Laboratory studies of the interaction of carbon monoxide with water ice

The interaction of carbon monoxide (CO) with vapour-deposited water(H₂O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption from amorphous H₂Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as the water ice crystallises and then desorbs. The astronomical implications of this model are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

关于国有地了企业经营者实行年薪制的构想

为建立社会主义市场经济的地矿工作新秩序，本文对国有地矿企业的经营者（厂长、经理）这一特殊群体进行了分析。着重研究了新形势下企业经营者实行年薪制的问题。指出年薪制就是以企业一个生产经营周期为单位确定经营者的报酬，这一周期通常为一年。进而阐述了为什么要实行企业经营者年薪制；企业经营者的收入应与职工工资完全脱钩；采用基础报酬加效益报酬的方法确定收入等等。并构想了实行经营者年薪制所需要的外部环境：建立经营者人才市场、经营者要能进能出、实行任职资格制度、建立风险机制、按劳动力市场经济规律办事。     

Outflow channel sources, reactivation, and chaos formation, Xanthe Terra, Mars

The undulating, warped, and densely fractured surfaces of highland regions east of Valles Marineris (located north of the eastern Aureum Chaos, east of the Hydraotes Chaos, and south of the Hydaspis Chaos) resulted from extensional surface warping related to ground subsidence, caused when pressurized water confined in subterranean caverns was released to the surface. Water emanations formed crater lakes and resulted in channeling episodes involved in the excavation of Ares, Tiu, and Simud Valles of the eastern part of the circum-Chryse outflow channel system. Progressive surface subsidence and associated reduction of the subsurface cavernous volume, and/or episodes of magmatic-driven activity, led to increases of the hydrostatic pressure, resulting in reactivation of both catastrophic and non-catastrophic outflow activity. Ancient cratered highland and basin materials that underwent large-scale subsidence grade into densely fractured terrains. Collapse of rock materials in these regions resulted in the formation of chaotic terrains, which occur in and near the headwaters of the eastern circum-Chryse outflow channels. The deepest chaotic terrain in the Hydaspis Chaos region resulted from the collapse of pre-existing outflow channel floors. The release of volatiles and related collapse may have included water emanations not necessarily linked to catastrophic outflow. Basal warming related to dike intrusions, thermokarst activity involving wet sediments and/or dissected ice-enriched country rock, permafrost exposed to the atmosphere by extensional tectonism and channel incision, and/or the injection of water into porous floor material, may have enhanced outflow channel floor instability and subsequent collapse. In addition to the possible genetic linkage to outflow channel development dating back to at least the Late Noachian, clear disruption of impact craters with pristine ejecta blankets and rims, as well as preservation of fine tectonic fabrics, suggest that plateau subsidence and chaos formation may have continued well into the Amazonian Period. The geologic and paleohydrologic histories presented here have important implications, as new mechanisms for outflow channel formation and other fluvial activity are described, and new reactivation mechanisms are proposed for the origin of chaotic terrain as contributors to flooding. Detailed geomorphic analysis indicates that subterranean caverns may have been exposed during chaos formation, and thus chaotic terrains mark prime locations for future geologic, hydrologic, and possible astrobiologic exploration.     

THE CHARACTERISTIC OF MARINE ENVIRONMENT IN LINGDINGYANG ESTUARY

1 HYDROLOGIC FEATURES Lingdingyang Estuary, located at the middle south of Guangdong Province, is a bell-shaped estuary with a north-south direction. Its area is about 2100km2. The north of Qi′ao Island and Inner-Lingding Island, and the south of Humen are grouped as Neilingdingyang Estuary, having an area of 1041km2. Affected by topography, runoff and tide, its dynamic condition is very complicated. Different water areas have different hydrologic features. The topography under …     

金州地区震旦系基本层序与沉积环境

金州地区广泛发育震旦纪地层,具分布连续、出露完整、沉积相标志明显的特点。本文运用现代沉积学和地层学理论,对区内震旦系岩石地层进行了基本层序研究与沉积环境分析。     

Recurrent Red-tides in the Southampton Water Estuary Caused by the Phototrophic CiliateMesodinium rubrum

In the Southampton Water estuary (southern England, U.K.), red-tides caused by the planktonic, phototrophic ciliateMesodinium rubrum(=Myrionecta rubra) occur during most summers and sometimes in autumn. These events were investigated in detail between 1985 and 1987 and were characterized by levels of chlorophylla(chl a) of over 100 μg l⁻¹, cell numbers ofM. rubrumof over 1×10³ ml⁻¹, oxygen saturations of around 150%, and depleted numbers of macrozooplankton. Initiation of red-water did not appear to be triggered by irradiance or nutrients, but coincided with an increase in temperature and water column stability. This enhanced stability was promoted by increased surface to bottom gradients of both temperature and salinity, and by reduced mixing during neap tides. Development of red-water was accompanied by removal of most of the dissolved NH⁺₄from the water column, whereas some NO⁻₃persisted, presumably maintained by freshwater input. NO⁻₃and NH⁺₄gradually returned to pre-bloom concentrations as the red-water declined in late summer. Maximal biomass ofM. rubrumappeared to be limited by irradiance, and self-shading probably imposed an upper limit of around 300 mg chl a m⁻²within the water column. At the observed levels of chl a, irradiance values within the population maximum between 1 and 3 m depth were only just of the order (≈15 μmol photons m⁻² s⁻¹) required to balance estimated respiratory demands. Oxygen concentration became undersaturated during the late bloom phase, with minimal values of 20–30% saturation recorded in deeper waters; however, despite this and reduced numbers of macrozooplankton, direct deleterious effects on other organisms were not observed.     

Effective collision strengths with inclusion of resonance for hyperfine-structure transitions in H- and Li-like ions

Calculations are made of the resonance contribution to electron-impact excitation of H-like ¹³C and Li-like ²³Na, ²⁵Mg, ²⁷Al and ²⁹Si to the upper hyperfine levels that produce millimetre (mm) lines of likely astrophysical interest. The resonance contribution is found to be very important for these Li-like ions, considerably more important than for Li-like ⁵⁷Fe considered previously. However, resonances are found to be rather unimportant for H-like ¹³C. The effect of radiative decay on the resonance contribution is found to be insignificant in all of the present calculations.     

On water ice formation in interstellar clouds

A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol⁻¹, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ₃( A _v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.