赣南印支期柯树岭花岗岩体SHRIMP锆石U-Pb 年龄、地球化学、锆石Hf同位素特征及成因探讨

利用SHRIMP锆石U-Pb定年方法测得赣南柯树岭-仙鹅塘云英岩-石英脉型钨锡多金属矿床柯树岭区段钻孔中的新鲜花岗岩的成岩年龄为251.5±6.6Ma和202±15Ma。柯树岭花岗岩属过铝质高钾钙碱性花岗岩;ΣREE较低(<80.16×10-6),与华南典型含铌钽矿化花岗岩ΣREE含量低的特点一致,是岩浆高度分异演化的产物;锆石εHf(t)值为-14.5～-1.3,Hf两阶段模式年龄TDM2为3.21～2.55Ga,表明该岩体起源于太古宙地壳物质的部分熔融;Al/(Mg+Fe)-Ca/(Mg+Fe)图解表明该岩体主要来源于变质杂砂岩和变质泥岩的部分熔融,但也混有一些变质玄武岩和变质英云闪长岩,两个正的εHf(t)值(+2.4和+3.0)显示岩浆在上升侵位过程中捕获了幔源残留锆石。包括柯树岭在内的华南印支期花岗岩是于后碰撞或碰撞晚期,在以被动侵位机制为主和挤压应力松弛的间隙环境中侵位的,为加厚地壳局部熔融的产物。     

U-Pb Age Determination for Seven Standard Zircons using Inductively Coupled Plasma–Mass Spectrometry Coupled with Frequency Quintupled Nd-YAG (λ = 213 nm) Laser Ablation System: Comparison with LA-ICP-MS Zircon Analyses with a NIST Glass Reference Material

This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For ²⁰⁷Pb/²⁰⁶Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the ²⁰⁶Pb/²³⁸U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the ²⁰⁶Pb/²³⁸U (= 0.2302) newly defined in the present study is used, the measured ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for ²⁰⁶Pb/²³⁸U by measuring several zircon standards in individual laboratories.     

辽北西丰地区宝兴岩体LA-ICP-MS锆石U-Pb年龄及岩石地球化学特征

宝兴岩体位于华北板块北缘陆缘活动带东段,岩性为花岗闪长岩,LA-ICP-MS锆石~(206)Pb/~(238)U年龄加权平均值为235.0±1.3Ma,属于中三叠世。岩石的K_2O/Na_2O平均值为1.07,属高钾钙碱性系列;富集大离子亲石元素,亏损高场强元素,具有活动陆缘钙碱性岩系特征;稀土元素总量平均值为147×10~(-6),稀土元素配分曲线右倾,属具中等负Eu异常的轻稀土元素富集、重稀土元素亏损型。通过岩石学、岩石地球化学及年代学研究,结合邻区构造演化研究,认为中三叠世研究区在伸展作用下岩石圈进行拆沉,从而形成大规模的岩浆活动。     

辽东岫岩地区下古生界碎屑锆石定年:罗迪尼亚和冈瓦纳超大陆在华北遗留的痕迹？

超大陆演化是地质研究的重要内容,华北克拉通与不同地质历史时期超大陆汇聚与裂解的联系对反演华北克拉通构造演化历史具有重要意义。本文在辽吉古元古代造山带中段的原划分为辽河群地层中首次识别出一套早古生代沉积建造。这套沉积建造与华北克拉通以浅海相的碳酸盐岩为主的早古生代沉积并不一致,以发育大量的陆源碎屑沉积为特征。我们对2件细砂岩分别进行了锆石LA-ICP-MS和SHRIMP U-Pb定年。定年结果显示,2件样品的最小年龄分别为~482Ma和~498Ma,反映了它们的最大沉积时代。2件样品的碎屑锆石年龄主要介于1600~500Ma,缺乏亲华北的物源信息,表明它们的物源主要来自于华北之外。2件样品年龄谱中最重要的峰值出现在格林威尔期和泛非期,表明华北克拉通曾与罗迪尼亚超大陆和冈瓦纳大陆存在联系。格林威尔期碎屑锆石可能来自于罗迪尼亚超大陆时期波罗地古陆物质在华北克拉通东缘的再循环;泛非期碎屑锆石可能来自于东冈瓦纳大陆的北缘造山带。

     

Polymetamorphism, zircon growth and retention of early assemblages through the dynamic evolution of a continental arc in Fiordland, New Zealand

