江南钨矿带桂林郑钼钨矿床钼的赋存状态、时空分布及其研究意义

安徽桂林郑钼钨矿床位于江南钨矿带北部,是目前区内唯一钼储量达到大型的钼钨矿床。本文在对该矿床地质特征和已有成果总结基础上,详细观察了各代表性矿化蚀变样品的岩相学特征,提出该矿床具镁质矽卡岩矿床特征,是桂林郑花岗斑岩熔体与奥陶系白云质灰岩地层交代的产物。矿石类型可分为靠近岩体(100m)浸染状矿石和远离岩体( 100m)的条带状矿石,分别赋存在接触交代矽卡岩和层控矽卡岩中。桂林郑矿床的矿石矿物为富钼白钨矿(钼钙矿-白钨矿系列),可分为三个世代,分别形成于无水矽卡岩阶段(Sch-Ⅰ)和含水矽卡岩-氧化物阶段(Sch-Ⅱ和Sch-Ⅲ),辉钼矿仅在浸染状矿石富钼白钨矿(Sch-Ⅲ)边部少量发育。不同矿石类型、不同世代富钼白钨矿的电子探针成分分析显示,富钼白钨矿的钼含量(MoO_3%)在5.75%～71.02%之间,均值为46.00%(n=224),总体具有超常富钼的特点;从无水矽卡岩阶段到含水矽卡岩-氧化物阶段(早→晚)、从浅部的条带状矿石到深部的浸染状矿石(浅→深),富钼白钨矿MoO_3含量有降低趋势。桂林郑钼钨矿床是首个以富钼白钨矿为主要矿石矿物的钼-多金属矿床,这一特殊钼钨矿床的发现深化了矽卡岩钼钨矿床的成因认识,同时对江南钨矿带内区域成矿规律与找矿勘探工作的推进提供了依据。     

新疆色尔特能地区超镁铁岩岩石地球化学特征及构造环境分析

通过对出露在康古尔韧性剪切带西段的色尔特能超镁铁岩的野外地质调查和岩石学、岩石地球化学方面的分析研究工作,结果显示：色尔特能超镁铁岩发生了强烈蛇纹石化,基本蚀变成蛇纹岩;岩石主量元素具高Mg （w（MgO）=36.15%~37.96%）、高Cr （w（Cr₂O₃）=0.32%~0.36%）、高Ni （w（NiO）=0.17%~0.21%）、低Si （w（SiO₂）=40.50%~41.92%）、贫Al （w（Al₂O₃）=1.19%~1.77%）、低Fe （w（TFeO）=6.98%~7.87%）特征,Mg^#值为94.71~97.73,m/f值为8.03~9.42,属于典型镁质超镁铁岩,推测原岩为斜方辉石橄榄岩;稀土元素总量w（ΣREE）=1.44×10^-6~2.92×10^-6,配分模式为轻稀土微弱富集近平坦型,w（La）_N/w（Yb）_N=3.09~5.49,具一定程度的负Eu异常（δEu=0.48~1.09）和负Ce异常（δCe=0.53~0.60）;微量元素富集Ba、U、Ta,亏损Nb、Ti。色尔特能超镁铁岩属变质橄榄岩,是SSZ型蛇绿岩的底部组成单元,由原始地幔经2%~10%部分熔融形成的亏损地幔岩,其形成于俯冲带环境中的洋内弧后盆地。     

基于KronosFlow软件对逆冲推覆带构造-热演化的初探

盆地模拟是含油气盆地勘探评价的重要技术方法之一,然而传统的盆地建模2D模拟技术仅适用于拉张型盆地,使得挤压型盆地横向上的热史重建一直是个难题,从而制约了进一步的油气勘探。目前由法国Beicip-Franlab公司设计的KronosFlow软件突破了传统盆模软件对逆冲推覆带、盐构造和泥底辟等复杂构造的局限性,精确控制了横向和垂向上的构造位移,通过跟踪单个网格连续运动形态、恢复侧向变形量以及与TemisFlow软件无缝衔接,实现了对挤压型盆地埋藏史、热史、生排烃史以及油气运聚史的恢复。以塔里木盆地北缘柯坪逆冲推覆带和库车逆冲推覆带为例,利用KronosFlow软件定量反演了新生代以来的构造-热演化历史,并以实测数据约束并验证挤压环境下盆地模拟结果的有效性。柯坪逆冲推覆带的依木干他乌断层在40~30 Ma再次活动,断层附近志留系—泥盆系的温度大于85 ℃,柯坪塔格断层在15~10 Ma活动,断层附近志留系—泥盆系的温度小于70 ℃,寒武系（烃源岩成熟度为1.3%~1.7%）和奥陶系（烃源岩成熟度为0.7%~1.2%）烃源岩热演化程度高,生烃能力强。库车逆冲推覆带侏罗系北段温度介于50~70 ℃,南段温度介于210~230 ℃,盐构造造成地温异常,其中秋里塔格构造带膏盐岩最厚,降温效果最明显。      

