土层结构对反应谱特征周期的影响

本文选取和构造了若干有工程意义的典型场地剖面,利用目前工程上广泛应用的场地地震反应分析的一维等效线性化波动方法,计算了在不同地震动输入下的不同场地剖面的地表加速度峰值和地表速度峰值。利用计算得到的地表加速度峰值和速度峰值计算了不同场地在不同地震动输入下的反应谱的特征周期。研究了不同土层结构对地表加速度反应谱特征周期的影响,获得了一些有意义的结果。     

北祁连西段香毛山一带早-中寒武世基性火山岩基本特征及其成因

香毛山一带早—中寒武世基性火岩以碱性玄武岩系列为主,具富钠,低钾、镁特点,稀土总量较低,属轻稀土富集型,分布模式为右倾平滑曲线,略具正铕异常;微量元素含量接近洋中脊过渡性玄武岩与板内拉斑玄武岩的丰度,岩浆来自富集的地幔源区;该火山岩系形成于强烈拉张产生的有限微洋盆构造环境,当时洋盆的扩张速率为l～2cm／a,属初始发育阶段。     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

Salt transport on islands in the Okavango Delta: Numerical investigations

This study uses a numerical model to investigate the groundwater flow and salt transport mechanisms below islands in the Okavango Delta. Continuous evapotranspiration on the islands results in accumulation of solutes and the formation of a saline boundary layer, which may eventually become unstable. A novel Lagrangian method is employed in this study and compared to other numerical methods. The numerical results support the geophysical observations of density fingering on Thata Island. However, the process is slow and it takes some hundreds of years until density fingering is triggered. The results are sensitive to changes of the hydraulic gradient and the evapotranspiration rate. Small changes may lead to different plume developments. Results further demonstrate that density effects may be entirely overridden by lateral flow on islands embedded in a sufficiently high regional hydraulic gradient.     

辐射井在强透水弱调节含水层地下水开采中的应用

本文通过在强透水弱调节含水层研究区建立了地下水流数模型、并在研究区域进行数值模拟计算的基础上,分析了不同取水构筑物的取水效果.得出了强透水弱调节含水层地下水采用辐射井开采的优越性和辐射井的设计参数,总结出辐射井是开采强透水弱调节含水层较为合理的取水构筑物.     

麦兹地区火山沉积岩型铅-锌矿床地质特征与找矿方向

阿尔泰山南缘的铅-锌矿床主要分布于麦兹地区,为了在其找矿空间和找矿类型上有所突破,详细地阐明了麦兹地区铅-锌矿床的主要地质特征、成因类型及其控矿因素,并结合区域构造演化背景,总结了麦兹地区铅-锌矿床的成矿规律,指明了铅-锌矿床的找矿方向。     

阿勒泰复向斜的成矿环境及其矿产

在阿勒泰复向斜内,分布有众多矿产,是阿尔泰山南缘重要的铜、铅、锌及多金属成矿区之一。文章详细介绍了这些重要矿床即铁木尔特铜-锌矿床、大东沟铅-锌矿床、乌拉斯沟铜-铅-锌矿床、阿巴宫铁矿床、红墩铅-锌矿床的地质特征,并从现代成矿理论角度全面分析了这些矿床形成的区域成矿环境及其找矿前景。     

A conceptual model for kimberlite emplacement by solitary interfacial mega-waves on the core mantle boundary

If convection in the Earth's liquid outer core is disrupted, degrades to turbulence and begins to behave in a chaotic manner, it will destabilize the Earth's magnetic field and provide the seeds for kimberlite melts via turbulent jets of silicate rich core material which invade the lower mantle. These (proto-) melts may then be captured by extreme amplitude solitary nonlinear waves generated through interaction of the outer core surface with the base of the mantle. A pressure differential behind the wave front then provides a mechanism for the captured melt to ascend to the upper mantle and crust so quickly that emplacement may indirectly promote a type of impact fracture cone within the relatively brittle crust. These waves are very rare but of finite probability. The assumption of turbulence transmission between layers is justified using a simple three-layer liquid model. The core derived melts eventually become frozen in place as localised topographic highs in the Mohorovicic discontinuity (Moho), or as deep rooted intrusive events. The intrusion's final composition is a function of melt contamination by two separate sources: the core contaminated mantle base and subducted Archean crust. The mega-wave hypothesis offers a plausible vehicle for early stage emplacement of kimberlite pipes and explains the age association of diamondiferous kimberlites with magnetic reversals and tectonic plate rearrangements.     

浙江沐尘岩体与西山头组火山岩的岩浆同源性分析

沐尘岩体与旁侧西山头组火山岩、潜火山岩在空间上密切共生,形成时间相近;岩石类型都属中酸性岩类;具有相近的岩石化学成分,均属弱碱质岩系;各种岩石的稀土配分曲线除Eu外具有基本一致的型式,微量元素配分曲线形态也基本一致,说明它们是同源岩浆演化的产物。其岩石类型、岩石化学和稀土元素、微量元素地球化学方面具有相似性和一致性,岩浆演化均有反序现象,说明它们属同熔型火山-侵入岩组合。根据2004年国际地层委员会公布的侏罗系与白垩系的分界年龄(145.5±4.0Ma),并结合沐尘岩体与旁侧西山头组火山岩的成因关系,沐尘岩体的形成时代确定为早白垩世早期似更合理。