Metallogenesis of Porphyry Cu Deposits of the Western Luzon Arc, Philippines: K-Ar ages, SO3 Contents of Microphenocrystic Apatite and Significance of Intrusive Rocks

Abstract: K–Ar ages of the following porphyry Cu deposits in the western Luzon arc are determined: Lobo-Boneng (10.50.4 Ma), Santo Niño (9.50.3 Ma), Black Mountain (2.10.1 Ma), Dizon (2.50.2 Ma) and Taysan (7.30.2 Ma). Microphenocrys-tic apatite in the late Cenozoic intermediate to silicic intrusions associated with porphyry Cu deposits in the western Luzon arc contains sulfur as SO₃ detectable by electron probe microanalyzer. Sulfur is supposed to have been accommodated dominantly as oxidized species in oxidizing hydrous magmas that generated porphyry Cu deposits. Likewise, such high SO₃ contents in microphenocrystic apatite are common characteristics of the intermediate to silicic magmatism of the western Luzon arc, from tonalitic rocks of the Luzon Central Cordillera of about 15 Ma to an active magmatism at Mount Pinatubo. Thus, the western Luzon arc has been generating porphyry Cu mineralization associated with oxidizing hydrous intermediate to silicic magmatism related to eastward subduction, since Miocene to the present day. Intermediate to silicic rocks since 15 Ma to present-day western Luzon arc generally show high whole-rock Sr/Y ratio ranging from 20 to 184. However, porphyry Cu deposit is not necessarily related to the rocks that show higher Sr/Y ratios compared to the other barren rocks in the western Luzon arc. The characteristics of the intermediate to silicic magma associated with porphyry Cu deposit are not attributed to the composition of the source material of the magma, but to the properties defined by the high activity of oxidized species of sulfur in the fluid phase that is encountered during the generation of intermediate to silicic magmas.     

思茅坳陷油气地质特征与勘探前景

思茅坳陷存在古生界和中一新生界两套沉积盖层,具有多套生储盖组合。以二叠系、三叠系为主力烃源岩,储层低孔低渗,侏罗系一白垩系“红层”组成区域盖层。思茅坳陷气水同喷、原油显示表明,该区海相地层仍有油气勘探前景,以存在K3-N区域盖层、断裂改造较弱、源岩成熟度较低、构造发育的英德一景谷、勐腊一勐满含油气保存单元为首选靶区,具有一定勘探前景。     

云南油页岩资源现状及潜力分析

截止目前云南已知油页岩矿点20余处,资源量1.58亿吨,折合页岩油550万吨;含油页岩岩系自寒武系下统—新近系上新统,主要赋存于下寒武统、中泥盆统近底部、中侏罗统、上白垩统和新近系中新统、上新统等层位.除下古生界为滨海—海湾泻湖相和滨外平原相外,其他则为内陆湖泊相.大部分矿点油页岩厚度可以达到最低可采厚度1m以上,含油率也达到或超过油页岩边界品位4ω％.下古生界油页岩含油率普遍较高,最高含油率可达27.07％.云南油页岩矿资源有望成为重要的非常规油气资源.     

The Material Sourece of a New Type of Copper Deposits—Evidence from Stable Isotopes

The new type of copper deposits concerned with in this paper are vein copper deposits found in the Lanping-Simao Rift Basin, Yunnan,China. As is indicated by H,O,C,S,Pb and Sr isotopes, water and mineralizers in the ore-forming fluids were derived from heated meteoric water and mantle, respectively.The metallic elements(Cu,Ag,Pb,Zn,As,Sb,Fe,REE,etc.)are characterized by a mixed source from the crust and the mantle.     

表生异极矿成因研究及其找矿意义

云南金顶异极矿产于铅锌矿床氧化带中,基于对该矿床异极矿产出特征、颜色环带、不同颜色环带的成份、显微结构以及其他铅锌氧化物的分析,认为异极矿是由硅酸与锌的重碳酸盐溶液反应生成。镜下异极矿集合体纤维交织结构、环带结构、毛粘状结构等显微结构特征分析表明异极矿是表生环境下形成。扫描电镜获得异极矿清晰的单晶体、集合体和晶体间充填物的图像,晶体大小约为100μm～300μm,晶体间片状充填物约为250μm。同时对云南金顶铅锌矿床和异极矿与其他地区铅锌矿床和异极矿产出特征进行比较认为：异极矿一般产出于铅锌矿床表生氧化带,在风化淋滤作用较强环境下产出,对矿床环境和原生铅锌矿床找矿有一定指示意义。     

