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91.
Ben J. Williamson Claire J. Horwell 《中国地球化学学报》2006,25(B08):224-225
A link between the inhalation of respirable silicas (SiO2) and respiratory diseases such as silicosis is widely recognized. Ash from dome collapse eruptions on Montserrat has been found to contain high levels (〉20%) of silicas in the form of cristobalite, tridymite, quartz and/or amorphous silica. The toxicity of these silica polymorphs varies widely. Cristobalite and quartz (tridymite less well established) are viewed as carcinogenic to humans whereas amorphous silica generally shows a reduced biological response. In assessing the potential health effects of volcanic ash particulates it is vital to determine the types and concentration of silicas as well as their size (respirable fraction), shape and surface properties. The aim of this study is to develop methods to assess potentially toxic respirable airborne silicas in the dome collapse ash (applicable to a range of ash types) and to develop a model to predict the levels and types of respirable silicas from future eruptions. The model is being developed by comparing dome rock with related ash from a series of previous eruption events. Mineralogical assessment using conventional scanning X-ray diffraction (XRD) was hampered by difficulties in differentiating characteristic peaks for cristobalite and tridymite in complex multi-component ash samples (containing high levels of plagioclase). These difficulties have been largely overcome using an Enraf-Nonius PDS120 diffractometer with curved (120 degrees 20) position sensitive detector (PSD). The determination of size, shape and elemental characteristics of ash particulate and dome rock samples has been carried out using automated analytical scanning electron microscopy. The quantification of mineral proportions using PSD-XRD was highly successful with an accuracy of 1 to 2 wt%. However, the determination of phase proportions using automated analytical SEM was problematic due to scattering effects and the multiphase nature of many of the particles. 相似文献
92.
Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya 总被引:1,自引:0,他引:1
Minghua Ren Peter A. Omenda Elizabeth Y. Anthony John C. White Ray Macdonald D.K. Bailey 《Lithos》2006,91(1-4):109-124
The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO2 > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas. 相似文献
93.
Leonard Boszke Artur Kowalski Witold Szczuciński Grzegorz Rachlewicz Stanisław Lorenc Jerzy Siepak 《Environmental Geology》2006,51(4):527-536
The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g−1 dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them. 相似文献
94.
A. V. Maslov V. N. Podkovyrov Yu. L. Ronkin M. T. Krupenin E. Z. Gareev V. M. Gorozhanin 《Stratigraphy and Geological Correlation》2006,14(2):126-149
In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean. 相似文献
95.
David W. Kelley Stefanie A. Brachfeld Edward A. Nater Herbert E. Wright Jr. 《Journal of Paleolimnology》2006,35(1):193-206
Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations
in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment
is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined
from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental
abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source
areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 14C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation,
snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded
by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis
that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America. 相似文献
96.
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99.
吐拉苏火山盆地中与金成矿有关的热液富含K^+、Na^+、F、SO4^2-和N2、O2等,是一种主要来源于岩浆.火山的热液,有大气水参于的次生热液.平均均一温度96~158℃,平均盐度0.26%~1.08%,热液活动深度0.26~0.67km,具有低温、低盐度、在地壳浅部活动的基本特征.热液活动生成围绕金矿体由内向外环状展布的黄英岩化、高级泥化、泥化和绿泥石碳酸盐化4个围岩蚀变带.与其有关的金成矿期分为原生沉积富集和次生热液交代蚀变2期,后者包括毒砂黄铁矿化、面状硅化、脉状硅化和绿泥石碳酸盐化4个成矿阶段.金富集成矿主要与黄英岩化蚀变带和面状硅化、脉状硅化2个成矿阶段密切相关. 相似文献
100.
藏北的若拉岗日岩群,因处于拉竹龙-金沙江缝合带南缘,其成生背景及构造属性历来倍受关注。白头山、岗盖日、狮头山等地的若拉岗日岩群主要为一套变质中基性火山岩系,不同地段夹杂大理岩、变质砂板岩、硅质岩、超基性岩等小岩片或块体,分别具有洋岛型、洋脊型及岛弧型火山岩的基本特征,并构成白头山西以岛弧火山岩为主的弧火山岩片,岗盖日以洋脊型变玄武岩为主夹杂硅质岩、超基性岩小岩片而共同组成的蛇绿混杂岩片及白头山、狮头山以洋岛型火山岩为主夹杂碳酸盐岩块体的大洋海山岩片,从而指出该区若拉岗日岩群为一套不同构造属性的火山岩与大理岩、硅质岩、超基性岩等相伴的构造混杂岩,其中既有某大洋的产物,又有某洋岛及陆缘岛弧的产物。 相似文献