Factors Controlling Sulfide Geochemistry in Sub-tropical Estuarine and Bay Sediments

The primary factors that control the concentration of total reduced (inorganic) sulfide in coastal sediments are believed to be the availability of reactive iron, dissolved sulfate and metabolizable organic carbon. We selected nine sites in shallow (<3 m), close to sub-tropical, estuaries and bays along the central Texas coast that represented a range in sediment grain size (a proxy for reactive iron), salinity (a proxy for dissolved sulfate), and total organic carbon (a proxy for metabolizable organic carbon). Based on these parameters a prediction was made of which factor was likely to control total reduced sulfide at each site and what the relative total reduced sulfide concentration was likely to be. To test the prediction, the sediments were analyzed for total reduced sulfide, acid volatile sulfide, and citrate dithionate-extractable, HCl-extractable and total Fe in the solid phase. Using solid-state gold–mercury amalgam microelectrodes and voltammetry, we determined pore water depth profiles of Fe(II) and ΣH₂S and presence or absence of FeS_(aq). At five of the nine sites the calculated degree of sufildization of citrate dithionite-reactive-iron was close to or greater than 1 indicating that rapidly reactive iron was probably the limiting factor for iron sulfide mineral formation. At one site (salinity = 0.9) dissolved Fe(II) was high, ΣH₂S was undetectable and the total reduced sulfide concentration was low indicating sulfate limitation. At the last three sites a low degree of sulfidization and modest total reduced (inorganic) sulfide concentrations appeared to be the result of a limited supply of metabolizable organic carbon. Fe(II)–S(-II) clusters (FeS_(aq)) were undetectable in 10 out of 12 bay sediment profiles where ΣH₂S was close to or below detection limits, but was observed in all other porewater profiles. Acid volatile sulfide, but not total reduced sulfide, was well correlated with total organic carbon and ranged from being undetectable in some cores to representing a major portion of total reduced sulfide in other cores. Although predicted controls on total reduced sulfide were good for very low salinity water or sandy sediments, they were only right about half the time for the other sediments. The likely reasons for the wrong predictions are the poor correlation of total organic carbon with grain size and differing fractions of metabolizable organic carbon in different sedimentary environments. Differences in sediment accumulation rates may also play a role, but these are difficult to determine in this region where hurricanes often resuspend and move sediments. This study demonstrates the need to examine more complex and often difficult to determine parameters in anoxic “normal marine” sediments if we are to understand what controls the concentration and distribution of sulfides.     

桉树腐殖酸(HA)专用肥区域试验与配方的优选

采用随机区组设计,以等价投入的常规化肥为对照,开展专用肥多点施肥试验研究.通过专用肥对林木生长量、林相特征的影响分析,结果表明:与等价投入(肥料成本)的常规化肥相比,施用系列专用肥的林分生长量均显著或极显著地高于常规化肥处理,且叶片浓绿、树势强壮,施后19个月内,树高、胸径、材积分别提高了7.8%~51.8%、9.8%~53.0%和30%以上,叶片叶绿素含量提高26.3%~94.2%,叶面积指数提高41.0%~172.8%.经对HA桉树专用肥的增产性、适应性和稳定性的综合分析与评定,选出基肥专用的优化配方为:有机质≥30.0%、N P2O5 K2O≥6.0%(2.5-2.0-1.5)、腐殖酸总量≥8.0%,并加上适量的"绿滴"复合微生物菌剂(于施用时和基肥按每50 kg∶1 kg的量掺入);追肥专用的优化配方为:有机质≥20.0%、N P2O5 K2O≥20.0%(9-8-3)、腐殖酸总量≥6.0%.     