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

东昆仑山中段布尔汗布达山地区断裂特征及昆中断裂带南界讨论

布尔汗布达山西南缘属东昆仑造山带腹地,新太古代以来区域构造作用强烈。中二叠世,随着东昆仑地区多岛洋盆依次关闭,研究区形成数条近于平行的EW向深大断裂组合,构成昆中断裂带主体格架。通过研究分析与断裂相关的地形地貌、遥感影像、地球物理、岩石地层、变形变质、断裂结构组成、显微构造等,总结出主要断裂特征,并梳理了区内构造格架,针对尚未统一认识的昆中断裂带南界问题进行探讨,最终认为温冷恩断裂属昆中断裂带南界断裂。研究成果为进一步开展相关地质问题分析提供了依据。     

冕宁-德昌稀土成矿带碳酸岩流体研究

通过对四川冕宁-德昌稀土矿带主要矿物中包裹体岩相学、显微测温分析与包裹体成分分析,指出由岩浆碳酸岩分异出的成矿流体为富含高密度CO2、K、Na、SO42-和多种成矿元素的超临界流体,流体以高温、高压、超高盐度、富CO2为特征,从早期到晚期流体中CO2含量增加。结合前人对碳酸岩流体、稀土矿带周边新生代盆地中无机成因CO2气藏、富钾卤水、稳定同位素和隋性气体同位素研究成果,从碳酸岩流体的性质、流体体系、碳、氦同位素组成,初步探讨了碳酸岩流体与周边新生代盆地中CO2气藏、富钾卤水的成因联系。     

峨眉山玄武岩浆喷发对贵州西部区域成矿贡献研究

早、晚二叠世之间大规模峨眉山玄武岩喷发是峨眉地幔热柱基性岩浆活动的高峰期.峨眉山玄武岩在贵州西部地区广泛分布,它不仅以矿源层形式参与钼、铜、铅、锌、金、锑、汞、铊等以地下水热液成矿作用为主的层控矿床的形成,而且它自身形成火山气液型矿床--玄武岩铜矿及伴生热液型铂、钯等矿化点;再者它是外生矿床--高砷煤、高氟煤、高硫煤、高汞煤形成的主要原因.     

个旧老卡岩体接触-凹陷带构造控矿特征研究

个旧老卡岩体接触-凹陷带是个旧矿集区最重要的锡铜多金属成矿构造带,带内锡铜矿体的成生与凹陷带构造密切相关,受构造、岩性和岩浆活动联合控制,凹陷带的形态、产状、规模的变化直接影响矿体的形态、产状、规模.凹陷带构造是一个有利成矿的构造部位,并配之有其他控矿因素,最终在燕山晚期含矿岩浆气液作用下形成富厚矿体.     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

山东英格庄金矿床构造控矿特征及深部预测

英格庄金矿床位于山东牟乳金矿带巫山断裂的南缘,其围岩主要以古老变质岩与昆嵛山花岗岩为主,为含金石英脉型金矿。文章通过对英格庄金矿床控矿断裂发展史以及断面几何形态与金矿体赋存位置关系的研究,发现矿体在断层带中的分布具有规律性。深部地球化学原生晕研究表明,英格庄金矿床Bi与Hg关系非常密切,是金矿化的最佳指示元素,且在已知矿体下方出现前缘晕与尾晕相互叠加的现象。结合矿体在断裂中分布的规律以及原生晕特点,对英格庄矿床深部第二富集段进行了预测,并预测在-220m下有第二金富集段存在,且具有很大的经济价值。