氟镁石-萤石型金矿的成岩成矿机制新探索

在岩浆及热液中,氟以氟化硅,硅氟酸迁移,金呈金氢化物,金合金氢化物迁移（或）,金,银,铜,铁,铬羰基化合物迁移。在合适的条件下形成氟镁石－萤石型金矿床。     

Discovery of Cu-Ni-Zn-Sn-Fe intermetallic compounds and S-bearing alloys in the Zhaishang gold deposit, southern Gansu Province and its geological significance

Examination of ores by optical microscope and EPMA from the Zhaishang gold deposit, southern Gansu Province, has revealed an abundance of rare minerals. These include native metals, Cu-Ni-Zn-Sn-Fe polymetallic compounds and S-bearing alloys of Ni, Fe, Zn, Cu and Sn, occurring as native nickel, Zn-Cu alloy, Ni-Zn-Cu alloy, Sn-Zn-Ni-Cu alloy, Zn-Cu-Ni alloy, Zn-Fe-Cu-Sn-Ni alloy, Fe-Ni-S alloy, Sn-Fe-Ni-S alloy, Fe-Zn-Cu-Ni-S alloy, Zn-Ni-Cu-Fe-S alloy and others. Compared with the Zn-Cu alloy minerals discovered previously, these Zn-Cu minerals fall in the α or α β portion in Zn-Cu alloy phase diagram, and the α portion has higher Cu content. Cu-Ni-Zn-Sn-Fe intermetallic compounds and S-bearing alloy minerals have not been previously reported in the literature. These rare alloys formed in a strongly reducing environment with absent oxygen and low sulfur activities.     

Influence of pressure on the solid state phase transformation of Cu—Al—Bi alloy

The solid state phase transformation of Cu--Al--Bi alloy under high pressure was investigated by x-ray diffraction, energy dispersive spectroscopy and transmission electron microscopy. Experimental results show that the initial crystalline phase in the Cu--Al--Bi alloy annealed at 750 °C under the pressures in the range of 0--6 GPa is α-Cu solid solution (named as α-Cu phase below), and high pressure has a great influence on the crystallisation process of the Cu--Al--Bi alloy. The grain size of the α-Cu phase decreases with increasing pressure as the pressure is below about 3 GPa, and then increases (P>3 GPa). The mechanism for the effects of high pressure on the crystallisation process of the alloy has been discussed.     

切向流动对偏晶合金定向生长机理的影响

研究了静态和切向流动作用下对二氯苯-丁二腈(DCB-SCN)偏晶合金的定向凝固过程.实验结果表明,静态条件下,DCB以小平面相方式生长,随着抽拉速度的提高,DCB-SCN偏晶凝固组织形貌发生液/固两相完全分离组织-规则纤维状共生组织-不规则弥散组织转变.施加切向流动作用后,DCB生长晶面出现胞状扰动,并且偏晶共生纤维间距随流速的增高而变大,但对于同一流速,仍然满足λV^0.5=常数.同时,切向流动能够细化弥散偏晶组织中第二相颗粒尺寸,这主要缘于流动引发的固液界面形态变化能     

低合金钢在海洋各腐蚀区带的锈层研究

１９９５年５月通过对低合金－１６Ｍｎ钢在埕岛海区挂片两年（１９９２年１０月－１９９４年１０月）的腐蚀产物的穆斯堡尔谱测定,研究了低合金钢在飞浅区,潮差区,全浸区和海泥区四个不同海洋腐蚀区带的锈层组成和含量。锈层中的ＦｅＯＯＨ和Ｆｅ３Ｏ４的不同含量说明了内锈层中的β－ＦｅＯＯＨ作为氧化剂参与了阴极作用,加速了干湿交替区低合金的腐蚀。     

Modeling and cyclic behavior of segmental bridge column connected with shape memory alloy bars

This paper examines the quasi-static cyclic behavior,lateral strength and equivalent damping capacities of a system of post-tensioned segmental bridge columns tied with large diameter martensitic Shape Memory Alloy(SMA) link-bars.Moment-curvature constitutive relationships are formulated and analysis tools are developed for the PT column,including a modified four-spring model prepared for the SMA bars.The suggested system is exemplified using a column with an aspect ratio of 7.5 and twelve 36.5 mm diameter NiTi martensitic SMA bars.A post-tensioning force of 40% to 60% of the tendon yield strength is applied in order to obtain a self re-centering system,considering the residual stress of the martensitic SMA bars.The cyclic response results show that the lateral strength remains consistently around 10% of the total vertical load and the equivalent viscous damping ratios reach 10%-12% of critical.When large diameter NiTi superelastic SMA bars are incorporated into the column system,the cyclic response varies substantially.The creep behavior of the superelastic SMA bar is accounted for since it affects the re-centering capability of the column.Two examples are presented to emphasize the modeling sensitivities for these special bars and quantify their cyclic behavior effects within the column assembly.     

热浸镀锌-5%铝钢材在海水中的氢脆敏感性

热浸镀锌-5％铝镀层钢材在海洋环境中使用时可能存在氢脆问题。采用慢应变速率拉伸实验法,结合扫描电镜分析,研究了锌-5％铝镀层钢材在海水中的氢脆敏感性。发现锌-5％铝镀层对钢材基体进行阴极保护引起的氢渗透,可显著降低钢材的断后延伸率和能量密度,使钢材的断裂方式由韧性向准解理转变,提高了其在海水中的氢脆敏感性。     

一种新型变形可恢复SMA阻尼器力学性能的研究

利用形状记忆合金（Shape Memory Alloy,简称"SMA"）丝材的超弹性与复位弹簧特性,开发出一种新型变形可恢复SMA阻尼器,以增强其变形可恢复的能力。同时,为了解决SMA丝材在实际工程中锚固难的问题,提出了一种新型可调节夹具,不仅解决了SMA丝材的不易锚固问题,而且增强了调节预应变的能力。对所提出的新型SMA阻尼器进行了循环加载试验研究和数值仿真分析,探讨不同加载频率及位移幅值对其力学性能的影响,建立了恢复力模型。结果表明:新型SMA阻尼器在循环荷载作用下滞回性能稳定,具有良好的耗能性能;内置弹簧对新型SMA阻尼器变形可恢复能力有较大帮助。基于所建立恢复力模型的数值模拟结果与试验结果符合情况很好,验证了阻尼器恢复力力模型的正确性。     

金银铂族元素成矿机理的新探索

通过对金、银、铂族元素的氢化物，羧基化合物理化性质，贵金属矿物主要和次要化学成分，贵金属矿物的共伴生矿物组合，有关矿物流体包裹体化学成分，类地行星概况，生产实验等相关问题的讨论，认为金、银、铂族元素主要呈单质及其合金氢化物，单质羧基化合物，单质羧基氢化物迁移的。它们随岩浆，热液，热气迁至地壳浅部，由于减压，降温，氧逸度显著加大，Eh、Ph值发生变化，H2，CO逃逸，氧化，形成贵金属的单质及合金矿物，有的还能与硫，硫化氢作用形成贵金属的硫化矿物和硫盐矿物。