中太平洋CP25岩心的矿物、稀土元素及Sr、Nd同位素组成--晚新生代海底火山活动的证据

中太平洋ＣＰ２５岩心沉积物中钙十字沸石、蒙脱石／伊利石比值（Ｍ／Ｉ）、稀土元素含量、铈异常（δＣｅ）、铕异常（δＥｕ）及Ｓｒ、Ｎｄ同位素特征作为海底火山活动的证据,揭示了中太平洋海盆晚新生代以来火山活动和沉积的历史。其结果是,早中新世约２０～１７ＭａＢ．Ｐ．间,火山活动逐渐强烈,在１７ＭａＢ．Ｐ．最强烈,使得沉积物具有高Ｍ／Ｉ和∈Ｎｄ、低δＣｅ和８７Ｓｒ／８６Ｓｒ。１７～１ＭａＢ．Ｐ．发生沉积间断。１ＭａＢ．Ｐ．至现代,火山活动较早中新世减弱     

内蒙古丰镇市泉子沟斑岩钼矿床成岩成矿年代学及其地质意义

泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。     

New data on the correlation of skarn and gold mineralization at the Tardan deposit (northeastern Tuva)

Gold mineralization of the Tardan deposit is of different spatial occurrences and is related to different hydrothermal-metasomatic formations, the main ones being skarn-magnetite bodies, metasomatites of mineralized crush zones, and metasomatites of argillizitic-rock association. The formation of gold mineralization was a multistage process related to the repeated magmatism of the Tannu-Ola complex. It took place in a wide temperature range (400–150 °C), which determined the diversity of produced mineral assemblages. The gold mineralization associated with magnetite bodies shows a spatial correlation with magnesian and calcareous skarns and is localized in plagiogranites and gabbro-diorites of the Tannu-Ola complex intruded in the Late Ordovician. Gold mineralization that occurs in crush zones and along the fault sutures in moderate- and low-temperature hydrothermal-metasomatic rocks (propylites, beresites, serpentinites, and argillizites) formed somewhat later than skarns as a result of the intrusion of granite dike bodies. Comparative analysis of different types of gold mineralization showed both a change of mineral assemblages of the gold mineralization during the ore formation and some geochemical difference between gold and gold-bearing ores. In passing from early to late occurrences of native gold, its fineness decreases, the contents of admixtures correspondingly increase, and the gold composition changes. Gold of high-temperature rocks is rich in Cu (up to 17%), and gold of low-temperatures rocks has higher contents of Ag and Hg.     

铁—磺基水杨酸—二甲氧基羟基苯基荧光酮—TritonX—100体系的光度研究 …

研究了在表面活性剂存在下,铁与新显色剂二甲氧基羟基苯基荧光酮（ＤＭＨＰＦ）的显色反应。在ｐＨ９．０～１０．５的氨性介质中,有磺基水杨酸（Ｓａｌ）存在下,形成Ｆｅ３＋ＳａｌＤＭＨＰＦＴｒｉｔｏｎＸ１００四元混配配合物,其最大吸收峰在５９０ｎｍ,测定波长选择６１０ｎｍ,表观摩尔吸光系数分别为１．３×１０５Ｌ·ｍｏｌ－１·ｃｍ－１和９．４×１０４Ｌ·ｍｏｌ－１·ｃｍ－１。配合物组成比ｎＦｅ３＋∶ｎＤＭＨＰＦ＝１∶２,Ｆｅ３＋的质量浓度为０～６００μｇ／Ｌ时符合比尔定律。以直接光度法测定工业硅和石灰石样品中微量铁,结果与标准值相符,５次测定的ＲＳＤ在０．６４％～２．４１％。     

新疆新源县一带大哈拉军山组火山岩形成环境探讨

在新源县一带进行1∶5万区域地质调查时,认为新源县一带的大哈拉军山组火山岩以中酸性岩为主,依据其岩性特征、地球化学特征、微量元素特征,认为此地区大哈拉军山组火山岩不属于裂谷火山岩,应属于岛弧构造环境产物。     

