微细矿物颗粒表面水化膜研究现状及进展综述

微细矿物颗粒表面水化膜对其在水溶液中的分散与聚团具有重要影响。本文主要介绍了水化膜的形成机理及其对溶液中微细矿物颗粒分散与聚团的影响。并且分析了水化膜厚度及强度测量、水化作用力以及水化膜破解的研究现状。最后展望了水化膜研究在煤泥水微细颗粒聚团沉降方面的应用前景。     

Coal resource potential of Afghanistan

abstract

Coal exploration in Afghanistan has focused exclusively on expanding the boundaries of the known Jurassic coal deposits. The systematic stratigraphic and sedimentologic studies needed to locate and characterize new prospects in other parts of the country have never been conducted. Exploration strategies are based on received wisdom formulated before tectonic theory developed, and do not incorporate current understanding of the geologic and environmental processes responsible for peat formation and burial. This analysis reassesses existing data and limited new field reconnaissance data using modern tectonic and coal geology concepts to provide a new understanding of Afghanistan’s true coal potential. Afghanistan assembled during the Phanerozoic from a minimum of 11 microcontinental fragments, 5 arc systems, 3 accretionary wedges, and 2 rift systems. An unknown number of additional Precambrian terranes with separate tectonic histories are exposed in the cores of the Phanerozoic microcontinents. All of the Phanerozoic microcontinents separated from the disintegrating Gondwanaland. Each transited equatorial latitudes prior to accreting to Asia. From a purely theoretical standpoint, peat could have accumulated on every fragment during its equatorial transit. Mississippian, Triassic, Jurassic, Cretaceous, Oligocene, and Pliocene coals and carbonaceous shales are known. Triassic, Jurassic, and Pliocene deposits have been mined, but only the economically important Jurassic outcrops have been studied to any detail. Graphite-rich Precambrian strata are common from the Mesoarchean to the Neoproterozoic, and a Neoproterozoic bone coal was encountered while drilling for copper near Kabul. Jurassic and potentially Triassic and Carboniferous coals may underlie a significant percentage of the North Afghan Platform. Jurassic coals are extremely gassy and are known hydrocarbon source rocks across most of Central Asia. In Afghanistan, where these coal systems are closer to the surface, they could be coalbed methane reservoir rocks.     

Paleo‐fires and Atmospheric Oxygen Levels in the Latest Permian: Evidence from Maceral Compositions of Coals in Eastern Yunnan,Southern China

Inertinite maceral compositions of the Late Permian coals from three sections in the terrestrial and paralic settings of eastern Yunnan are analyzed in order to reveal the paleo-fire events and the atmospheric oxygen levels in the latest Permian. Although the macerals in the studied sections are generally dominated by vitrinite, the inertinite group makes up a considerable proportion. Its content increases upward from the beginning of the Late Permian to the coal seam near the Permian-Triassic boundary. Based on the microscopic features and the prevailing theory that inertinite is largely a by-product of paleo-fires, we suggest that the increasing upward trend of the inertinite abundance in the latest Permian could imply that the Late Permian peatland had suffered from frequent wildfires. Since ignition and burning depend on sufficient oxygen, a model-based calculation suggests that the O2 levels near the Wuchiapingian/Changhsingian boundary and the Permian-Triassic boundary are 27% and 28% respectively. This output adds supports to other discoveries made in the temporal marine and terrestrial sediments, and challenges the theories advocating hypoxia as a mechanism for the Permian-Triassic boundary crisis.     

Changes of Precipitation Infiltration Recharge in the Circumstances of Coal Mining Subsidence in the Shen‐Dong Coal Field,China