The Marguerite Amphibolite and associated rocks in northern Fiordland, New Zealand, contain evidence for retention of Carboniferous metamorphic assemblages through Cretaceous collision of an arc, emplacement of large volumes of mafic magma, high‐P metamorphism and then extensional exhumation. The amphibolite occurs as five dismembered aluminous meta‐gabbroic xenoliths up to 2 km wide that are enclosed within meta‐leucotonalite of the Lake Hankinson Complex. A first metamorphic event (M1) is manifest in the amphibolite as a pervasively lineated pargasite–anorthite–kyanite or corundum ± rutile assemblage, and as diffusion‐zoned garnet in pelitic schist xenoliths within the amphibolite. Thin zones of metasomatically Al‐enriched leucotonalite directly at the margins of each amphibolite xenolith indicate element redistribution during M1 and equilibration at 6.6 ± 0.8 kbar and 618 ± 25 °C. A second phase of recrystallization (M2) formed patchy and static margarite ± kyanite–staurolite–chlorite–plagioclase–epidote assemblages in the amphibolite, pseudomorphs of coronas in gabbronorite, and thin high‐grossular garnet rims in the pelitic schists. Conditions of M2, 8.8 ± 0.6 kbar and 643 ± 27 °C, are recorded from the rims of garnet in the pelitic schists. Cathodoluminescence imaging and simultaneous acquisition of U‐Th‐Pb isotopes and trace elements by depth‐profiling zircon grains from one pelitic schist reveals four stages of growth, two of which are metamorphic. The first metamorphic stage, dated as 340.2 ± 2.2 Ma, is correlated with M1 on the basis that the unusual zircon trace element compositions indicate growth from a metasomatic fluid derived from the surrounding amphibolite during penetrative deformation. A second phase of zircon overgrowth coupled with crosscutting relationships date M2 to between 119 and 117 Ma. The Early Carboniferous event has not previously been recognized in northern Fiordland, whereas the latter event, which has been identified in Early Cretaceous batholiths, their xenoliths, and rocks directly at batholith margins, is here shown to have also affected the country rock. However, the effects of M2 are fragmentary due to limited element mobility, lack of deformation, distance from a heat source and short residence time in the lower crust during peak P and T. It is possible that many parts of the Fiordland continental arc achieved high‐P conditions in the Early Cretaceous but retain earlier metamorphic or igneous assemblages.     

黑龙江宁安英城子热液金矿床与成矿伴生的辉绿玢岩的锆石U-Pb年龄及其地质意义

英城子热液金矿床产于张广才岭岩浆构造带东侧的早古生代花岗岩岩体内的韧脆性剪切带中。矿区内出露的辉绿玢岩中锆石的SHRIMPU--Pb测年结果表明:16个单颗粒锆石的谐和年龄值可划分为4组,分别为849.7～897.0Ma、755.6±19.2Ma、486～514.0Ma和419～451Ma。结合锆石的特征和相关地质测年结果,初步认为辉绿玢岩岩浆作用发生在麻山期或加里东期陆内造山后的地壳伸展环境内(432Ma);该区在晚元古代和早古生代属于佳木斯地块的一部分或地壳演化与佳木斯地块、额尔古纳地块处于相同的地质环境中。     

湖南锡田矿田花岗岩时空分布与钨锡成矿关系:来自锆石U-Pb年代学与岩石地球化学的约束

锡田钨锡多金属矿田位于南岭成矿带中段,发育多期次岩浆活动与钨锡成矿. 为了厘清花岗岩与钨锡成矿的时空关系,采用野外调查、显微鉴定、锆石U-Pb同位素定年与岩石地球化学的方法对矿田内多期次花岗岩岩体（脉）的空间分布、岩石类型、成岩时代、地球化学组成等进行了研究. 结果表明,锡田矿田发生了三期岩浆事件,分别为加里东期（435~441 Ma）、印支期（220~230 Ma）、燕山期（141~160 Ma）;三期花岗岩普遍富集大离子亲石元素Rb、K、U、Th等,亏损Ti、P、Sr、Ba等微量元素,具明显的负Eu异常,其中加里东期花岗岩与印支期花岗岩为S型花岗岩,而燕山期花岗岩为A型花岗岩;不同时期花岗岩中的成矿元素从加里东期→印支期→燕山期逐渐升高,特别是W、Sn元素在燕山期白云母与二云母花岗岩中最为富集,这与华南地区燕山期钨锡大爆发的时间是一致的;印支期岩体接触带发育少量矽卡岩型Fe-Cu-W多金属矿床,燕山期岩体接触带也发育矽卡岩型W-Sn多金属矿床,并在附近陡倾的张裂隙中发育多个中大型石英脉型W-Sn矿床,而加里东期岩体附近尚未发现钨锡矿化. 因此,锡田矿田的多期次花岗岩与钨锡多金属成矿是时空耦合的,且成矿以燕山期矽卡岩型与石英脉型钨锡矿为主.      