水资源中氯代烃污染物的去除方法

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。     

Anomalous Enrichment of Silver in Organic Matter of the Songxi Shale-hosted Ag-Sb Deposit in Northeastern Guangdong

The silver contents of organic matter in the host rocks of the Songxi shale-hosted Ag-Sb deposit of northeastern Guangdong, South China, have been directly determined using the electron microprobe technique. The silver contents in two types of organic matter, marine vitrinite and solid bitumen, vary in the range from 100×10-6to 350×10-6, which are from tens of times to thousands of times higher than those of the host rocks in the ore deposit. The average silver content of the organic matter is also several times higher than the pay grade of silver for commercial mining of the ore deposit. It is quite obvious that the organic matter of the host rocks in the ore district is characterized by an anomalous enrichment of silver. The results of this study indicate that the silver anomalies in the organic matter have been derived from both the host rocks and the silver-bearing fluids of the Songxi black shale ore source. In the course of sedimentation and later hydrothermal reworking, organic matter was able     

我国水平地带性土壤中有机质的空间变化特征

主要根据全国第二次土壤普查的成果，对我国水平地带性土壤中有机质的含量和胡敏酸与富里酸比值的空间变化特征进行了概括，进而探讨了在不同自然和人因素影响下，土壤有机质的累积状况与稳定性特征。     

有机烃气法在个旧锡矿松树脚矿田中的应用

各类岩体、矿石、围岩、地表土壤的烃气测量结果表明,个旧锡矿的成矿存在有机物的参与,矿体周围存在烃气晕圈异常场,已知矿体上方地表有良好的烃气异常反映。认为有机质对金属元素的沉淀、成岩、活化迁移和成矿作用可能比通常认识的大得多,应深入研究有机烃气寻找金属矿这一新方法。     

藏北高原双湖地区中侏罗统海相油页岩生物标志化合物分布特征及其意义

重点报道了藏北双湖地区中侏罗统海相油页岩的生物标志化合物特征,首次在该层位油页岩中检出丰富的正烷烃、类异戊二烯烷烃、萜类化合物及甾类化合物。正烷烃图谱呈单峰形,nC₁₅、nC₁₆或nC₁₇为主峰碳,轻烃组份占有绝对优势,OEP值 0.93～ 1.0 1,无明显的奇偶碳数优势分布;Pr/Ph值为 0.77～ 1.5 9,在剖面序列中呈波动分布,显示弱植烷优势或姥鲛烷优势;藿烷以C₃₀ 占优势,萜烷相对丰度五环三萜烷 >三环萜烷 >四环萜烷;规则甾烷∑ (C₂₇+C₂₈) >∑C₂₉,∑C₂₇/∑C₂₉值为 0.79～ 1.2 0,在剖面序列中下部C₂₇甾烷略占优势,上部C₂₉甾烷略占优势,重排甾烷C₂₇/规则甾烷C₂₇值为 0.5 1～ 3.6 3,在剖面序列中具有显著的波动性,同时检出了少量孕甾烷和 4-甲基甾烷。有机质母质构成中,既有丰富的藻类等低等水生生物,可能还有一定比例陆生高等植物输入混合的特点。油页岩处于成熟阶段,整个油页岩剖面序列具有一致的热演化程度。剖面中部油页岩具有极高的原始生产力,氧化-还原条件也是控制油页岩TOC和沥青“A”含量在剖面垂向变化的重要因素.     

基于有机包裹体研究追索海拉尔盆地煤成油

有机包裹体在油气成因，运移研究中具有重要的意义，本文通过对海拉尔盆地砂岩样品中的有机包裹体进行显微荧光观察，包裹体均一测温，并对包裹体成分进行轻烃气相色谱及碳同位素分析，索了研究区油气的成因性质及油气运移期次,结果表明，海拉尔地区存在煤成油，并有两期以上的油气运移。     

KN系列难降解有机废水处理新药剂的研制及应用

KN系列污水处理剂对不同污水采用多孔、层状非金属矿经活化复配而成，不仅对难降解有机废水具有良好的处理效果，也可用于易生物降解废水，并且价格低，相关工艺具有占地少、投资省、运转费用低的特点。所产生的污泥脱水性能好，并可无害化最终处理，不产生二次污染。     

柱层累托石材料对有机废水的处理及效果评价

就使用柱层累托石材料对有机废水处理的实验研究进行讨论。采用累托石材料，在用量为15kg/t时，加入用量为4kg/t的还原剂FE，废水中COD去除率达70%；如果再用累托石进行二次吸附，其COD去除率达92%；处理水COD值降为96mg/L，达到GB8978-1996一级排放标准，同时实验了累托石的再生利用效果。