蛭石精矿的有机改性试验

采用十六烷基三甲基溴化铵(HDTMAB)对蛭石精矿进行了有机改性,利用X射线衍射法(XRD)、红外光谱(IR)、差示扫描量热法(DSC)和热失重分析(TG)对蛭石精矿和有机改性蛭石进行了表征。实验结果表明,当反应液中蛭石与水的质量比为1∶10、反应温度在60~70℃时,HDTMAB的阳离子HDTMA进入绝大部分蛭石晶粒的晶层,将蛭石的晶层间距撑大,蛭石的(001)晶面间距d001从1.45986 nm增大到3.70134 nm。HDTMA进入了单晶颗粒之间,将蛭石颗粒分散成单晶颗粒。     

Reactive flow models of the Anarraaq Zn–Pb–Ag deposit,Red Dog district,Alaska

The Red Dog ore deposit district in the Brooks Range of northern Alaska is host to several high-grade, shale-hosted Zn + Pb deposits. Due to the complex history and deformation of these ore deposits, the geological and hydrological conditions at the time of formation are poorly understood. Using geological observations and fluid inclusion data as constraints, numerical heat and fluid flow simulations of the Anarraaq ore deposit environment and coupled reactive flow simulations of a section of the ore body were conducted to gain more insight into the conditions of ore body formation. Results suggest that the ore body and associated base metal zonation may have formed by the mixing of oxidized, saline, metal-bearing hydrothermal fluids (<200°C) with reducing, HS-rich pore fluids within radiolarite-rich host rocks. Sphalerite and galena concentrations and base metal sulfide distribution are primarily controlled by the nature of the pore fluids, i.e., the extent and duration of the HS⁻ source. Forward modeling results also predict the distribution of pyrite and quartz in agreement with field observations and indicate a reaction front moving from the initial mixing interface into the radiolarite rocks. Heuristic mass calculations suggest that ore grades and base metal accumulation comparable to those found in the field (18% Zn, 5% Pb) are predicted to be reached after about 0.3 My for initial conditions (30 ppm Zn, 3 ppm Pb; 20% deposition efficiency).     

Post-mine metal transport and attenuation in the Keno Hill mining district, central Yukon, Canada

 The Keno Hill mining district in central Yukon was the second largest silver producer in Canada with mines operating from 1913 to 1989 on more than 65 vein silver deposits. The seven and a half decades of mining activities have generated large volumes of mine waste disposed on the land surface, resulting in elevated metal contents in numerous small drainages. To assess the extent of metal mobilization, old mine workings and the associated mine waste were examined and the water courses draining to a major river valley sampled. The results of field observations and an array of water and sediment analyses led to three major conclusions. 1. Acid mine drainage is not widespread because of galvanic protection of pyrite from oxidative dissolution and neutralization by carbonates in the country rock. 2. Mechanisms operative to limit aqueous metal transport in small streams in the district include cryogenic precipitation, coprecipitation and sorption. 3. The near-surface concentration of metals limits the options of waste disposal in future mining developments due to potential metal-leaching problems. Received: 12 December 1995 · Accepted: 26 March 1996     

4,4′-二[(8-羟基喹啉)偶氮]-3,3′-二甲基联苯分光光度法测定锌

研究了新显色剂4,4,＇-二[(8-羟基喹啉)偶氮]-3.3＇-二甲基联苯(D-HQADMB)与Zn(Ⅱ)的显色反应条件。在CPC存在下的pH7.5～8.5缓冲介质中、Zn(Ⅱ)与D-HQADMB形成稳定的深红色配合物,组成比为Zn(Ⅱ):D-HQADMB=1:2,λ_(max)=550nm,表观摩尔吸光系数为7.19×10~4 L·mol~(-1)·cm~(-1),Zn量在0～1.25μg/ml范围内服从比尔定律。方法可用于测定矿样中的Zn。     

浅谈微粒金刚石在找矿中的作用

微粒金刚石是指粒度<0.5mm的金刚石,用作找矿指示矿物可帮助发现不含或少含其他找矿指示矿物的金刚石原生矿。找矿中遇到可疑的风化岩体,筛取<4mm的泥砂,细砾样品40kg,运回室内加工处理,淘洗时水中应加入肥皂水,使泥水表面起一层皂泡,以防微粒金刚石悬浮进入废弃的尾泥中。磁选后对<0.5mm无磁性精矿采用磁液電力分离仪选取微粒金刚石。     

