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81.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
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《中国地球化学学报》2006,25(B08):108-109
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Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152
The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use. 相似文献
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东北漫岗黑土区春季冻融期浅沟侵蚀 总被引:7,自引:0,他引:7
浅沟侵蚀是东北漫岗黑土区农耕地上常见的水蚀类型,往往对坡耕地造成严重的破坏。2005年春季,通过对两个小流域浅沟侵蚀的调查测量,发现该区浅沟侵蚀相当严重,两流域分别形成浅沟14条、16条,浅沟总长度分别达3 269 m、2 146 m,浅沟密度分别为908 m/km2、766 m/km2,侵蚀深度分别为0.17 mm、0.16 mm,侵蚀模数分别达181.8 t/km2、173.6 t/km2。2005年春季两流域浅沟侵蚀期的径流深分别是6.8 mm、7.7 mm。分析表明,研究区在春季表层土壤解冻、地表裸露和存在季节性冻土层的条件下,春季融雪及强降水易造成强烈的浅沟侵蚀。在分布上,浅沟一般位于坡面的中下部,而且多发育在瓦背状坡面的集流水路上。另外,耕作措施对浅沟的形成和发展也有重要影响。 相似文献
88.
灌丛对川西北高寒草甸土壤资源的影响 总被引:7,自引:1,他引:7
以川西北高原红原县为研究区,用方格取样法,在相邻的高寒灌丛草地和高寒草甸样地中分别随机取0~20 cm土样50个,并分析了这些土样的土壤性状。利用SPSS(11.0)软件对实验数据进行了统计、分析和比较,研究了两个样地的各种土壤养分的平均含量、空间异质性和相关关系。结果表明,草甸样地的粘粒含量、Ptotal、Ntotal、ORG、Pavail、Navail、Kavail的含量都高于灌丛样地,且两样地速效养分差异极显著,但草甸样地土壤的ORG、Navail、Kavail的变异系数(CV)却明显小于灌丛样地,特别是Kavail的CV值,灌丛样地比草甸样地高出了53.37%;相关分析还表明,相对于草甸,灌丛样地中各养分元素之间的相关性明显增强。说明灌丛对高寒草甸土壤资源的异质性有明显的影响,其存在降低了草甸土壤养分的均值含量并增强了土壤养分的变异性和侵蚀潜力,不利于高寒草甸土壤养分的保持。 相似文献
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90.
Ir. Lahuddin M S Zulkifli Nasution 《湿地科学》2006,4(3):161-167
1 INTRODUCTIONQuality of chemical properties of flooded soils isgenerally determined by salinity and alkalinity,bothof these acts as inhibiting factors of plant growth.Thecorrelation of electrical conductivity and other analysisindex has been reported by … 相似文献