新疆西天山查岗诺尔铁矿床环带石榴子石和绿帘石的发现及意义

查岗诺尔铁矿是新疆西天山阿吾拉勒铁矿带内的重要大型铁矿床之一。矿体赋存在下石炭统大哈拉军山组安山质火山岩中,与普遍发育的石榴子石化、阳起石化和绿帘石化时空关系密切。石榴子石和绿帘石分属不同热液成矿阶段,它们均发育丰富的环带结构,具体表现为明显地颜色、干涉色、背散射图像及成分（FeO、Al₂O₃、SiO₂、MnO、TiO₂）等差异性。石榴子石具有2个世代、3个类型。早世代石榴子石（Grt1和Grt2）产于块状石榴子石-磁铁矿蚀变岩,呈褐黄色,粒度较细,发育核-边结构,呈非均质性,显示异常干涉色,其核部（Grt1-c）均匀相对富钙铝榴石（Gro_51-53And_41-43Spr_4-8）,而边部（Grt1-r）发育振荡成分环带,总体相对富钙铁榴石（Gro_18-35And_60-77Spr_4-6）;Grt2核部（Grt2-c）呈均质性,为钙铁榴石（And_99-100Spr_0-1）,边部显异常干涉色,发育振荡成分环带,为钙铝铁榴石（Gro_34-54And_38-61Spr_6-9）。晚世代的石榴子石（Grt3）以细脉状或角砾胶结物形式分布,呈红褐色,自形粗粒结构,显非均质性,发育振荡成分环带,端员组分总体以钙铁榴石为主,次为钙铝榴石（Gro_27-43And_50-68Spr_3-8）。石榴子石结构和元素含量变化表明,早期石榴子石形成于弱氧化-氧化、中性-碱性流体体系,其中向边部生长过程,由于新注入流体以及周期性压力汇聚和释放,体系的氧逸度、pH值呈振荡变化;晚期石榴子石形成于弱氧化、弱碱性、动荡的开放流体环境。绿帘石发育3个世代（Ep1、Ep2和Ep3）。Ep1发育核-边结构,核部（Ep1-c）均匀无环带,X_Fe值（X_Fe=Fe³⁺/（Al+Fe³⁺）,原子比值）为0.19~0.21,w（MnO）为0.05%~0.18%,w（TiO₂）为0.10%~0.12%,生长边（Ep1-r）多发育振荡环带,X_Fe值为0.26~0.29,w（MnO）为0.01%~0.14%,w（TiO₂）为0.19%~0.26%。Ep2沿Ep1-r边缘生长,不均匀且经历了溶解-再沉淀过程,X_Fe值为0.15~0.20,w（MnO）为0.42%~1.19%,w（TiO₂）为0.02%~0.07%。Ep3呈柱状或不规则粒状交代Ep2、贴近或穿切Ep1-r生长,较均匀、无环带结构,X_Fe值为0.28~0.37,w（MnO）为0.12%~0.77%,w（TiO₂）为0.02%~0.10%。绿帘石成分变化表明,从Ep1-c到Ep1-r,到Ep2,再到Ep3,流体体系氧逸度经历了先增加,后降低,再升高的变化过程。同时,流体成分也在变化,先从相对贫Ti和Mn向相对富Ti贫Mn演化,而后又变为富Mn贫Ti。因此,在热液磁铁矿矿化阶段,查岗诺尔铁矿的成矿热液的物理-化学环境是不断变化的。研究显示,石榴子石和绿帘石结构和成分研究可以刻画热液成矿系统的流体演化历史。     

Isotopic tracers for water masses in the coastal region of eastern Hokkaido

In this study we used two stable isotopes, δ¹³C and δ¹⁸O, for water mass classification in the coastal region off eastern Hokkaido. δ¹³C* values, which were corrected for the biological effect, and δ ¹⁸O values up to 300 m depth suggested that the isotopic character of the onshore and offshore water in the southern Okhotsk Sea, the Nemuro Strait and the western North Pacific could be explained by the mixing of three source waters: the Oyashio water (OYW), Soya Warm Current water (SWCW) and East Sakhalin Current water (ESCW). In summer, δ ¹³C*-δ ¹⁸O plots indicated mixing between SWCW from the southern Okhotsk Sea and OYW in the Pacific coast of southeastern Hokkaido, while temperature-salinity plots of the onshore water showed minimal difference from the offshore OYW. In winter, on the other hand, the mixed water of ESCW and OYW (or SWCW) appeared in the Pacific coastal region, distributed as cold, low salinity onshore water. Finally, we estimated mixing ratios of OYW, SWCW and ESCW in the coastal region of western North Pacific using their mean values of δ ¹³C* and δ ¹⁸O as endmembers. These results suggest seasonal and yearly changes of water mass combination en route from the southern Okhotsk Sea to the western North Pacific.     

辽西义县组与冀北大店子组、西瓜园组的对比

辽西义县组与冀北大店子组、西瓜园组的对比关系一直存有分歧.综合分析前人生物地层学资料,并结合同位素年代学,提出老公沟层、业南沟层、尖山沟层和冀北滦平盆地大店子组1~2段及3~4段下部相当,大康堡层可与大店子组3~4段上部对比,金刚山层与西瓜园组大致相当.     

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.     

