电子探针化学测年方法

介绍含Th U Pb矿物电子探针化学测年方法的基本原理 ,并利用应用实例说明该方法在研究岩石形成年龄、构造热事件年代等方面的重要作用 ,最后简要评价该方法的优、缺点 ,并指出它的应用前景 ,认为电子探针化学测年方法将有可能在深源岩石包体年龄研究、含放射性元素矿床形成年代研究等方面大有作为 ,并使地质年代学研究更加精细化 ,有助于深入探讨复杂地质事件及其演化历程。     

天然气水合物体系动态演化研究（I）：地质历史演变

1995年Dickens对55．5Ma前古新世末增温事件进行了研究，提出天然气水合物作为全球环境变化重要因子的假说．认为古新世末增温事件溶解无机碳-2～-3‰的^13δC位移可以用水合物所含甲烷的释放与随后氧化成二氧化碳来解释．此后，地质历史演变中的天然气水合物演化研究蓬勃发展，本文总结古新世末增温事件、新元古代末期雪球事件、第四纪千年尺度事件等最新进展，为天然气水合物动态演化研究提供基础．开展天然气水合物-天然气体系动态演化过程数值模拟与特征分析，可望促进天然气水合物在全球变化与碳循环中作用的深入认识．     

Monitoring volcanic hazard using eddy covariance at Solfatara volcano, Naples, Italy

An eddy covariance (EC) station was deployed at Solfatara crater, Italy, June 8–25, 2001 to assess if EC could reliably monitor CO₂ fluxes continuously at this site. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes calculated in 30-min averages varied between 950 and 4460 g CO₂ m⁻² d⁻¹; the highest measurements were made downwind of degassing pools. Comparing turbulent fluxes with chamber measurements of surface fluxes using footprint models in diffuse degassing regions yielded an average difference of 0% (±4%), indicating that EC measurements are representative of surface fluxes at this volcanic site. Similar comparisons made downwind of degassing pools yielded emission rates from 12 to 27 t CO₂ d⁻¹ for these features. Reliable EC measurements (i.e. measurements with sufficient and stationary turbulence) were obtained primarily during daytime hours (08:00 and 20:00 local time) when the wind speed exceeded 2 m s⁻¹. Daily average EC fluxes varied by ±50% and variations were likely correlated to changes in atmospheric pressure. Variations in CO₂ emissions due to volcanic processes at depth would have to be on the same order of magnitude as the measured diurnal variability in order to be useful in predicting volcanic hazard. First-order models of magma emplacement suggest that emissions could exceed this rate for reasonable assumptions of magma movement. EC therefore provides a useful method of monitoring volcanic hazard at Solfatara. Further, EC can monitor significantly larger areas than can be monitored by previous methods.     

New unspiked K–Ar ages of volcanic rocks of the central and western sector of the Aeolian Islands: reconstruction of the volcanic stages

A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium–argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K–Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc–alkaline to potassic volcanism. The distribution of the K–Ar ages within the Salina–Lipari–Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina–Lipari–Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma–water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 188–100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval.     

中国东部陆缘中区第三纪构造-火山事件及其对含油气盆地的控制

中国东部陆缘中区第三纪主要发育5期构造-火山事件高峰，分别发生在58～46Ma、38～36Ma、26～24Ma、20～16Ma、8～4Ma。形成的火山岩岩性相对单一，主要为玄武岩，大量隐伏于新生代含油气断陷盆地中，这与裂谷作用有关，而野外露头区只发育古新世、中新世和上新世火山岩。研究表明，火山作用伴随着盆地发育的全过程。成盆早期的火山岩代表着裂谷作用的开始。成盆中期火山活动相对强烈，不但形成大量火山岩，而且也是盆地生油岩发育的主要时期。盆地形成后期火山作用微弱。新生代火山作用的中心往往成为成盆中心和油气聚集区。     

Late Cenozoic deformation subsequence in northeastern margin of Tibet --Detrital AFT records from Linxia Basin

Two events of Tibet uplifting are revealed by detrital apatite fission track (AFT) age data from Linxia Basin. They occurred at about 14 and 5.4-8.0 MaBP respectively. We interpret the first one to be related to the uplifting of the northern Tibet, which might have resulted from convectively removing the thickened lower lithosphere. The second one is a result of Laji Mountain uplifting. Numerous studies of the Tibetan Plateau suggest that the onset time of the deformation in the northeastern margin of Tibetan Plateau and the time of Tibet attaining to its present elevation is about 8 MaBP. They are approximately coincident with the uplift of Lajishan Mountain. It suggests that the northeastern margin of Tibet propagated northeastwardly to its present site in about 8 MaBP for accommodating the sustained convergence between India-Eurasia plate and for keeping its high elevation. The active block pattern dominating the strong earthquake distribution of Chinese continent probably formed at about 8.0-5.4 MaBP.     

