吉林东部延吉地区中生代火山岩地球化学特征

吉林东部延吉地区大面积出露的中生代火山岩,根据岩性特征可分为三个火山喷发旋回。各旋回火山岩均属ＳｉＯ２过饱和的中基性—中酸性岩类。从第一旋回至第三旋回岩石碱度变化较大,岩浆分异明显,特别是第三旋回分异作用明显高于第一、二旋回。火山岩中金、铜微量元素的平均含量普遍高于同类岩石的克拉克值几倍至几十倍,而且随着岩浆分异程度的升高,其平均含量有明显升高的趋势,为本区金、铜矿床的形成提供了物质来源。     

An application of Mie's series to soft particles

Summary The scattering of electromagnetic radiation from soft particles has been studied by a new method which allows to transform the Mie series into a simplified form through the use of some auxiliary expansions derived in the Appendix of this article. This simplified form (eq. 1) converts into the Hulst and Rayleigh-Debye-Gans' formulae if the parameters of eq. I are properly restricted. A further simplified form (eq. II), improves the well-known Hulst approximation.     

A note on the approximate determination of the dispersion of Love waves in a laterally nonhomogeneous layer lying over a homogeneous half-space

Rayleigh's principle and the concept of the local wave number have been utilised for the approximate determination of the dispersion of Love waves propagating in a laterally heterogeneous layer lying over a homogeneous half-space. The shear wave velocity and the rigidity in the surface layer have been assumed to decrease with the increase of the lateral distance from the origin. The range of validity of the dispersion equation obtained by this method has been examined critically. It was found that: (a) for existence of Love waves the minimum value of shear wave velocity in the layer must be less than that in the matter below, and (b) the phase velocity of Love waves decreases with the increase of the lateral distance from the origin.     

Measurement of lower-stratospheric aerosol by a balloon-borne photometer

Height distribution of the stratospheric aerosol extinction coefficient was measured in the altitude range 10 to 20 km by a balloon-borne multi-color sunphotometer in May 1978. It is demonstrated that detailed structures of the distribution of stratospheric aerosol can be remotely measured by the solar occultation method as well as by lidar andin situ particle counter observations. In the aerosol layer appearing at 18 km altitude the extinction coefficient at 800–1000 nm wavelength reached to 3×10^–7 m^–1, which was reasonable compared with lidar observations. Wavelength dependence of the aerosol optical depth was crudely estimated to be proportional to ^–1.5.     

The stratospheric sulfate aerosol layer: Processes,models, observations,and simulations

After briefly reviewing the observational data on the stratospheric sulfate aerosol layer, the chemical and physical processes that are likely to fix the properties of the layer are discussed. We present appropriate continuity equations for aerosol particles, and show how to solve the equations on a digital computer. Simulations of the unperturbed aerosol layer by various published models are discussed and the sensitivity of layer characteristics to variations in several aerosol model parameters is studied. We discuss model applications to anthropogenic pollution problems and demonstrate that moderate levels of aerospace activity (supersonic transport and space shuttle operations) will probably have only a negligible effect on global climate. Finally, we evaluate the possible climatic effect of a ten-fold increase in the atmospheric abundance of carbonyl sulfide.     

Mean Profiles of Moisture Fluxes in Snow-Filled Boundary Layers

Profiles of moisture fluxes have been examined for convective boundary layers containing clouds and snow, using data derived from aircraft measurements taken on four dates during the 1983/1984 University of Chicago lake-effect snow project. Flux profiles were derived from vertical stacks of aircraft cross-wind flight legs taken at various heights over Lake Michigan near the downwind shore. It was found that, if ice processes are taken into account, profiles of potential temperature and water content were very similar to those presented in past studies of convective boundary layers strongly heated from below. Profiles of total water content and equivalent potential temperature adjusted for ice were nearly invariant with height, except very near the top of the boundary layer, suggesting that internal boundary-layer mixing processes were rapid relative to the rates at which heat and vapour were transported into the boundary layer through entrainment and surface fluxes. Ice was found to play a significant, measurable role in boundary-layer moisture fluxes. It was estimated that 40 to 57% of the upward vapour flux was returned to the surface in the form of snow, converting about 45 to 64% of the surface latent heat flux into sensible heat in the snow-producing process. Assuming advective fluxes are relatively small (thought to be appropriate after the first few tens of km over the lake as suggested by past studies), the boundary layer was found to warm at a rate faster than could be explained by surface heat fluxes and latent heat releases alone, the remainder of the heating presumably coming from radiational processes and entrainment. Discussions of moisture phase change processes throughout the boundary layer and estimates of errors of these flux measurements are presented.     