桑托斯盆地L构造Aptian期火山喷发旋回特征与Itapema组介壳灰岩沉积

桑托斯盆地裂陷初期岩浆活动与储层发育关系密切。本文以盆地L区块火成岩-介壳灰岩复合体为研究对象,通过对火成岩岩石学、年代学测试及钻井、测井资料分析等,首次明确了桑托斯盆地裂陷初期岩浆活动特征及其对介壳灰岩沉积过程的控制,并指出介壳灰岩储层的分布特征。L区块内火成岩分属晚白垩世Santonian期—Campanian期和早白垩世Aptian两期岩浆活动产物,并以Aptian期为主,至少经历了7次不连续喷发和3次侵入过程,形成了块状玄武岩、杏仁状玄武岩和玻基斑状玄武岩(含再沉积玻基斑状玄武岩)等喷发相火成岩和以辉绿岩(局部属粗玄岩)、煌斑岩形式产出的侵入相火成岩。Aptian期岩浆多期活动重塑了古地貌,形成了局部构造凸起,促成并控制了下白垩统Itapema组至少6期介壳灰岩沉积,最终形成了～620 m厚火成岩-介壳灰岩复合体。介壳灰岩储层呈透镜体形状,以“散点式”不连续分布在Aptian期盆内古隆、古断阶(坡)等区域,横向连续性差,垂向连通性受限,其发育规模和质量受古地貌及水深条件等影响。     

利用测井方法识别火山岩岩相方法

利用实际岩石薄片数据及测井数据,通过GR-TH 及GR-AC 交会图方法将松南气田营城组岩石结构划分为熔岩结构、熔结结构和凝灰结构3 种。凝灰结构和熔结结构对应爆发相,熔岩结构对应喷溢相。结合次生孔隙度的大小及岩心、录井信息对出现的6 种亚相: 热碎屑流亚相、热基浪亚相、空落亚相、上部亚相、中部亚相和下部亚相进一步划分,其结果与地质上的岩相亚相基本一致。     

塔里木盆地早二叠世岩浆特征及其对油气成藏关系初探

塔里木盆地早二叠世裂谷盆地阶段有一次强烈的岩浆活动,主要为玄武岩—中酸性凝灰岩喷发和大规模基性岩墙群的侵入,玄武岩K-Ar法同位素年龄为241~278Ma,而辉长岩的Sm-Nd法年龄为259Ma。火山活动产生的能量使得塔里木盆地内的寒武系—奥陶系烃源岩大量生烃并运移,自生伊利石K-Ar年龄测定数据显示哈得4石炭系油藏、塔中4CⅢ油藏油气充注时间为224~275Ma,与上述火成岩的活动时间相当。东河砂岩,一套深埋的优质储层,其形成的原因可能是二叠纪末油气的注入并导致其后期深埋时只有机械压实而无其他成岩作用的缘故。     

Monitoring volcanic hazard using eddy covariance at Solfatara volcano, Naples, Italy

An eddy covariance (EC) station was deployed at Solfatara crater, Italy, June 8–25, 2001 to assess if EC could reliably monitor CO₂ fluxes continuously at this site. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes calculated in 30-min averages varied between 950 and 4460 g CO₂ m⁻² d⁻¹; the highest measurements were made downwind of degassing pools. Comparing turbulent fluxes with chamber measurements of surface fluxes using footprint models in diffuse degassing regions yielded an average difference of 0% (±4%), indicating that EC measurements are representative of surface fluxes at this volcanic site. Similar comparisons made downwind of degassing pools yielded emission rates from 12 to 27 t CO₂ d⁻¹ for these features. Reliable EC measurements (i.e. measurements with sufficient and stationary turbulence) were obtained primarily during daytime hours (08:00 and 20:00 local time) when the wind speed exceeded 2 m s⁻¹. Daily average EC fluxes varied by ±50% and variations were likely correlated to changes in atmospheric pressure. Variations in CO₂ emissions due to volcanic processes at depth would have to be on the same order of magnitude as the measured diurnal variability in order to be useful in predicting volcanic hazard. First-order models of magma emplacement suggest that emissions could exceed this rate for reasonable assumptions of magma movement. EC therefore provides a useful method of monitoring volcanic hazard at Solfatara. Further, EC can monitor significantly larger areas than can be monitored by previous methods.     

滇西南钾盐调查MK-3大口径超深井绳索取心钻进工艺

滇西南中生代盐盆地钾盐资源调查评价项目MK-3井,设计井深2700 m,全孔取心,岩心直径≮80 mm,一般井段岩心采取率达到80%以上,盐岩段岩心采取率＞95%。工程技术要求高,施工难度大。施工中遇到了地层坍塌、涌水、掉块、盐岩溶蚀等问题,通过采用氯化镁饱和盐水冲洗液,HXY-9B型钻机取心钻进、TSJ-2000型水源钻机扩孔钻进,分级下管隔离等措施,圆满完成了钻探任务。完钻井深2701 m,岩心采取率90%,盐岩段岩心采取率达98.65%,终孔口径127 mm,岩心直径81 mm。经地球物理测井,各项指标都达到了设计要求。刷新了国内CHD127标准绳索取心钻杆P口径钻探深度的记录。