掺铝氧化锌厚膜制备及其对三甲胺和海产品鲜度的敏感性

用烧结法制备掺铝氧化锌厚膜，把氧化锌粉末分别同０％，１％，３％，５％的Ａｌ２Ｏ３粉末机械研磨混合均匀，在１１００℃下烧３ｈ，再同粘合剂，有机溶剂混合制成浆料，用刮刀法在氧化铝基片上浆料制成膜，在１００℃下烘干后再经１１００℃烧结２ｈ。膜的灵敏度的测量方法是将膜放在玻璃管内加热到测量温度，测量膜暴露在一定浓度ＴＭＡ气体或由牡蛎放出的气体时电阻值的变化。测量温度为２００，２５０，３００℃和４００℃，Ｔ     

Marine diatom Thalassirosira weissflogii nutrient drawdown and its physiological status variation challenged to zinc and cadmium exposure

The uptake of zinc and cadmium by a species of marine diatom Thalassirosira weissflogii and the nutrient variation (phosphorus and silicon) in the culture medium were estimated when exposed to zinc and cadmium stress under controlled laboratory conditions.It was found that low cadmium addition could stimulate the culture to grow with a relatively high rate and exert its toxicity at the elevated concentration.The cellular uptake of zinc and cadmium by the diatom varied in the ranges of 1.21~3.75 and 0.060~0.629 fmol per cell respectively in the whole cultivation period.The mean cellular phosphorus and silicon drawdowns were constant with 0.26~0.42 and 0.30~0.46 pmol per cell respectively in those healthy cultures.It is illustrated that the algal cells can adjust some physiological mechanisms to decrease metal accumulation and keep metal homeostasis in the organism.The correlation analysis results further indicate that the cellular cadmium uptake might be closely related with the cellular phosphorus, silicon drawdown and the growth rate of diatom (P<0.05, 0.001, 0.01); and the cultures grow better in good conditions, the lower amount of phosphorus, silicon materials are consumed by a single cell to keep a high efficiency of utilization.     

含羟基西佛碱型大环冠醚铜(Ⅱ)、锌(Ⅱ)配合物的合成与表征

利用模板法合成 1种新的含醇羟基西佛碱型大环冠醚 L (7,11-二氮杂 - 3,15 -二氧杂 - 4 ,5 ;8,10 ;13,14-三苯并环十六 - 6 ,11-二烯 - 1-醇 )的铜、锌配合物。经元素分析 ,IR、MS分析确定配合物的组成 M(L2 ) (NO3 ) 2 及其配位情况 ,由模板反应得到 [1+ 1]型西佛碱大环化合物。 DMF溶液中的电导数据证实它们均属非电离型 ,并运用 TG- DTA分析比较铜、锌配合物的热稳定性。     

Geodynamically indicated targeting strategy for shale‐hosted massive sulfide Pb–Zn–Ag mineralisation in the Western Fold Belt,Mt Isa terrane

There is ongoing debate with respect to the genetic models for shale‐hosted massive sulfide Pb–Zn–Ag deposits contained in the Palaeoproterozoic to Mesoproterozoic intracontinental Isa Superbasin in the Western Fold Belt, Mt Isa terrane. Favourable sites of mineralisation can be predicted based on understanding the tectonic setting of the Isa Superbasin, the structural controls of mineralisation and the chemically favourable environments for ore deposition. Shale‐hosted massive sulfide Pb–Zn–Ag deposits are hosted in successions deposited during the dominant sag‐phase of the Isa Superbasin. These deposits are localised at the intersections of major basin‐scale extensional faults and are hosted in both shallow‐marine and deeper water carbonaceous shales that are characteristically anoxic and located near or at maximum flooding surfaces. All major shale‐hosted massive sulfide Pb–Zn–Ag deposits are located to the west of the Mt Isa Rift (ca 1710–1670 Ma). This spatial association is explained by an asymmetrical lithosphere extension model for the evolution of the Isa Superbasin. Elevated geothermal gradients at the location of maximum subcrustal lithospheric thinning to the west of the Mt Isa Rift may have driven the migration of basinal brines. Increased subsidence at this location produced favourable anoxic sedimentary horizons for metal precipitation during orebody formation.     

东北水稻产区土壤-作物系统锌元素生态地球化学特征

以东北主要水稻产区为研究区,以土壤-作物系统锌元素地球化学为研究对象,进行了系统的野外调查和土壤、水稻样品的采集、测试及统计分析。研究结果表明,东北水稻产区土壤表层锌含量介于11.01~94.95 mg/kg之间,平均值为43.97 mg/kg,锌含量总体处于缺乏状态;籽实锌含量介于14.27~36.92 mg/kg之间,平均值为24.70 mg/kg,样品中97.56%的籽实锌含量满足人体需要从谷物摄取到的量,品质优良;水稻籽实锌生物富集系数从高到低依次为草原风沙土、草甸土、盐渍水稻土、黑土、淹育水稻土、水稻土、暗棕壤、草甸白浆土;水稻籽实中锌元素的富集与土壤表层硼、锗、铋、镉、铅、锂、铍等元素含量呈现不同程度的显著负相关。