极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

利用地下水预报河南登封4.7级地震的资料分析过程

通过对１９９２年河南登封４．７级地震的资料分析，表明拐河老井地下水位变化是区域应力场的变化效应。在时间上有连续性，在空间上和构造体系上有一定的相关性     

邯郸市西部岩溶地下水的利用与开发

根据区域内岩溶地下水供需水现状，特别是通过对岩溶地下水最新开采动态资料分析，认为邯郸市西部岩溶水区尚具有一定的开发潜力，并提出了解决岩溶山区(革命老区)人畜用水的可行性和拦蓄滞洪、人工补给的有效途径，为地方经济持续发展提供决策依据，也可为北方类似岩溶地区所借鉴。     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

GPS水汽遥感中的大气干延迟局地订正模型研究

在GPS遥感水汽过程中,大气干延迟模型的精度直接影响水汽遥感的精度。根据广东清远站1995～2001年的气象探空资料,计算了GPS水汽测量中的实际大气干延迟。在此资料基础上,利用地面气象要素建立了大气干延迟的年和分月局地订正模型。分析结果表明,年模型的精度优于目前广泛使用的普适模型;月模型与年模型相比,效果不是很明显,建立局地分月订正模型意义不大;在对高度角的敏感程度上,局地模型略大些;当高度角小于75时,大气干延迟弯曲路径与直线路径之差ΔS随天顶角增大而迅速增大。     

沸石在水环境治理中的应用现状与前景

文章叙述了沸石的基本结构以及吸附、离子交换特性，总结了近年来国内外有关沸石在水环境保护方面的研究与应用成果，提出了沸石在今后的水环境保护和改善方面将具有广泛的应用前景。     

冬小麦遥感冠层温度监测土壤含水量的试验研究

在冬小麦主要生育期(2002年4月初到5月底),对不灌溉的冬小麦测定了冠层温度、地温、气温以及土壤含水量,计算了冠气温差且分析了冠层温度和冠气温差与不同土层厚度的土壤含水量相关关系。结果表明:14:00的冠层温度能较好地反映20cm土层的土壤含水量变化,但与其它各土层相关性有较大的波动性;14:00的冠气温差能较好地反映40cm以上土层的土壤含水量变化,二者的相关性很高,在20cm、40cm土层,两者相关系数R2分别为0.98866、0.99389,这为用区域遥感数据反演主要生育期冬小麦的冠气温差进而监测区域40cm土壤含水量提供了实验性的依据;拔节期和灌浆期,用14:00冠气温差来拟合各土壤层的土壤含水量有较高的精度,从而为用区域遥感数据监测区域土壤含水量提供了经验性的模型。     

青藏高原的水塔功能

青藏高原是维持我国乃至东亚地区生态系统的重要水塔。高原平均海拔在4000m以上,与周边地区形成了巨大的地势差。高原东南部不仅具有丰富的降水,而且在3500m以上以冰川雪被形态储存了巨大的水资源,因此,高原具有重要的水塔功能。基于高原潜在输出总水量和不同海拔区域水体所具有的势能两个方面,建立了高原水塔功能的模型,从而利用GIS方法,通过对我国1∶400万系列图和相关资料的统计分析,计算出高原不同高度带贮存的大气降水、冰川储水量、湖泊水量以及工农业用水量。计算结果表明,青藏高原冰川湖泊的淡水储量达39921×108m3,其中冰川储水量为39228×108m3,可利用湖泊储水量为693×108m3,平均每年由降水获得的水资源量为8495×108m3,高原工农业用水量为129×108m3。因此,高原的输出水量即出境河川径流量为6870×108m3。高原储水主要分布在海拔3000～5000m间,与高原周围相比,平均势差在2000～4000m间,最大的势差达5500m。水体具有巨大的势能,在势能的作用下,自然向周边区域输送汇集,维持着周边地区的生态过程和社会经济活动,因此,青藏高原的水塔功能对于周边地区的生态系统和社会经济系统是极其重要的。     

Relationship between solar radiation and the development and morphology of small cirque glaciers (Maladeta Mountain massif, Central Pyrenees, Spain)

Abstract Spatial and temporal variations in radiative fluxes influence glacier mass‐balance in mountain areas. The primary goal of this study was to assess differences in solar radiation on three glacial cirques located in the Maladeta Mountain massif (Central Spanish Pyrenees), and analyse their implications on glacier development and morphology. A quantitative approach is adopted to obtain the values of solar radiation (direct, diffuse and global radiation), combining several field data parameters (measured at 55 control‐points) with the solar radiation modelling package Ecosim. The data obtained confirm that the morphologies of the glacial bodies developed in the three cirques have a good correlation with the spatial variation on solar radiation inputs, favouring also the conservation (Aneto and Coronas cirques) or total vanishing (Llosás cirque) of the glacial remnants analysed here. The study shows how strongly in this Alpine‐Mediterranean context solar radiation — firstly as a function of latitude and time of year, and locally as a function of topographic slope, aspect and shadowing — controls the mass‐balance and the spatial distribution of melting in small glaciers, having an effect on the development of their morphologies.     

RIVER SYSTEM AND DISTURBANCE FACTORS IN THE LAKE TOBA

Situated at an elevation of 905 m above sea level in the Province of North Sumatra, Lake Toba and its surrounding landscapes are regarded as a natural heritage in a certain extent, as a quoted national treasure. Unfortunately degradation of the land and water resources in the watershed along Lake Toba is taking place at an alarming and totally unacceptable rate. The quality of the lake is partly depended on input the quality of the rivers. When compared to the control area the water quality that influenced by the piggeries are highly polluted. It can be concluded that the Salbe River at the downstream of the piggeries has been polluted and apparently it is a serious problem to the catchment area management. It should be noted that the polluted river would influence the water quality of the Lake Toba. Based on calculation, the permissible BOD5 according to B- river standard is 238 mg/L, it means the river still in B standard but the condition and quality are decreasing continuously. Following the Indonesian health standard the permissible BOD is - 461 mg/L. It means BOD in the river should be reduced 461 mg/L or clean program is needed.