乙酰胺-尿素-NaBr熔体中Ce-Sm-Co合金膜的电化学制备

应用循环曲线法研究了在353 K的乙酰胺-尿素-NaBr熔体中Co2+在Cu电极上的电化学行为,获知Co2+电还原为金属Co是一步不可逆过程,测得a=0.25和Do=3.24×10-6cm2.s-1;而Ce(Ⅲ)、Sm(Ⅲ)不能单独还原为Ce和Sm,但可以被Co(Ⅱ)诱导而共沉积;由恒电位电解法得到非晶态的Ce-Sm-Co合金膜,合金膜中Ce和Sm的含量随电位、时间和浓度的变化而变化。其合金膜中Sm的最高质量分数可以达到47.98%,Ce的最高质量分数可以达到47.32%。     

Gaseous transport and deposition of gold in magmatic fluid: evidence from the active Kudryavy volcano, Kurile Islands

The distribution of gold in high-temperature fumarole gases of the Kudryavy volcano (Kurile Islands) was measured for gas, gas condensate, natural fumarolic sublimates, and precipitates in silica tubes from vents with outlet temperatures ranging from 380 to 870°C. Gold abundance in condensates ranges from 0.3 to 2.4 ppb, which is significantly lower than the abundances of transition metals. Gold contents in zoned precipitates from silica tubes increase gradually with a decrease in temperature to a maximum of 8 ppm in the oxychloride zone at a temperature of approximately 300°C. Total Au content in moderate-temperature sulfide and oxychloride zones is mainly a result of Au inclusions in the abundant Fe–Cu and Zn sulfide minerals as determined by instrumental neutron activation analysis. Most Au occurs as a Cu–Au–Ag triple alloy. Single grains of native gold and binary Au–Ag alloys were also identified among sublimates, but aggregates and crystals of Cu–Au–Ag alloy were found in all fumarolic fields, both in silica tube precipitates and in natural fumarolic crusts. Although the Au triple alloy is homogeneous on the scale of microns and has a composition close to (Cu,Ni,Zn)₃(Au,Ag)₂, transmission electron microscopy (TEM) shows that these alloy solid solutions consist of monocrystal domains of Au–Ag, Au–Cu, and possibly Cu₂O. Gold occurs in oxide assemblages due to the decomposition of its halogenide complexes under high-temperature conditions (650–870°C). In lower temperature zones (<650°C), Au behavior is related to sulfur compounds whose evolution is strongly controlled by redox state. Other minerals that formed from gas transport and precipitation at Kudryavy volcano include garnet, aegirine, diopside, magnetite, anhydrite, molybdenite, multivalent molybdenum oxides (molybdite, tugarinovite, and ilsemannite), powellite, scheelite, wolframite, Na–K chlorides, pyrrhotite, wurtzite, greenockite, pyrite, galena, cubanite, rare native metals (including Fe, Cr, Mo, Sn, Ag, and Al), Cu–Zn–Fe–In sulfides, In-bearing Pb–Bi sulfosalts, cannizzarite, rheniite, cadmoindite, and kudriavite. Although most of these minerals are fine-grained, they are strongly idiomorphic with textures such as gas channels and lamellar, banded, skeletal, and dendrite-like crystals, characteristic of precipitation from a gas phase. The identified textures and mineral assemblages at Kudryavy volcano can be used to interpret geochemical origins of both ancient and modern ore deposits, particularly gold-rich porphyry and related epithermal systems.     

铜合金可见光谱特征及其应用

对铜合金可见光谱线进行了计算机数字模拟处理，研究了基体元素铜和各成分元素的可见光谱特征。使用光栅看谱镜和棱镜看谱镜对铜合金可见光谱进行了看谱分析研究，摄制了彩色图谱。利用铜元素及成分元素特征谱线进行了基体鉴别和成分元素分析，研究结果可用于合金基体鉴别及铜合金成分元素的定性和半定量分析。     

Structural vibration control by shape memory alloy damper

A damper device based on shape memory alloy (SMA) wires is developed for structural control implementation. The design procedures of the SMA damper are presented. As a case study, eight such SMA dampers are installed in a frame structure to verify the effectiveness of the damper devices. Experimental results show that vibration decay of the SMA damper controlled frame is much faster than that of the uncontrolled frame. The finite‐element method is adopted to conduct the free and forced vibration analysis of the controlled and uncontrolled frame. The experimental and numerical results illustrate that the developed SMA dampers are very effective in reducing structural response and have great potential for use as efficient energy dissipation devices with the advantages of good control of force and no lifetime limits, etc. Copyright © 2003 John Wiley & Sons, Ltd.     

Research on Effect of SMA Damper in Passive Control

In this article, mechanics model of SMA center tension from damper is developed. According to the theory of Brinson constitutive model and thermodynamics first law, damper thermodynamics non-linear equation has been developed. Dynamics non-linear equation of frame structure under operation of SMA damper and its solution have been worked out; the software of seismic response analysis for frame structure and of damper characteristic analysis have been compiled with MATLAB software, andthe examples have been computed with it. The result indicates that SMA damper has obvious damp characteristics and it can provide with obvious restraint effect for seismic response of frame structure. Decreasing rate of displacement and velocity on top of frame structure reaches 50％-60％. The result is in accordance with other pundits experimentation results, which indicates that the above methods are correct and useful.     

