冶炼废渣综合回收铀、铌、钽和锡

根据某冶炼尾渣的成分和矿物特性,研究了铀、铌、钽和锡的回收工艺。开发出酸浸提铀-重选抛尾-弱磁选回收铌、钽一强磁选除铁回收锡的联合工艺流程。铀浸出率大于80％;铌、钽品位大于31％,回收率大于80％;锡精矿品位大于62％,回收率大于65％,锡精矿经放射性去污后,其放射性水平基本符合有色冶金行业标准。     

我国天然锌铜金属互化物的发现和特征

锌、铜金属互化物是罕见的天然合金矿物，由锌、铜两种元素组成。由于形成条件、环境不同及矿物中锌、铜元素含量不同，形成系列锌、铜金属互化物。经过对我国近二十年来发现的各类型天然锌、铜金属互化物产出的地质特征，物理、化学及光学性质进行的系统研究发现，目前我国在不同的地质体中出现多种不同类型的锌、铜金属互化物，该类矿物主要形成于高温、还原且缺硫的条件下，多数与造岩矿物共生，而与多数金属硫化物形成条件不同。     

热液中铅、锌、银共生分异的热力学探讨

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。     

Geology,ore facies and sulphur isotopes of the Koushk vent-proximal sedimentary-exhalative deposit,Posht-e-Badam Block,Central Iran

The Koushk zinc–lead deposit in the central part of the Zarigan–Chahmir basin, central Iran, is the largest of several sedimentary–exhalative (SEDEX) deposits in this basin, including the Chahmir, Zarigan, and Darreh-Dehu deposits. The host-rock sequence consists of carbonaceous, fine-grained black siltstone with interlayered rhyolitic tuffs. It corresponds to the upper part of the Lower Cambrian volcano-sedimentary sequence that was deposited on the Posht-e-Badam Block due to back-arc rifting of the continental margin of the Central Iranian Microcontinent. This block includes the late Neoproterozoic metamorphic basement of the Iran plate, overlain by rocks dating from the Early Cambrian to the Mesozoic. Based on ore body structure, mineralogy, and ore fabric, we recognize four different ore facies in the Koushk deposit: (1) a stockwork/feeder zone, consisting of a discordant mineralization of sulphides forming a stockwork of sulphide-bearing dolomite (quartz) veins cutting the footwall sedimentary rocks; (2) a massive ore/vent complex, consisting of massive replacement pyrite, galena, and sphalerite with minor arsenopyrite and chalcopyrite; (3) bedded ore, with laminated to disseminated pyrite, sphalerite, and galena; and (4) a distal facies, with minor disseminated and laminated pyrite, banded cherts, and disseminated barite. Carbonatization and sericitization are the main wall-rock alterations; alteration intensity increases towards the feeder zone. The δ³⁴S composition of pyrite, sphalerite, and galena ranges from?+6.5 to?+36.7‰. The highest δ³⁴S values correspond to bedded ore (+23.8 to?+36.7‰) and the lowest to massive ore (+6.5 to?+?17.8‰). The overall range of δ³⁴S is remarkably higher than typical magmatic values, suggesting that sulphides formed from the reduction of seawater sulphate by bacteriogenic sulphate reduction in a closed or semi-closed system in the bedded ore, whereas thermochemical sulphate reduction likely played an important role in the feeder zone. Sulphur isotopes, along with sedimentological, textural, mineralogical, and geochemical evidences, suggest that this deposit should be classified as a vent-proximal SEDEX ore deposit.     

云南会泽麒麟厂铅锌矿床构造地球化学及定位预测

在论述构造地球化学基本理论与方法的基础上，深入讨论了会泽麒麟厂铅锌矿床构造地球化学特点，认为构造地球化学异常集中区是进行隐伏矿定位预测的重要依据，提出了1571中段44－62剖面线间的深部等重点定位找矿靶区，已被验证工程证实，新发现八号隐伏矿体。该方法对隐伏矿定位预测和评价具有重要指导意义。     