桂西下三叠统牙形石序列的新认识

桂西下三叠统为海相沉积,根据其岩性、厚度、化石类型等诸方面的明显差异可以分为两种类型,即作登型和太平型。本文详细研究了桂西两种类型下三叠统的牙形石,认为不同类型的下三叠统具有不同的牙形石序列。在前人工作基础上,对桂西下三叠统牙形石序列予以重新厘定。补充了作登型下三叠统的Neogondolella carinta带;指出作登型下三叠统不宜建立Platyvillosus costatus带;在太平型下三叠统Dienerian阶—Spathian阶中新建了Pachvcladina erromera带,Platyvillosus costatus带,Pachycladina obliqua-Parachirognathus delicatulus带和Neospathodus triangularis带;指出了每一个牙形石带的性质并与作登型下三叠统牙形石序列进行了对比。本文还从事件地层学和生物地层学两个角度,对桂西二叠一三叠系界线提出了新的认识。     

云南会泽超大型铅锌矿床成矿元素迁移和沉淀机制

云南会泽铅锌矿床是扬子块西南缘川―滇―黔接壤区的铅锌银多金属矿集区已探明的唯一超大型铅锌矿床,矿床规模大（Pb＋Zn探明储量超过500万吨）、品位高（Pb＋Zn平均品位大于25%）、伴生元素多（Ag、Ge、Cd、Ga等）,有很高的研究和经济价值。本文在总结该矿床地质特征、成矿流体性质及来源基础上,探讨了成矿流体迁移和沉淀机制。研究表明,低温（150～200℃）条件下,Zn主要以硫氢化物络合物迁移,少量呈氯化物络合物形式;Pb主要以氯化物络合物,少量以硫氢化物络合物形式进行迁移;高温（300～400℃）条件下,Pb、Zn主要以氯化物络合物的形式进行迁移。流体混合作用导致成矿流体温度降低,还原硫和Cl-浓度降低,pH值升高和氧逸度降低是成矿元素沉淀的主要机制。     

新矿物—盈江铀矿

新矿物产于云南盈江县的一个铀矿点氧化带,与多种铀矿物共生。该矿物为致密状集合体,黄色,透明至半透明。斜方晶系,空间群C222_1,晶胞参数a=13.73(1),b=15.99(1),c=17.33(2);V=3804(5);Z=8。计算比重4.17。二轴晶负光性,2V计算=83°,α=1.669;β=1.692;γ=1.710。紫外光照射发弱绿黄色荧光。化学成分UO_376.54,P_2O_511.10,K_2O 2.46,CaO 1.57,ThO 0.51,RE_2O_3 0.45,H_2O 7.37%。矿物化学式为(K_(1-x),Ca_x)(UO_2)_3 (PO_4)_2 (OH)_(1+x)·4H_2O,文中还给出X射线粉晶衍射数据。     

云南羊拉铜矿三维地质建模及储量计算

以云南羊拉铜矿的断层、地层、岩体、矿体为研究对象,在分析研究建模技术方案的基础上,依据收集到的钻孔柱状图、勘探线剖面图、中段地质图和地形地质图,结合野外踏勘与认识,利用Micromine软件建立了研究区的地形、地层、断层以及矿体的三维实体模型,直观展示了区内地表、断层、地层、岩体以及矿体的空间展布以及相互的空间位置关系。运用克里格法对里农矿段的铜矿体进行品位估值,获得了矿体的储量。     

云南石林世界地质公园阿诗玛石柱碳酸盐岩 显微特征及沉积环境

云南石林世界地质公园阿诗玛石柱,其岩石地层是呈水平产状的中二叠统茅口组厚层块状灰岩,但其构成岩石的具体岩性却未见做过详细工作。笔者等经公园管理部门同意,自下而上分别在阿诗玛石柱背侧底部、下部、中部、上部和顶部共采集样品五块,对其岩石学特征及沉积微相作了详细研究,弄清了这一世界著名景点自下而上的岩石构成及沉积相。底部为高能浅滩相灰色厚层块状具平行层理生屑颗粒灰岩,构成阿诗玛脚部。下部为中能浅潮下灰色厚层块状虫筳生屑泥粒灰岩,构成阿诗玛腿部。中部为中能浅潮下灰色厚层块状砂屑泥粒灰岩,构成阿诗玛腰部。上部为中能浅潮下灰色厚层块状具生物扰动含砂屑生屑泥粒灰岩,构成阿诗玛胸部;顶部为高能浅滩相灰色厚层块状砂屑生屑颗粒灰岩,构成阿诗玛头部。其中含有大量生物化石碎屑:有孔虫、三叶虫、藻类、介形虫、腕足、苔藓虫、虫筳、海百合茎、双壳类,为高能浅滩相和中等能量浅潮下环境。希能为石林形成过程研究和科学普及提供参考。