我国天然锌铜金属互化物的发现和特征

锌、铜金属互化物是罕见的天然合金矿物,由锌、铜两种元素组成。由于形成条件、环境不同及矿物中锌、铜元素含量不同,形成系列锌、铜金属互化物。经过对我国近二十年来发现的各类型天然锌、铜金属互化物产出的地质特征,物理、化学及光学性质进行的系统研究发现,目前我国在不同的地质体中出现多种不同类型的锌、铜金属互化物,该类矿物主要形成于高温、还原且缺硫的条件下,多数与造岩矿物共生,而与多数金属硫化物形成条件不同。     

甘肃省肃南县雪泉铜(锌)矿床找矿勘查思路探讨

雪泉塞浦路斯型富铜(锌)块状硫化物矿床地处北祁连山西段奥陶纪弧后盆地火山岩带内,矿床的形成受火山热液喷流中心控制,每个喷流中心的成矿遵循"蘑菇"状的成矿模式,目前已发现矿区存在多个热液喷流中心,与此相对应的矿体表现出呈群出现,分段集中的特点。结合矿区地形特点,笔者提出矿床下一步的找矿勘查应按照"面上展开——利用地质测量、物探扫面进行探寻热液喷流中心;分段深入——在每个热液喷流中心主要利用硐探工程进行探矿验证"的思路开展工作。     

用离子色谱法测定金矿区水样中常规无机离子

利用DX－120离子色谱仪进行阴阳离子的精密度和准确度测定，100mg/L时相对标准偏差范围为1．00％－3．80％，回收经95．83％－105．00％；5mg／L时相对标准偏差范围为1．18％－4．57％，回收率92．40％－103．20％，完全达到实际要求。用该离子色谱仪测定甘肃阳山金矿山水样中常规无机离子，数据表明该区域水质较好，所测离子浓度都未超过饮用水标准。     

内蒙古自治区翁牛特旗姚家店铅锌矿地质特征

内蒙古自治区翁牛特旗姚家店铅锌矿矿床为一受NW向断裂带构造控制的中低温岩浆热液充填交代型铅锌矿床,形成于燕山晚期,矿体呈脉状产于二叠世额里图组安山质凝灰岩之构造破碎带内,形态产状严格受断裂构造控制。矿石为硅化、黄铁矿化碎裂岩型铅锌矿石。     

4 种重金属离子对中华鳖(Trionyx sinensis)稚鳖的急性致毒效应

以5日龄中华鳖稚鳖为实验动物,采用静水停食实验法,在水温(27.4±1.3)℃条件下,开展了Hg2+、Cr6+、Cu2+、Zn2+对中华鳖稚鳖的急性毒性和加和等毒性强度联合毒性试验。结果表明,4种重金属离子对中华鳖稚鳖均呈现以蓄积为主导的急性毒发效应,Cr6+、Zn2+对中华鳖稚鳖的急性致毒高峰期明显滞后于Hg2+、Cu2+;4种重金属离子毒性大小依次为Hg2+、Cu2+、Cr6+、Zn2+,其对中华鳖稚鳖96h的半致死质量浓度分别为5.98、16.42、28.90和91.88mg/L;所构建的中华鳖稚鳖累积死亡概率与重金属质量浓度和实验时间之间的数学模型,以及半致死时间-质量浓度回归方程,可作为侦查和分析重金属离子排放时间和致中华鳖稚鳖大量死亡时间的重要计算工具;Hg2+、Cr6+、Cu2+、Zn2+离子两两组合在加和等毒性强度下对中华鳖稚鳖96h联合急性毒性所呈现的致毒特征与离子种类及其毒性强度匹配情形密切相关。     

陶瓷釉的矿物学特征研究

应用原子吸收光谱（AAS）,X射线衍射（XRD）和 电子自旋共振（ESR）方法对工业及民用陶瓷釉进行了研究。实验表明：陶瓷釉的主要化学 成分为Al2O3、SiO2,少量为K2O、Na2O、MgO、CaO和微量的TiO2、Fe2O3 、S等;矿物相有石英、伊利石、方解石、长石、高岭石和滑石等。生釉经不同温度焙烧后 ,无论是化学成分、矿物相、微量杂质元素的价态及含量均发生了变化。讨论了在不同温度下的化学组分、含量、生成矿物相的种类以及杂质离子在矿物内部的电荷转移状态。这些结果对改进陶瓷釉的配方,探索最佳焙烧温度,生产高质量的陶瓷产品,有着实际的指导意义 。     

等离子体片离子与太阳风及地磁条件的关联研究

本文根据搭载于Cluster卫星的CIS/CODIF和RAPID仪器的观测数据,统计研究了等离子体片中的H+、O+离子在磁暴期间的时间变化特性,及其对太阳风条件的响应.观测结果表明：(1) 磁暴开始前,O+离子（0~40 keV）数密度保持在较低水平.随着磁暴的发展,O+数密度缓慢上升,其峰值出现在Dst极小值附近;H+离子(0~40 keV)数密度在磁暴开始之前的较短时间迅速增加并达到峰值,在磁暴开始之后迅速降低,并在整个主相和恢复相期间保持在相对较低水平.更高能量的离子则在磁暴开始后迅速增多,并在低能O+离子达到峰值之前达到峰值.因此我们推测磁暴初期从等离子体片注入环电流的主要是H+离子,主相后期O+离子可能扮演更为重要的角色.(2)在地磁活动时期,太阳风密度和动压强与等离子体片中的H+、O+数密度存在一定相关性.等离子体片中的H+离子对北向IMF Bz较为敏感,而IMF Bz南向条件下更有利于太阳风参数对等离子体片中O+数密度的影响.在地磁活动平静期,太阳风条件对等离子体片中的离子没有明显影响.     

上海洋山建港后港域夏季水文泥沙状况分析

对2007年9月17-26日在上海洋山港海域固定观测点(平均水深13 m)观测得到的水文泥沙要素,以及悬沙和底质样品分析.分析结果为:1)港域有效波高0.21-1.37 m(风速0.6～14.0 m/s),平均0.61 m(平均风速5.5 m/s).平静天气(平均风速小于5.0 m/s)下,波高随水深变化,两者的相关系数为0.899;而在强风天气下,波高受风况控制.2)最大表层流速超过2.00 m/s.大潮涨潮流占优势,小潮时落潮流占优势;与北岛链汉道封堵前相比,大潮涨、落潮平均流速分别减小15%和30%,小潮涨、落潮平均流速均减小30%～40%.各层余流均为西北方向,与涨潮流方向一致;垂向平均余流速0.11 cm/s,表层达0.25 m/s.3)离底高程1.35 m层和0.35m层最大悬沙浓度均大于3 kg/m3,两层平均悬沙浓度分别为0.89和0.95 kg/m3.无论大潮还是小潮涨潮悬沙浓度均大于落潮,这种现象在大潮时更为显著,潮周期中最大悬沙浓度出现在涨急.与工程前相比悬沙浓度明显降低,大、小潮降低均达20%.4)港区底质平均粒径9.0μm,工程后有变细的趋势.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.