crusts, the contrasting types of bimodal magmatism are proposed to occur in an arc–continent collision orogen during the supercontinental rifting, in response to the attempted breakup of the supercontinent Rodinia at c. 780 Ma.     

Micro-zircon: origin and evolution during metamorphism

The size and distribution of zircon within a garnet-mica-schist from the Scottish Highlands were assessed using scanning electron microscopy. The study reveals that abundant 0.2–3.0 μm sized zircon is preferentially concentrated within garnet and biotite porphyroblasts. The micro-zircon has grown during regional metamorphism and represents >90% of the total number of zircon in the schist. It is texturally distinct from a few larger detrital zircon grains in the schist that commonly preserve evidence of dissolution, and more rarely, small metamorphic outgrowths. The sequential incorporation of zircon in porphyroblasts allows prograde changes in the morphology of the zircon population to be identified. Zircon is reactive and soluble, and responds to medium-grade metamorphism in a series of dissolution and crystallization events, linked to possible changes in fluid composition. Deformation also has a significant influence on the distribution of zircon, allowing inclusions previously trapped within biotite to react. About 8 × 10⁶ micro-zircon occur as inclusions within a typical individual 5-mm garnet porphyroblast and their presence must be considered prior to trace-element or isotopic analysis of such metamorphic phases.     

Zircon U-Pb geochronology of Early Jurassic-Late cretaceous volcanic rocks in North Yellow Sea BasinEI北大核心CSCD

The X-drilling cores of the North Yellow Sea basin reveal two sets of Mesozoic clastic rocks, which are the dark rocks in lower part and the red rocks in upper part, respectively. There are two layers of volcanic rocks at the bottom and the upper part of the dark rock unit. The volcanic rocks at the bottom part are trachytic dacite while rocks at the upper part are clastic dacite. The zircon grains from the upper and lower units of volcanic rocks are euhedral-subhedral columnar crystals and show oscillatory zoning on cathodoluminescence images. 22 tests of zircons in the trachytic dacite from the bottom part yield an age of 141-151 Ma, with weighted mean 206Pb/238U age of 145±2 Ma. Whereas 18 tests of zircons from the sample at the upper part give 206Pb/238U ages around 139-149 Ma with weighted mean 206Pb/238U age of 141±2 Ma, which implies that the X well volcanic rocks belong to Late Jurassic-Early Cretaceous. Comparing with the age and geochemical characteristics of the Mesozoic igneous rocks in Shandong peninsula, we suggest that the igneous rocks from both the North Yellow Sea basin and Jiaolai basin were formed under same dynamic setting, i.e., the subduction related volcano arc and back-arc extension. ©, 2015, Science Press. All right reserved.     

Geochemical characteristics and LA-ICP-MS zircon U-Pb age of the Lanhualing granite in Ningguo,Anhui ProvinceEI北大核心CSCD

The Lanhualing tungsten-molybdenum deposit is a skarn-type deposit located in Ningguo county, Anhui province. This deposit is mainly hosted in the Yinzhubu Formation and the Yanwashan Formation of Ordovician, and genetically related to the Lanhualing granite. The Lanhualing granite belongs to high-K calc-alkaline series with high alkali (Na2O+K2O=4.00%-7.03%), SiO2 (67.87%-74.92%) and MgO (0.62%-1.23%) contents. The granitic rocks show right-dipping chondrite normalized REE patterns with weak δEu anomalies. The granitic rocks are relatively enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE). The ore-bearing granite was dated at 148.17±0.94 Ma by LA-ICP-MS zircon U-Pb method. The late Yanshanian is the main tungsten mineralization epoch in the South Anhui-north Jiangxi area; and indeed, the Dongyuan, Zhuxi, Yangchuling, Dahutang and other large and super-large tungsten deposits were formed in this period. Geochemical Characteristics of the Lanhualing granite indicate a crustal source but with mantle input under tectonic regime of compression thickening. ©, 2015, Science Press. All right reserved.     

大沽河地下咸淡水过渡带的水-岩作用模拟

大沽河是青岛市最大的地下水源地,过量开采导致严重的地下咸水入侵,研究地下咸-淡水的地球化学作用对于地下咸水的治理具有重要的指导作用。本文选取大沽河地下咸淡水过渡带作为研究区,在地下水动态监测的基础上,通过地下水水质和含水介质矿物分析,借助当前成熟的水文地球化学模拟软件—PHREEQC 2.0,计算地下水中主要离子和络合离子的含量,定量确定矿物的饱和指数和地下水流向上矿物相与水之间的物质交换量。研究结果表明:(1)地下水中钠、钾、镁、钙主要以单一离子形态存在,硫、碳主要以络阴离子形态存在,而硅和铝主要以络合物形态存在;(2)在地下水流动路径上,方解石、白云石、伊利石、高岭土处于过饱和状态;而石膏、CO2、氯化钠、萤石、玉髓处于不饱和状态;(3)咸淡水过渡带地下水化学类型由HCO3-Ca·Na型水向Cl-Na型水转变的趋势。