A study of a fair weather boundary layer in TOGA-COARE: Parameterization of surface fluxes in large scale and regional models for light wind conditions

The study focuses on a way to parameterize the effect of subgrid scale convective motions on surface fluxes in large scale and regional models for the case of light surface winds. As previously proposed, these subgrid effects are assumed to scale with the convection intensity through the relationship: where is the mean velocity of the wind, U₀ the velocity of the mean wind, w_* the free convection velocity, and an empirical coefficient to be determined. Both observations and numerical simulation are presently used to determine the free convection coefficient .Large eddy simulation of a fair weather convective boundary layer case observed during TOGA-COARE is performed. Comparisons between observations and the simulation of surface properties and vertical profiles in the planetary boundary layer are presented. The simulated vertical turbulent fluxes of heat, moisture and buoyancy range well within estimates from aircraft measurements.The most important result is that the true free convection coefficient , directly estimated from simulation, leads to a value of 0.65, smaller than the ones estimated from temporal and spatial variances. Using observations and simulation, estimates of from temporal and spatial variances are obtained with similar values 0.8. From both theoretical derivations and numerical computations, it is shown that estimates of the true from variances are possible but only after applying a correction factor equal to 0.8. If this correction is not used, is overestimated by about 25%. The time and space sampling problem is also addressed in using numerical simulations.     

Unsteadiness as a cause of non-equality of eddy diffusivities for heat and vapour at the base of an advective inversion

This paper examines the effect of non-stationarity of the wind on similarity of the eddy diffusivities for heat and vapour within a stable layer at the bottom of an internal boundary layer formed downwind of a dry-to-wet transition. First, we present some experimental data taken above a rice crop downwind of very extensive dry range lands at Warrawidgee, NSW, Australia. These data establish that periods of higher wind speed were associated with periods of higher saturation deficit in the canopy of the rice crop, and lower Bowen ratio. It is shown that Bowen ratios calculated for 30-second sub-intervals varied three-fold within a single 20-minute averaging period. Thus periods of higher wind speed corresponded to periods of higher moisture flux and smaller sensible heat flux.An idealized situation is then analysed theoretically. It is assumed that the time scale of the slow variations of the wind is long compared with the surface-layer time scale and that fetch is sufficient that the air near the ground is in continuous equilibrium with the surface. Using a two-scale Reynolds decomposition of the fluctuating wind and scalar variables into active and inactive components, it is shown that unsteadiness can lead to an eddy diffusivity for saturation deficit, calculated as the ratio of average flux to average gradient, that is larger than that for total energy calculated in a similar way. Using this ratio to calculate the ratio of diffusivities for temperature and humidity, K_T/K_q, it is found that the latter can be much larger than one if the Bowen ratio is small and negative. Despite this, assuming K_T = K_q and using the Bowen ratio method to calculate surface energy fluxes will usually incur only minor errors.     

The Henry's Law Constants of the Haloacetic Acids

Henry's law constants K_H (mol kg^-1 atm^-1) have been measured between 278.15 K and 308.15 K for the following organic acids: CH₂FCOOH (ln(K_H[298.15 K]) = 11.3 ± 0.2), CH₂ClCOOH (11.59 ± 0.14), CH₂BrCOOH (11.94 ± 0.21), CHF₂COOH (10.32 ± 0.10), CHCl₂COOH (11.69 ± 0.11), CHBr₂COOH (12.33 ± 0.29), CBr₃COOH (12.61 ± 0.21), and CClF₂COOH (10.11 ± 0.12). The variation of K_H with temperature was determined for all acids except CH₂FCOOH and CBr₃COOH, with _r H° for the dissolution reaction ranging from –85.2 ± 2.6 to –57.1 ± 2.5 kJ mol^-1, meaning that their solubility is generally more sensitive to temperature than is the case for the simple carboxylic acids. The Henry's law constants show consistent trends with halogen substitution and, together with their high solubility compared to the parent (acetic) acid (ln(K_H[298.15 K]) = 8.61), present a severe test of current predictive models based upon molecular structure. The solubility of haloacetic acids and strong dissociation at normal pH mean that they will partition almost entirely into cloud and fog in the atmosphere (0.05–1.0 g H₂O m^-3), but can reside in both phases for the liquid water contents typical of aerosols (10^-5-10^-4 g H₂O m^-3).