试论火山岩储层的类型及其成因特征

本文在总结前人研究的基础上，结合胜利及辽河油田最新资料，提出了一种火山岩油气藏储层分类方案，共分为火山熔岩型、火山碎屑岩型和潜火山岩型3种类型。其中火山碎屑岩型又可分为正常火山碎屑岩型和火山碎屑沉积岩型两种亚类型；潜火山岩型分为隐爆角砾岩型和蚀变岩型两种亚类型。文中结合实例对各种类型储层的成因机制、空间展布特点以及储集性的变化特征进行了阐述和讨论。     

辽宁义县—北票地区义县组地层层序——义县阶标准地层剖面建立和研究之一

义县地区广义的义县组可解体为王家屯组 (暂命名 )和义县组 ;分属王家屯和义县火山旋回 ,前者为偏酸、偏碱性 ,后者主体为中基性、末期为中酸性火山岩系 ,并广泛发育潜火山岩相的玄武玢岩、安山玢岩和火山集块角砾熔岩筒。该区有七个主要沉积层 ,自下而上分别为王家屯组马神庙层、义县组老公沟层、业南沟层、砖城子层、大康堡层、朱家沟层和金刚山层 ;产有较丰富的无脊椎动物、脊椎动物和植物化石。以砖城子层、大康堡层和金刚山层为界 ,义县火山旋回可划分为 4个亚旋回 ,分别代表火山活动的初始期、主期、晚期和末期。北票四合屯地区的义县组相当义县地区义县组的第一和第二亚旋回 ,含鸟类化石的主沉积层 (尖山沟层和上园层 )可与砖城子层对比     

羌塘岩带碰撞后超钾质火山岩地球化学特征及成因探讨

羌塘超钾质火山岩为板块碰撞后的产物,地球化学特征表明,其同时具有板内火山岩和俯冲带岛弧火山岩的双重地球化学特性。化学组成上富含轻稀土和大离子亲石元素而亏损Cr、Ni等相容元素。在成因上受分离结晶作用和源区混合作用共同制约。源区为受古俯冲上地壳物质和下地幔上升流体交代混合的EMII型富集地幔端元,可能富含角闪石和金云母等矿物。     

Caledonian Low-Temperature Granulite-Facies Metamorphism in the West Kunlun Orogenic Belt—SHRIMP Chronological Evidence from Zircon

The West Kunlun orogenic belt is located at the conjunction of the paleo-Asian tectonic system and the Tethys tectonic system. Petrological and mineralogical studies of the Early Cambrian metamorphic surface crust in this region have shown that in case the metamorphism reached low-temperature granulate facies, the typical mineral assemblage is biotite-garnet-silimanite-K feldspar-plagioclase-quartz. The peak metamorphic temperatures are within the range of 720–740°C and the pressure is 0.6 GPa ±. Three types of metamorphic zircon have been detected in the metamorphic rocks: the complex inclusion-bearing type ; the early relic zircon inclusion-bearing type; and the inclusion-free type. SHRIMP age determination of these three types of metamorphic zircon have revealed that these zircons were formed principally during 400–460 Ma, indicating that pre-Cambrian metamorphic surface crust rocks underwent low-temperature granulite facies metamorphism during the Caledonian. In combination with the geological characteristics of this region, it is considered that when the oceanic basin was closed, there occurred intense intracontinental subduction (type A), bringing part of the Early Cambrian metamorphic basement in this region downwards to the lower crust. Meanwhile, there were accompanied with tectonic deformation at deep levels and medium- to high-grade metamorphism. This study provided important chronological and mineralogical evidence for the exploration of the evolutionary mechanism and process of the West Kunlun Early Paleozoic. Part of the results from the research project “ Research on the West Kunlun pre-Cambrian tectonic events” under the program “ Research on the important geological problems of China’ s pre-Cambrian” (No. 200113900070) sponsored by the China National Geological Surveying Bureau.