基于Vulcan软件的山东莱州留村金矿区三维建模及资源量估值北大核心CSCD

留村金矿位于山东莱州市城区西南12 km的留村断裂带上,是发育于古老变质岩中的小型石英脉型金矿。为深入研究该矿区地层、构造与矿体在地下的延伸分布情况,加快后续数字化矿山建设,山东黄金集团应用Vulcan矿业软件对矿区开展三维地质建模。在收集相关地质实物资料的基础上,通过建立地质数据库、数据转换、地质解译等系列功能操作建立了矿区地表、岩体、构造及矿体模型,并对其进行任意剖割划分,实现了矿区地层岩性、地质构造、矿体的三维可视化,促进了本区矿体赋存规律的研究以及三维空间的成矿预测。同时利用软件强大的数据处理功能对资源量进行估值,本次估值的金资源量为1984.18 kg,与原详查报告中提交的金资源量2009.34 kg误差仅为1.25%。经估值后的每个矿块段都被赋予了精确的资源量数据,为后续矿山采矿设计与排产计划提供了准确的数据支撑,助力实现数字化、智能化矿山建设。     

西藏玛圭铅锌多金属矿成矿地质特征及找矿远景

西藏玛圭铅锌多金属矿在冈底斯铅锌银成矿带已发现的矽卡岩型多金属矿床中处于最西段。通过目前的预查工作,在矿区内共发现有14条矿体,初步预测可达到中-大型矿床规模。冈底斯中东段目前研究程度已较高,而西段与之具有相同的良好的矽卡岩型多金属矿成矿地质条件,但发现的矿床却很少。玛圭矿床的发现为该成矿带向西延伸和扩大规模提供了依据,并增加了进一步向西寻找同类型矿床的信心。     

用于多接收器等离子体质谱铜铁锌同位素测定的离子交换分离方法

采用AGMP-1阴离子交换树脂，分别以7mol／L HCl、2mol／L HCl、0．5mol／L HNO3作为淋洗剂，可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明，Cu、Fe、Zn回收率均接近100％，标准溶液在离子交换分离前后同位素组成一致，可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。     

Interaction of trace metals with natural particle surfaces: Comparison between adsorption experiments and field measurements

The distribution of the metal ions Zn and Pb between particulate and dissolved phase in river Glatt was studied by field measurements and compared with calculated simulations, using parameters obtained by adsorption experiments with natural suspended particulate material. Differences in distribution coefficients obtained from field data are observed in function of the sampling locations and of the composition of the particulate matter.Experiments in which metal ion solutions are titrated with a suspension of natural particles and analyzed by anodic stripping voltammetry, are interpreted in terms of binding capacities and conditional stability constants of Zn and Pb with the surface sites. Binding constants of a particular metal ion varied very little for all samples. We obtained mean values for the conditional average complex formation constants at pH 8 of: log^cond K _Pb = 9.44 ± 0.18 and log^cond K _Zn = 8.17 ± 0.20. At this pH, binding capacities of 5 10^–3 – 1.7 10^–2 mol/kg of particles were obtained for samples collected at different locations and times; organic material, iron and manganese oxides are considered to be the main components that control the adsorption to the particles.Distribution coefficients are calculated from the experimentally obtained binding capacities and conditional stability constants. Calculated distribution coefficients for Zn agree with those obtained from the field data and are not very sensitive to changes in the composition of the solution. Good agreement was obtained for lead as well; for some samples it was important to take two types of sites with different affinity into consideration.     

Reactive flow models of the Anarraaq Zn–Pb–Ag deposit,Red Dog district,Alaska

The Red Dog ore deposit district in the Brooks Range of northern Alaska is host to several high-grade, shale-hosted Zn + Pb deposits. Due to the complex history and deformation of these ore deposits, the geological and hydrological conditions at the time of formation are poorly understood. Using geological observations and fluid inclusion data as constraints, numerical heat and fluid flow simulations of the Anarraaq ore deposit environment and coupled reactive flow simulations of a section of the ore body were conducted to gain more insight into the conditions of ore body formation. Results suggest that the ore body and associated base metal zonation may have formed by the mixing of oxidized, saline, metal-bearing hydrothermal fluids (<200°C) with reducing, HS-rich pore fluids within radiolarite-rich host rocks. Sphalerite and galena concentrations and base metal sulfide distribution are primarily controlled by the nature of the pore fluids, i.e., the extent and duration of the HS⁻ source. Forward modeling results also predict the distribution of pyrite and quartz in agreement with field observations and indicate a reaction front moving from the initial mixing interface into the radiolarite rocks. Heuristic mass calculations suggest that ore grades and base metal accumulation comparable to those found in the field (18% Zn, 5% Pb) are predicted to be reached after about 0.3 My for initial conditions (30 ppm Zn, 3 ppm Pb; 20% deposition efficiency).