内蒙古克什克腾旗长岭子斜长花岗斑岩锆石U-Pb年龄、成因与碰撞造山作用

内蒙古克什克腾旗长岭子斜长花岗斑岩位于大兴安岭锡林浩特增生杂岩带内.本文对长岭子斜长花岗斑岩进行了主微量元素地球化学以及锆石U?Pb年代学和Lu?Hf同位素研究.长岭子斜长花岗斑岩锆石206Pb/238U加权平均年龄为(248.1±4.7)Ma,是早三叠世岩浆活动的产物;继承锆石除外,样品中锆石具有正的εHf(t)值(...     

湖南川口岩体型钨矿赋矿花岗岩地球化学特征及LA-ICP-MS锆石U-Pb定年

川口矿田钨矿床产于湖南衡阳川口岩体的外接触带及岩体内部,矿床类型主要有岩浆热液石英细脉带型和石英大脉型。近年川口矿田取得了重大找矿突破,并发现了新类型的岩体型钨矿。本文对川口岩体型钨矿床的黑云母二长花岗岩及赋矿的白云母二长花岗岩分别进行了 LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究,获得川口岩体的成岩年龄为(223.1 ± 0.78)Ma,MSWD=0.98,n=24,岩体型钨矿成矿年龄为(224.6±1.31)Ma,MSWD=0.33,n=9,为印支期成岩成矿。川口花岗岩具有高SiO_2,富K_2O+Na_2O,低CaO、MgO的特点,属于过铝质高钾钙碱性系列S型花岗岩,形成于碰撞环境下弱挤压构造体制。川口岩体稀土总量(∑REE)整体较低,轻稀土相对较富集,具有强烈的负Eu异常,富集大离子亲石元素Ba、K和高场强元素Ta,而亏损大离子亲石元素Sr和相容元素P、Ti等,表明该岩体各阶段花岗岩来自同一岩浆源,且经历了高度演化。赋矿花岗岩更低的δEu值及(La/Yb)_N值,表明其结晶分异程度更高。     

Two Periods of Skarn Mineralization in the Baizhangyan W–Mo Deposit,Southern Anhui Province,Southeast China: Evidence from Zircon U–Pb and Molybdenite Re–Os and Sulfur Isotope Data

The recently discovered Baizhangyan skarn‐porphyry type W–Mo deposit in southern Anhui Province in SE China occurs near the Middle–Lower Yangtze Valley polymetallic metallogenic belt. The deposit is closely temporally‐spatially associated with the Mesozoic Qingyang granitic complex composed of g ranodiorite, monzonitic g ranite, and alkaline g ranite. Orebodies of the deposit occur as horizons, veins, and lenses within the limestones of Sinian Lantian Formation contacting with buried fine‐grained granite, and diorite dykes. There are two types of W mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization. Among skarn mineralization, mineral assemblages and cross‐cutting relationships within both skarn ores and intrusions reveal two distinct periods of mineralization, i.e. the first W–Au period related to the intrusion of diorite dykes, and the subsequent W–Mo period related to the intrusion of the fine‐grained granite. In this paper, we report new zircon U–Pb and molybdenite Re–Os ages with the aim of constraining the relationships among the monzonitic granite, fine‐grained granite, diorite dykes, and W mineralization. Zircons of the monzonitic granite, the fine‐grained granite, and diorite dykes yield weighted mean U–Pb ages of 129.0 ± 1.2 Ma, 135.34 ± 0.92 Ma and 145.3 ± 1.7 Ma, respectively. Ten molybdenite Re–Os age determinations yield an isochron age of 136.9 ± 4.5 Ma and a weighted mean age of 135.0 ± 1.2 Ma. The molybdenites have δ³⁴S values of 3.6‰–6.6‰ and their Re contents ranging from 7.23 ppm to 15.23 ppm. A second group of two molybdenite samples yield ages of 143.8 ± 2.1 and 146.3 ± 2.0 Ma, containing Re concentrations of 50.5–50.9 ppm, and with δ³⁴S values of 1.6‰–4.8‰. The molybdenites from these two distinct groups of samples contain moderate concentrations of Re (7.23–50.48 ppm), suggesting that metals within the deposit have a mixed crust–mantle provenance. Field observation and new age and isotope data obtained in this study indicate that the first diorite dyke‐related skarn W–Au mineralization took place in the Early Cretaceous peaking at 143.0–146.3 Ma, and was associated with a mixed crust–mantle system. The second fine‐grained granite‐related skarn W–Mo mineralization took place a little later at 135.0–136.9 Ma, and was crust‐dominated. The fine‐grained granite was not formed by fractionation of the Qingyang monzonitic granite. This finding suggests that the first period of skarn W–Au mineralization in the Baizhangyan deposit resulted from interaction between basaltic magmas derived from the upper lithospheric mantle and crustal material at 143.0–146.3 and the subsequent period of W–Mo mineralization derived from the crust at 135.0–136.9 Ma.