Coal mining subsidence is a universal environmental-geological problem in mining areas. By selecting the Shen-Dong coal mining subsidence area as the research field, this paper studies the changes in precipitation infiltration recharge in the circumstances of coal mining subsidence by means of field geological investigation and laboratory simulation experiments, which is expected to provide a scientific basis for eco-environmental restoration in the mining area. The results indicate that at the unstable stage of subsidence, three types of subsidence in the Shen-Dong mining area have positive effects on the precipitation infiltration recharge, and the type of full-thickness bedrock subsidence has the greatest influence. In the stable stage of subsidence, the precipitation infiltration process after long-term drought and the moisture migration in the aeration zone undergo three different stages: evaporation-infiltration before precipitation, infiltration-upward infiltration-infiltration during precipitation and evaporation-infiltration after precipitation. During a heavy rainfall infiltration process, the wetting front movement in fine sand, coarse sand and dualistic structure of fine-coarse sand consists of two stages: the stage of wetting front movement during precipitation, in which the wetting front movement distance has linear relationship with the depth, and the stage of wetting front movement after precipitation, in which the wetting front movement distance has the power function relationship with the depth. The wetting front movement velocity is influenced by the rainfall amount and the lithology in the aeration zone. However, as the depth increases, the movement velocity will decay exponentially.     

Geochemical Evidence for Coal and Carbonaceous Mudstone as the Possible Major Oil Source Rock in the Jurassic Turpan Basin,Northwest China

Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.     

瞬变电磁测深在煤炭勘查工作中的应用

目前瞬变电磁法在地质勘探中应用的越来越广。因其分辨率高,特别是横向分辨率更高,可分辨出地下规模较小的不均匀体,所以在金属矿及煤矿采空区等勘探方面应用的比较早,技术也比较成熟。笔者将瞬变电磁法用于火成岩侵入沉积地层的煤炭勘查工作中的应用效果做一介绍。     

宁夏香山含煤区找煤方向及前景探析

宁夏香山含煤区掩盖面积大,勘查程度低,空白区多。通过对已有地质资料分析,线驮石煤矿区边界断层为倾向北东的正断层,在东部土坡组露头附近有一倾向南西的正断层,两断层形成地堑使区内的含煤地层得以保存。根据矿区边界断层以西勘查资料推测,断层以东至土坡组露头区域太原组发育较稳定的中厚煤层及部分不稳定的厚煤层,煤种为无烟煤,全区可采煤层预测资源量约3．8亿t,此外在深井预测区以西大范围掩盖区也可能赋存可观的煤炭资源,如果上述两区资源量得以证实,将会改变对香山含煤区煤炭资源的评价。     

煤炭地质勘查中煤层综合对比方法研究——以永陇矿区老爷岭普查区为例

大型陆相煤盆地边缘的煤层划分与对比是煤炭地质勘查的关键性基础工作。依据基础地质勘探资料,应用标志层法、煤层自身特征法、测井曲线组合法、灰色关联分析法等,对永陇矿区老爷岭普查区延安组煤层进行综合对比。研究结果表明,在成煤环境不稳定地区,应用地质、地球物理和灰色关联分析等方法进行煤层综合对比可以取得可靠的结果。     

我国煤层甲烷碳同位素分布特征与瓦斯成因类型划分探讨

以170余组煤层甲烷碳同位素测定结果为依据,分析了我国煤层瓦斯的δ13C,值分布特征,探讨了瓦斯成因类型划分,研究结果显示：δ13C,值分布范围为～73．3％0—27．3‰,δ13C,值随煤的变质程度的增加总体增大,无烟煤阶段以后,δ13C。的变化趋于平稳,在-35‰上下波动;根据煤层甲烷碳同位素与煤级之间的变化关系,以煤的最大镜质体反射率作为指标,将我国煤层瓦斯成因分为次生生物成因气、混合成因气和热成因气三大类,并指出了我国部分煤矿区的瓦斯成因类型。     

遥感技术在四川省盐源地区煤炭资源调查评价中的应用

以卫星遥感技术为主要手段,通过室内遥感地质解译和野外调查验证,结合聚煤规律研究分析,对四川省盐源地区各时代含煤地层的含煤性及赋存规律进行了总结,最终圈定了8个含煤远景区,即盖祖-桃子含煤远景区、盐塘含煤远景区、梅雨含煤远景区、营盘山含煤远景区、小高山含煤远景区、大坡-白乌含煤远景区、巴折含煤远景区、白马-金河-藤桥含煤远景区;其中,盐塘、梅雨及白马-金河-藤桥含煤远景区为资源潜力较好区域,为该区进一步开展煤炭资源勘查工作提供了有利靶区。