测试超细煤粉粒度的实验研究

利用激光粒度仪测试超细煤粉的粒度。对测试超细煤粉试样粒度时的试样浓度、测试温度、分散时间、分散剂的种类及浓度等方面的影响进行了实验研究，给出了激光粒度仪测试超细煤粉粒度的最佳实验条件。     

含煤盆地煤储层后期改造形式及对煤层气选区影响--以华北克拉通选区为例

阐述了改造型含煤盆地煤储层被改造的两种形式；煤体结构的改造及构造煤的形成原因；后生充填物对煤层孔隙的改造及形成原因。提出了以构造煤发育程度作为改造型含煤盆地改造强度的一个指标。概述了华北克拉通盆地由中生代剪压应力转化为新生代剪张应力和拉张应力，而在盆地内形成以挤压构造为主到伸展构造为主的演化历程，及不同构造类型的区域分布，指出这种演化极易形成构造煤和后生充填物。提出将华北克拉通含煤盆地分为3种改造类型及其分布区域，分析了各自区域的煤储层物性及对煤层气开发选区的影响。提出应重视鄂尔多斯盆地侏罗纪煤层的煤层气．研究与开发．     

Numerical simulations for coupled rock deformation and gas leak flow in parallel coal seams

Based on the new viewpoint of interaction mechanics for solid and gas, gas leakage in parallel deformable coal seams can be understood. That is, under the action of varied geophysical fields, the methane gas flow in a double deformable coal seam can be essentially considered to be compressible with time-dependent and mixed permeation and diffusion through a pore-cleat deformable, heterogeneous and anisotropic medium. From this new viewpoint, coupled mathematical models for coal seam deformation and gas leak flow in parallel coal seams were formulated and the numerical simulations for slow gas emission from the parallel coal seams are presented. It is found that coupled models might be close to reality. Meanwhile, a coupled model for solid deformation and gas leak flow can be applied to the problems of gas leak flow including mining engineering, gas drainage engineering and mining safety engineering in particular the prediction of the safe range using protective layer mining where coal and gas outbursts can efficiently be prevented. This revised version was published online in July 2006 with corrections to the Cover Date.     

Design of backfilled thin-seam coal pillars using earth pressure theory

In underground coal mining any increase in coal recovery rate is dependent on a decrease in pillar size. Backfilling is one way of reducing the required size of pillars and hence the volume of coal left underground. Therefore any comparisons made between a self-supported mine layout and backfill supported mine layout are based directly on pillar design. The most effective way to examine the effect of backfill on pillar support, and subsequently the rate of recovery, would be to incorporate the mechanisms of backfill support directly into the current design procedure for coal pillars. This paper presents a review of the mechanics of backfill support, a method of estimating the magnitude of that support based on earth pressure theory, and an example that incorporates backfill support into current coal pillar design.     

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

Analysis of rock structure stability in coal mines

In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd.     

Localization of mining-induced horizontal fractures along rock layer interfaces in overburden: field measurements and prediction

The locations of mining-induced horizontal fractures along rock interfaces in the overburden of Donetsk Coal Basin were identified using an original experimental device. The device traps methane from horizontal fracture zone (100–fold coal seam thickness) over an active longwall mining excavation. Presence or absence of horizontal fractures along rock layer interfaces is correlated with physical characteristics of the overburden, such as thickness, uniaxial compressive strength of overburden rock layers, location of rock layer interfaces and thickness of extracted coal seams. As a result, a combined criterion based on these physical characteristics is proposed to predict the presence of overburden horizontal fracturing in coal mine operations.     

Erodibility of low‐compaction steep‐sloped reclaimed surface mine lands in the southern Appalachian region,USA

The use of loose spoils on steep slopes for surface coal mining reclamation sites has been promoted by the US Department of Interior, Office of Surface Mining for the establishment of native forest, as prescribed by the Forest Reclamation Approach (FRA). Although low‐compaction spoils improve tree survival and growth, erodibility on steep slopes was suspected to increase. This study quantified a combined K_C factor (combining the effects of the soil erodibility K factor and cover management C) for low compaction, steep‐sloped (>20°) reclaimed mine lands in the Appalachian region, USA. The combined K_C factor was used because standard Unit Plot conditions required to separate these factors, per Revised Universal Soil Loss Equation (RUSLE) experimental protocols, were not followed explicitly. Three active coal mining sites in the Appalachian region of East Tennessee, each containing four replicate field plots, were monitored for rainfall and sediment yields during a 14‐month period beginning June 2009. Average cumulative erosivity for the study sites during the monitoring period was measured as 5248.9 MJ·mm·ha^?1·h^?1. The K_C ranged between 0.001 and 0.05 t·ha·h·ha^?1·MJ^?1·mm^?1, with the highest values occurring immediately following reclamation site construction as rills developed (June – August 2009). The K_C for two study sites with about an 18–20 mm spoil D₈₄ were above 0.01 t·ha·h·ha^?1·MJ^?1·mm^?1 during rill development, and below 0.003 t·ha·h·ha^?1·MJ^?1·mm^?1 after August 2009 for the post‐rill development period. The K_C values for one site with a 40 mm spoil D₈₄ were never above 0.008 t·ha·h·ha^?1·MJ^?1·mm^?1 and also on average were lower, being more similar to the other two sites after the rill development period. Based on an initial K_C factor (K_e) measured during the first few storm events, the average C factor (C_e) was estimated as 0.58 for the rill development period and 0.13 for the post‐rill development period. It appears that larger size fractions of spoils influence K_C and C_e factors on low‐compaction steep slopes reclamation sites. Copyright © 2013 John Wiley & Sons, Ltd.     

Concentration–discharge relationships in the coal mined region of the New River basin and Indian Fork sub‐basin,Tennessee, USA

For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m³/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m³/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.