Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.     

汾河口傍河水源地激发补给量研究

该文阐述傍河水源地地下水资源构成和补给特性。利用野外试验与室内数值模拟相结合方法，分析汾河口傍河水源地可采水资源量，数值模型刻画黄河实际摆动边界，考虑潜水延迟给水和极端干旱气候条件等多种方案；利用环境同位素技术追踪傍河水源地开采条件下的河水激发补给过程和补给强度。研究表明，在渗透性较好的常年性河流旁建立的水源地，具有抵御极端气象、水文环境以丰补歉的能力，枯水年动用的含水层储存量。丰水年恢复性强。     

镜泊湖地区水体的同位素、元素地球化学特征及地下热水储存状态分析

依据镜泊湖地区水体的同位素、水化学及微量元素中子活化分析资料，详细阐述了各采样点水体的来源、补给相对高程和它们之间可能的水力联系，以及有关的地热信息；分析了区内地热资源的有利地质背景条件研究区地处深大断裂及岩浆喷发带，火山喷发一直延续至第四纪全新世，有充分的热源供给；区内上部为较厚的玄武岩覆盖，有利于储存地热；下部白垩系上统为主要含水层，发现有广泛分布的典型木／岩热蚀变产物——斜发沸石，进而证明存在地下热水的可能性。     

湖北黄土岭麻粒岩锆石拉曼光谱和等离子体质谱研究

对湖北黄土岭麻粒岩中锆石同时进行了激光拉曼探针、阴极发光 (CL)观察和U ,Th及Pb Pb年龄ICPMS测定 ,发现麻粒岩中部分锆石发生的不是固态重结晶作用 ,而是部分熔蚀 /沉淀再结晶过程。结合CL图像结构特征和2 0 7Pb/ 2 0 6Pb年龄初步推断 ,麻粒岩相事件发生在 2 0亿年之后。结构、化学和同位素组成的测定表明 ,大别地区广泛存在的燕山期热事件使锆石发生不同程度的变质重结晶作用 ,使锆石晶格愈合。     

壳幔混染作用——下扬子区早中生代玄武岩同位素地质特征

下扬子区中生代（231Ma）玄武质火山岩全岩εNd（t）值-8.62～1.92,87Sr/86Sr 值0.7074～0.7179，206Pb/204Pb值为17.786～18.323。岩石中含有前寒武纪捕虏晶锆石。研究表明玄武质岩石可能是由亏损地幔与元古宙地壳岩石混染作用的结果。     

胶东招掖郭家岭型花岗岩锆石年代学及其Pb同位素特征

采用SHRIMP测年技术，精确地测定了郭家岭型花岗岩年龄为130-126Ma，主要金矿化在126-120Ma之间，郭家岭型花岗岩与金矿化关系最密切。岩体Pb同位素组成反映了本区所处构造背景。     

泥炭档案气候变化重建的定量模型

泥炭档案气候变化重建的定量模型＊陶发祥洪业汤（中国科学院地球化学研究所，贵阳５５０００２）李汉鼎冷雪天（东北师范大学地理系，长春１３００２４）关键词泥炭档案纤维素稳定同位素气候变化定量模型用泥炭档案定量重建大气ＣＯ２浓度的研究已取得重要进展［１］，但...     

松辽盆地白垩系的密集段及海水进侵的新证

在总结松辽盆地白恶系层地层特征的基础上，阐述了密集段的地质学和地球物理学标志，经分析，大多数重要反射与密集段相关而并非是层序边界，根据扫描电镜分析结果，在密集段中首次发现了钙质超微化石，为区内白垩纪海水进侵的提供了新的证据，由稳定同位素分析，密集段形成了缺氧，相对可容纳空间最大及水体最深时期。     

211地区铀矿床的稳定同位素地球化学特征

本文在讨论了 2 11地区花岗岩型铀矿床的稳定同位素组成的基础上 ,提出该区铀成矿热液可能主要来自晚期花岗岩浆 ,部分来自大气降水     

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.