The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

青藏高原的水塔功能

青藏高原是维持我国乃至东亚地区生态系统的重要水塔。高原平均海拔在4000m以上,与周边地区形成了巨大的地势差。高原东南部不仅具有丰富的降水,而且在3500m以上以冰川雪被形态储存了巨大的水资源,因此,高原具有重要的水塔功能。基于高原潜在输出总水量和不同海拔区域水体所具有的势能两个方面,建立了高原水塔功能的模型,从而利用GIS方法,通过对我国1∶400万系列图和相关资料的统计分析,计算出高原不同高度带贮存的大气降水、冰川储水量、湖泊水量以及工农业用水量。计算结果表明,青藏高原冰川湖泊的淡水储量达39921×108m3,其中冰川储水量为39228×108m3,可利用湖泊储水量为693×108m3,平均每年由降水获得的水资源量为8495×108m3,高原工农业用水量为129×108m3。因此,高原的输出水量即出境河川径流量为6870×108m3。高原储水主要分布在海拔3000～5000m间,与高原周围相比,平均势差在2000～4000m间,最大的势差达5500m。水体具有巨大的势能,在势能的作用下,自然向周边区域输送汇集,维持着周边地区的生态过程和社会经济活动,因此,青藏高原的水塔功能对于周边地区的生态系统和社会经济系统是极其重要的。     

东吴小筑园林植物应用评价

园林植物配置是园林植物应用的重要内容，对充分发挥园林功能和观赏特性具有重要作用。通过对东吴小筑入口、前庭小院、主景区、山林区、园路、出口等6个功能区园林植物水平配置的现状调查，分析了本景区园林植物的物种多样性、水平结构、垂直结构、色彩变化等特征。结果表明：东吴小筑园林景观营造中．植物配置显示出较高水准。在树种选择、树丛组合、层次搭配、空间组织、色彩表现、季相变化等方面的设计布局十分精细，对今后园林设计及园林绿化水平的提高具有较好的指导作用。     

Geography Education: The Glass Is Half Full and It's Getting Fuller

This article examines the recent progress of geography education as an academic subfield of geography and as an area of activity in K–12 education. Challenges to both endeavors are described. A restructuring of geography education's research program that focuses on spatial thinking and reasoning and merges applied and theoretical research is proposed.     

Simulation of seismic response in a city-like environment

We study the seismic response of idealized 2D cities, constituted by non-equally spaced, non-equally sized homogenized blocks anchored in a soft layer overlying a hard half space. The blocks and soft layer are occupied by dissipative media. To simulate such response, we use an approximation of the viscoelastic modulus by a low-order rational function of frequency and incorporate this approximation into a first-order-in-time scheme. Our results display spatially variable, strong, long-duration responses inside the blocks and on the ground, which qualitatively match the responses observed in some earthquake-prone cities of Mexico, France, the USA, etc.     

基于二维小波变换的FMI图象分割

为了从FMI资料中定量提取参数，一个重要的步骤是从实际FMI资料中分离出反映溶孔、溶洞、裂缝的子图像。本文给出的方法，考虑图像像元邻域的特征，应用二维小波变换求出目标与背景边缘的点集，按这个边缘点集的坐标点所对应的原图像像素灰度值的平均值作为分割阈值进行图像分割。实际资料处理表明，应用这种方法可以从实际的FMI资料中准确地分割出孔洞、裂缝的子图像并且可以按深度段连续自动处理，为后续定量计算参数奠定了良好基础。     

The diurnal and seasonal characteristics of urban heat island variation in Beijing city and surrounding areas and impact factors based on remote sensing satellite data

Based on the land surface temperature (LST), the land cover classification map,vegetation coverage, and surface evapotranspiration derived from EOS-MODIS satellite data, and by the use of GIS spatial analytic technique and multivariate statistical analysis method, the urban heat island (UHI) spatial distribution of the diurnal and seasonal variabilities and its driving forces are studied in Beijing city and surrounding areas in 2001. The relationships among UHI distribution and landcover categories, topographic factor, vegetation greenness, and surface evapotranspiration are analyzed. The results indicate that: (i) The significant UHI occur in Beijing city areas in the four seasons due to high heat capacity and multi-reflection of compression building, as well as with special topographic features of its three sides surrounded by mountains,especially in the summer. The UHI spatial distribution is corresponding with the urban geometry structure profile. The LST difference is approximately 4-6℃ between Beijing city and suburb areas, comparatively is 8- 10℃ between Beijing city area and outer suburb area in northwestern regions. (ii) The UHI distribution and intensity in daytime are different from nighttime in Beijing city area, the nighttime UHI is obvious. However, in the daytime, the significant UHI mainly appears in the summer, the autumn takes second place, and the UHI in the winter and the spring seem not obvious. The surface evapotranspiration in suburb areas is larger than that in urban areas in the summer, and high latent heat exchange is evident, which leads to LST difference between city area and suburb area. (iii) The reflection of surface landcover categories is sensitive to the UHI, the correlation between vegetation greenness and UHI shows obviously negative.The scatterplot shows that there is the negative correlation between NDVI and LST (R2 = 0.6481).The results demonstrate that the vegetation greenness is an important factor for reducing the UHI,and large-scale construction of greenbelts can considerably reduce the UHI effect.     

Signatures in flowing fluid electric conductivity logs

Flowing fluid electric conductivity logging provides a means to determine hydrologic properties of fractures, fracture zones, or other permeable layers intersecting a borehole in saturated rock. The method involves analyzing the time-evolution of fluid electric conductivity (FEC) logs obtained while the well is being pumped and yields information on the location, hydraulic transmissivity, and salinity of permeable layers. The original analysis method was restricted to the case in which flows from the permeable layers or fractures were directed into the borehole (inflow). Recently, the method was adapted to permit treatment of both inflow and outflow, including analysis of natural regional flow in the permeable layer. A numerical model simulates flow and transport in the wellbore during flowing FEC logging, and fracture properties are determined by optimizing the match between simulation results and observed FEC logs. This can be a laborious trial-and-error procedure, especially when both inflow and outflow points are present. Improved analyses methods are needed. One possible tactic would be to develop an automated inverse method, but this paper takes a more elementary approach and focuses on identifying the signatures that various inflow and outflow features create in flowing FEC logs. The physical insight obtained provides a basis for more efficient analysis of these logs, both for the present trial and error approach and for a potential future automated inverse approach. Inflow points produce distinctive signatures in the FEC logs themselves, enabling the determination of location, inflow rate, and ion concentration. Identifying outflow locations and flow rates typically requires a more complicated integral method, which is also presented in this paper.     

浅论安阳市传染病医院规划设计

以安阳市第五人民医院整体搬迁工程的设计为例,通过设计思路的详细介绍,阐述了传染病医院规划设计中注意到的几点问题。