A multi-scale study on land use and land cover quality change: The case of the Yellow River Delta in China

This paper presents a case study of the Yellow River Delta in China, to trace land use and land cover changes during the past 20 years, with an emphasis on land quality changes. Three sets of data are used in this case study: remote sensing data derived from satellite images; crop yield data from statistics; and soil data collected by the researchers in the field. Our study reveals that at the regional scale, LUCC has taken place in a positive direction: vegetation cover has been expanding and crop yields per hectare have been on rise. However, while the overall eco-environment has improved, the improvement is uneven across the Delta region. At local levels, some areas show signs of increased salinization and declining organic content. Both natural forces and human activities are responsible for the LUCC, but human activities play a more important role. While some impacts of human activities are positive, the damages are often long-lasting and irreversible. We also conclude that it is necessary to use both macro data (such as remote sensing data) and micro data (data collected in the field) to study land quality change. The former are efficient in examining land quality changes at the regional scale, the latter can serve to verify ground patterns revealed from macro data and help to identify local variations, so as to get a comprehensive understanding of LUCC and promote sustainable land use and land management. This revised version was published online in July 2006 with corrections to the Cover Date.     

Ordovician Graptolite Rhabdosome Complication and Its Implications on Sea Level Changes

A total of four times of rhabdosome complication events, i.e., the lateral branching of graptolite stipes during the Late Middle Ordovician, the secondary branching of graptolite stipes at the earliest Upper Ordovician, the early Qiantangjiangian of Upper Ordovician and the middle Qiantangjiangian, respectively, is discussed in this paper. These events and other adaptation events demonstrate close relationships between a diverse graptolite fauna and sea level changes, and consequently can be employed to study sea level fluctuations. It is safe to conclude that the complication of rhabdosome started at the maximum flooding surface (MFS) and terminated at the beginning of regression.     

Physical properties of ultrahigh-pressure metamorphic rocks from the Sulu terrain, eastern central China: implications for the seismic structure at the Donghai (CCSD) drilling site

About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm³. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

山东省胶莱盆地东北缘宋家沟金矿地质特征及其成因初探

山东省宋家沟金矿位于胶莱盆地东北缘 ,产于莱阳群林寺山组断裂破碎带中。牟—即断裂带为切割莱阳群的断裂 ,对金矿起控制作用。早白垩纪晚期的火山—岩浆活动为深部含金热液的运移提供了通道 ,并在其有利的构造部位沉淀成矿。稀土元素特征和氧、硫同位素特征亦说明宋家沟金矿的物质来源以深源为主 (幔源及下地壳中的金 ) ,是早白垩世晚期的火山—岩浆活动作用的结果。     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

Cu–Fe Bearing Zinc Sulfide from Laloki Stratabound Massive Sulfide Deposit, Papua New Guinea: Chemical Characterization

Abstract: A strange, unidentified, Cu-Fe bearing zinc sulfide occurs in the Laloki massive sulfide deposit, Papua New Guinea. The mineral is optically uniform in texture but is chemically variable and zoned even within a single grain. Copper contents vary from 0.1 up to 8.85 wt%. Iron reaches 18.31 wt% at maximum and decreases as Cu increases. It is remarkable, however, that the total Fe+Cu remains essentially unchanged between roughly 18 and 20 wt%. Zn and S are least variable, giving 45.85–47.84 wt% and 33.48–34.58 wt%, respectively. Other trace elements such as Cd and Mn are in general less than 0.2 wt%. It is strongly suggested that the mineral in question constitutes a unique Fe-Cu substitutional solid solution series belonging essentially to the Zn–Fe–Cu–S system.
The ideal chemical formula of the solid solution series can well be presented as Zn₁₀(Fe, Cu)₅S₁₅ or Zn₂(Fe, Cu)S₃, where Fe is always greater than Cu. It is intriguing that chalcopyrite blebs are recognizable restrictively only in nearby portions of the Cu-rich end member with the ideal composition close to Zn₁₀Fe₃Cu₂S_15. It has been confirmed by vacuum-sealed heating experiments that this mineral is decomposed to produce chalcopyrite and Fe-bearing normal sphalerite at temperatures below 200C. This would provide another evidence for the existence of such distinct phase as suggested here.     

中原地区M≥6级地震后的减(增)震效应

通过对中原地区1500年－2000年所有19次M≥6级地震后空间图像的分析，初步认为M≥6级地震发生后平均63年内，在距原震中平均176km内无M≥5级地震发生，全部19次震例均呈现出内部减震效应，而在其外围出现地震增强的活动图像特征，增震效应对应率为72％。这种强震后的减（增）震效应，不仅对地震危险性分析，而且对1年尺度以上的地震趋势预测均有一定的意义。     

MODELING THE FATE AND TRANSPORT OF HYDROPHOBIC ORGANIC COMPOUNDS IN AN UNSTEADY RIVER-ESTUARINE SYSTEM

1 INTRODUCTION Extensive literature (Brown et al., 1985; Sawhney et al., 1981; Bierman and Swain, 1982; Connolly, 1980; Lopez-Avila and Hites, 1980; O扖onnor, 1988) described lots of sorbed pollutants or toxic substances in bed sediments of rivers, even after the effluent was halted for a long time. This is particularly true for hydrophobic organic compounds that can be sorbed on the particles and accumulated in the river bed sediments (Karickhoff et al., 1979). Pollution events of…     

Crystal-rich mass flow deposits related to the eruption of a sublacustrine silicic cryptodome (Early Permian Collio Basin, Italian Alps)

Sedimentological, granulometric and petrographic data are presented from a detailed study on a crystal-rich mass flow deposit, which is presumably related to the eruption of a sublacustrine cryptodome. The deposit forms a prominent intercalation in the Lower Permian Collio Formation in the Italian Alps north of Brescia. Outcrops of the 10–20-m-thick volcaniclastic deposit (Dasdana I Beds, DB) can be traced over 12 km from east to west. The DB consists of a thick, crystal-rich, sandy–gravelly lower subunit representing a sequence of amalgamated Bouma-a(b) divisions overlain by a thin, well-bedded, sandy–muddy subunit that is rich in outsize porphyritic silicic fragments. Modal and computer-aided image analyses reveal that the crystal-rich lower subunit contains up to 80% of volcanogenic crystals. Some samples contain up to 60% of porphyritic fragments, which have a phenocryst content of about 20%. The wide textural range from cryptocrystalline, poikilomosaic, to rarer medium-grained granophyric groundmass, the irregular to lensoid shapes of the porphyritic fragments, and the presence of basement and sedimentary clasts suggest that the DB originated from a sublacustrine eruption of a partially extrusive cryptodome (ca. 1.6 km³). Two other porphyritic felsic cryptodomes (Dosso dei Lupi, Dosso del Bue), described briefly here, emplaced into the Collio Formation sometime after the DB event, and expose flat bases and tilted sediments at their sides. Textures observed in these domes are comparable to those found in the DB porphyritic fragments.