提高金刚石-硬质合金超硬复合体性能的研究

采用金刚石表面镀覆技术、预合金基体金属粉末，提高金刚石热稳定性及其与金属粘结剂的浸润性，使金刚石的高耐磨性和硬质合金的高抗冲击性能有机地结合在一起；优化超硬复合体结构形状，提高其耐磨性能和高抗冲击性能；设计合理模具大大降低了加工成本，从而研制出性能优良、价格低廉的金刚石－硬质合金超硬复合体。     

钨的迁移形式成矿机理新探

通过对钨羰基络合物及钨合金氢化物的物理化学性质、钨矿床矿物流体包裹体的化学组成、钨矿物的化学成分、主要共生伴生矿物组合的研讨,结合钨成矿的地质背景和环境,认为钨羰基络合物及钨合金氢化物是钨的主要迁移形式。它们形成于地球深部高压、富氢、富CO的强还原环境,随着岩浆、热液、热气迁移至地壳浅部,由于压力、温度下降,氧逸度大增,H2、CO逃逸、氧化,钨羰基络合物、钨合金氢化物分解,氧化形成钨矿物,沉淀富集形成钨矿床。     

基于SMA连接件的半刚接钢框架-混凝土墙结构滞回性能试验研究

针对半刚接钢框架-混凝土墙(PSRCW)结构中连接件易发生疲劳断裂的问题,利用形状记忆合金(SMA)制成连接件并将其应用到PSRCW结构中。对4个2层单跨PSRCW结构试件在水平低周往复荷载作用下的抗震性能进行了试验研究。根据试验现象分析了各试件的受力破坏过程,研究了连接件类型、尺寸和布置位置对各试件的滞回性能、耗能能力、强度、刚度、延性和变形恢复能力的影响。试验结果表明:基于SMA连接件的PSRCW结构整体性较好、耗能能力强、结构强度退化具有2个平台阶段、刚度退化较为缓慢、延性好和结构具有较强的变形恢复能力。同时,增大SMA连接件的直径可以提高结构的承载能力、初始刚度和延性;在框架梁柱与内填墙交界面间均布置SMA连接件时,结构整体性最好,强度退化缓慢,延性好。因此,将SMA连接件应用于PSRCW结构中,对于改善钢混组合结构的力学性能有一定的理论意义和实用价值。     

Shake table test and numerical study of self‐centering steel frame with SMA braces

Given their excellent self‐centering and energy‐dissipating capabilities, superelastic shape memory alloys (SMAs) become an emerging structural material in the field of earthquake engineering. This paper presents experimental and numerical studies on a scaled self‐centering steel frame with novel SMA braces (SMAB), which utilize superelastic Ni–Ti wires. The braces were fabricated and cyclically characterized before their installation in a two‐story one‐bay steel frame. The equivalent viscous damping ratio and ‘post‐yield’ stiffness ratio of the tested braces are around 5% and 0.15, respectively. In particular, the frame was seismically designed with nearly all pin connections, including the pinned column bases. To assess the seismic performance of the SMA braced frame (SMABF), a series of shake table tests were conducted, in which the SMABF was subjected to ground motions with incremental seismic intensity levels. No repair or replacement of structural members was performed during the entire series of tests. Experimental results showed that the SMAB could withstand several strong earthquakes with very limited capacity degradation. Thanks to the self‐centering capacity and pin‐connection design, the steel frame was subjected to limited damage and zero residual deformation even if the peak interstory drift ratio exceeded 2%. Good agreement was found between the experimental results and numerical simulations. The current study validates the prospect of using SMAB as a standalone seismic‐resisting component in critical building structures when high seismic performance or earthquake resilience is desirable under moderate and strong earthquakes. Copyright © 2016 John Wiley & Sons, Ltd.     

典型海洋大气环境中AZ80镁合金电偶腐蚀行为研究

镁合金作为最轻的金属结构材料,具有比强度高、比刚度高、减震性能好、电磁屏蔽等优点。随着海洋强国战略的实施,先进镁合金结构材料逐步在海洋装备上开始应用。已列装的新型高强AZ80镁合金,通过与QBe1.7铍青铜紧固件连接,共同构成整体在典型海洋大气环境中服役。在高盐、高湿的海洋环境环境中,镁合金与电位更正的QBe1.7铍青铜偶接后,极易发生电偶腐蚀。电位相对更负的高强AZ80镁合金,作为电偶腐蚀的阳极被加速溶解。本研究对高强AZ80镁合金电偶腐蚀样品经过12个月青岛海洋大气暴露试验,发现空白对照组、电偶1组(紧固件铍青铜直径Ψ=10mm)和电偶2组(紧固件铍青铜直径Ψ=20mm)的平均腐蚀速率分别为108.1071、133.8929、173.6250g/(m~2·a)。电偶对表面的主要腐蚀产物为:Mg(OH)_2、MgSO_4和MgCl_2。空白样品、电偶1组和电偶2组平均腐蚀深度分别为:0.175、0.330、0.315mm/a。样品中部腐蚀深度最大,边部腐蚀深度则相对较小。不同样品在青岛试验站的腐蚀产物对基体保护能力的量度(n值)分别为1.1337、1.1378、1.0895,表明随着暴露时间的延长,试样在海洋大气环境中的腐蚀速率会加快,试样表面的腐蚀产物对基体根本起不到保护作用。通过灰色关联分析法,计算了青岛海洋大气腐蚀站点的环境因素与AZ80镁合金腐蚀深度和腐蚀失重之间的关联度,结果表明:青岛海洋大气环境因素对高强AZ80镁合金空白样品腐蚀失重影响前三位分别为:SO_4~(2-)非水溶性硫酸盐转化率;对电偶1组样品影响前三位的环境因素分别为:SO_2硫酸盐转化率NO_2;对电偶2组样品影响前三位的环境因素分别为:水溶性降尘SO_2NH_3。对比电偶对2组和1组,唯一的差别是电偶对的面积比,但决定镁合金腐蚀速度的大气成分完全不同,相关机制会在未来工作中详细研究。