川东南—鄂西渝东地区下古生界页岩气勘探前景

中上扬子地台发育2套重要的海相深灰色—黑色页岩,分别为下寒武统牛蹄塘组和上奥陶统五峰组—下志留统龙马溪组,主要由富含黄铁矿、有机质或生物化石的黑色炭质页岩组成,厚度大、分布广。牛蹄塘组页岩有机质演化程度高、埋藏相对较深、钻井无天然气显示; 龙马溪组页岩有机质演化程度相对中等、埋藏深度适度、钻井天然气显示丰度高,特别是志留系其它粉砂岩层段可产工业性气流。因此,下志留统页岩更有利于研究区页岩气的勘探和开发,更加适合作为中国南方页岩气战略先导区的重点目标勘探层位。总体上,两套页岩在川东南—鄂西渝东地区出露范围广,有利于针对页岩展开相关研究,特别是背斜和向斜的翼部区是页岩气勘探最为有利的地区。     

新疆洛浦县和巴楚县晚石炭世—早二叠世牙形石动物群及其地层意义

本文依据对新疆洛浦县阿其克和巴楚县小海子剖面牙形石动物群研究，详细探讨了塔里木盆地西部石炭－二叠系界线的划分和克孜里奇曼组、南闸组和康克林组上部地层的归属问题；指出从牙形石的发展和演化看，上述地层应属于下二叠统。     

Sea surface temperature and salinity reconstruction based on stable isotopes and Mg/Ca of planktonic foraminifera in the western Pacific Warm Pool during the last 155 ka

Changes in sea surface temperature(SST), seawater oxygen isotope(δ 18 O sw), and local salinity proxy(δ 18 O sw-ss) in the past 155 ka were studied using a sediment core(MD06-3052) from the northern edge of the western Pacifi c Warm Pool(WPWP), within the fl ow path of the bifurcation of the North Equatorial Current. Our records reveal a lead-lag relationship between paired Mg/Ca-SST and δ 18 O during Termination II and the last interglacial period. Similarity in SST between our site and the Antarctic temperature proxy and in CO 2 profi le showed a close connection between the WPWP and the Antarctic. Values of δ 18 O sw exhibited very similar variations to those of mean ocean δ 18 O sw, owing to the past sea-level changes on glacial-interglacial timescale. Calculated values of δ 18 O sw-ss refl ect a more saline condition during high local summer insolation(SI) periods. Such correspondence between δ 18 O sw-ss and local SI in the WPWP may refl ect complex interaction between ENSO and monsoon, which was stimulated by changes in solar irradiance and their infl uence on the local hydrologic cycle. This then caused a striking reorganization of atmospheric circulation over the WPWP.     

桂西念寅铝土矿稀土元素地球化学特征及物质来源分析

[摘要]桂西靖西念寅铝土矿不整合于早二叠茅口灰岩之上,分析其稀土元素地球化学特征对研究其物质来源具有重要意义。对念寅原生铝土矿、堆积型铝土矿及其围岩的11个样品进行稀土元素含量测试,并同靖西、平果等地各类铝土矿、茅口灰岩等样品对比分析,结果表明: （1）念寅铝土矿主量元素主要SiO₂、Fe₂O₃、Al₂O₃、TiO₂组成,Al₂O₃与Fe₂O₃和SiO₂呈负相关;（2）念寅铝土矿球粒陨石标准化曲线与茅口灰岩配分曲线趋势一致,具有ΣREE富集、LREE与HREE分异且LREE相对富集、Eu负异常等显著特征;（3）念寅铝土矿显示出被动大陆边缘地带海相沉积的典型特征,原生铝土矿成矿物质来源主要为下伏的茅口灰岩。     

Seismic structure of the Helan–Liupan–Ordos western margin tectonic belt in North-Central China and its geodynamic implications

We study high-resolution three-dimensional P-wave velocity (Vp) tomography and anisotropic structure of the crust and uppermost mantle under the Helan–Liupan–Ordos western margin tectonic belt in North-Central China using 13,506 high-quality P-wave arrival times from 2666 local earthquakes recorded by 87 seismic stations during 1980–2008. Our results show that prominent low-velocity (low-V) anomalies exist widely in the lower crust beneath the study region and the low-V zones extend to the uppermost mantle in some local areas, suggesting that the lower crust contains higher-temperature materials and fluids. The major fault zones, especially the large boundary faults of major tectonic units, are located at the edge portion of the low-V anomalies or transition zones between the low-V and high-V anomalies in the upper crust, whereas low-V anomalies are revealed in the lower crust under most of the faults. Most of large historical earthquakes are located in the boundary zones where P-wave velocity changes drastically in a short distance. Beneath the source zones of most of the large historical earthquakes, prominent low-V anomalies are visible in the lower crust. Significant P-wave azimuthal anisotropy is revealed in the study region, and the pattern of anisotropy in the upper crust is consistent with the surface geologic features. In the lower crust and uppermost mantle, the predominant fast velocity direction (FVD) is NNE–SSW under the Yinchuan Graben and NWW–SEE or NW–SE beneath the Corridor transitional zone, Qilian Orogenic Belt and Western Qinling Orogenic Belt, and the FVD is NE–SW under the eastern Qilian Orogenic Belt. The anisotropy in the lower crust may be caused by the lattice-preferred orientation of minerals, which may reflect the lower-crustal ductile flow with varied directions. The present results shed new light on the seismotectonics and geodynamic processes of the Qinghai–Tibetan Plateau and its northeastern margin.     

生态足迹模型在山区生态可持续评价中的初步应用--以1999年北京西部山区为例

在剖析生态足迹分析法的理论基础上，进一步考虑不同消费水平对生态足迹时空变异的影响，划分农村居民和城镇居民两类不同的消费群体，分别计算各自的生态足迹，其次进一步细化模型中人均水资源足迹，从而构建生态足迹与生态容量平衡模型。根据平衡模型计算出生态盈亏，得出区域生态持续性评价结果。并以1999年北京西部山区门头沟区为例，进行模型计算和生态可持续评价，结果表明1999年门头沟区处于生态赤字状态，说明该区生态系统处于不可持续状态。在对门头沟区的初步研究基础上，指出生态足迹作为山区生态可持续评价指标的优点及当前存在的缺点。