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111.
为了了解水对受力岩石的宏观力学效应,在MTS电液伺服材料试验系统上,对不同饱水度的砂岩、花岗闪长岩、灰岩和大理岩进行了单轴压缩试验,取得了这几种岩石的单轴抗压强度和弹性模量随饱水度变化的定量结果.结果表明,水对受力岩石的力学效应与岩石中的含水状态是密切相关的,自然状态的砂岩、花岗闪长岩浸水后,其峰值强度和弹性模量随饱水度的增加而迅速衰减,当饱水度达到某一定值时,这两种岩石的峰值强度和弹性模量基本稳定下来;文中用函数Y=Aexp(-Bx)+C对实验结果进行了最小二乘法拟合.实验中求得水饱和状态和自然状态砂岩的泊松比并没有明显差异,说明在宏观上水对该种岩石受力变形的作用是各向同性的.通过10-5/s和10-4/s两种不同应变率试验,发现水对受力岩石的力学效应具有时间依赖性,这一特点说明仅从有效应力原理来考虑水对受力岩石的力学效应是不够的,而应考虑应力腐蚀这样复杂的过程.此外,大理岩的试验结果表明,水对受力的碳酸盐类岩石的作用机理是一个值得进一步探讨的问题,它与水对受力的含SiO2类岩石相比,可能存在差异. 相似文献
112.
人工合成硅灰石的发光性质与发光机理的初步研究 总被引:2,自引:0,他引:2
在254nm紫外光照激发条件下,对人工合成掺入不同激活离子的低温TC型和高温型假硅灰石的发光性质进行了实验测定,从微观原子能量谱项讨论了在全的硅灰石基质中Eu^3+和Gd^3+的发光机理,分析了Bi^3+对Eu^3+与Pb^2+对Mn^2+的敏化发光条件,初步探讨了掺放Eu^3+的高温型假硅灰石发光强度减弱的原因。 相似文献
113.
Interpolated grids of coal bed thickness are being considered for use in a proposed method for taxation of coal in the state of West Virginia (United States). To assess the origin and magnitude of possible inaccuracies in calculated coal tonnage, we used conditional simulation to generate equiprobable realizations of net coal thickness for two coals on a 7
min topographic quadrangle, and a third coal in a second quadrangle. Coals differed in average thickness and proportion of original coal that had been removed by erosion; all three coals crop out in the study area. Coal tonnage was calculated for each realization and for each interpolated grid for actual and artificial property parcels, and differences were summarized as graphs of percent difference between tonnage calculated from the grid and average tonnage from simulations. Coal in individual parcels was considered minable for valuation purposes if average thickness in each parcel exceeded 30 inches. Results of this study show that over 75% of the parcels are classified correctly as minable or unminable based on interpolation grids of coal bed thickness. Although between 80 and 90% of the tonnages differ by less than 20% between interpolated values and simulated values, a nonlinear conditional bias might exist in estimation of coal tonnage from interpolated thickness, such that tonnage is underestimated where coal is thin, and overestimated where coal is thick. The largest percent differences occur for parcels that are small in area, although because of the small quantities of coal in question, bias is small on an absolute scale for these parcels. For a given parcel size, maximum apparent overestimation of coal tonnage occurs in parcels with an average coal bed thickness near the minable cutoff of 30 in. Conditional bias in tonnage for parcels having a coal thickness exceeding the cutoff by 10 in. or more is constant for two of the three coals studied, and increases slightly with average thickness for the third coal. 相似文献
114.
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116.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Physics and Chemistry of Minerals》2007,34(2):121-127
A multi-anvil device was used to synthesize 24 mg of pure γ-Fe2SiO4 crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C
p) of γ-Fe2SiO4 was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured
heat capacity data show a broad λ-transition at 11.8 K. The difference in the C
p between fayalite and γ-Fe2SiO4 is reduced as the temperature increases in the range of 50–300 K. The gap in C
p data between 300 and 350 K of γ-Fe2SiO4 is an impediment to calculation of a precise C
p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C
p and entropy of γ-Fe2SiO4 at standard temperature and pressure (S°298) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol−1 K−1, respectively. The Gibbs free energy at standard pressure and temperature (ΔG°
f,298) is calculated to be −1,369.3 ± 2.7 J mol−1 based on the new entropy data. The phase boundary for the fayalite–γ-Fe2SiO4 transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent
with extrapolated results of previous experimental studies. 相似文献
117.
118.
链烷烃的热力学性质与分子拓扑指数的关系 总被引:1,自引:0,他引:1
定义了一种新的连接性指数^1Y=Σk1/m^2 n^2,研究了链烷烃的标准生成焓、标准熵、标准生成吉布斯自由能等三个热力学性质与碳原子个数N,^1Y之间的定量关系,相关系数为优,其计算值与实验值较为接近,对未参与回归的正癸烷的60个异构体的三个热力学性质进行了计算,计算值与实验值较一致。 相似文献
119.
利用视电阻率测井曲线的周期性对渤南海油田沙三段中上部地层进行地层基准面旋回的划分对比后发现:该旋回界面与地层基准面由上升到下降期间可容纳空间单向增加的极限位置基本一致;地层基准面旋回的划分与测井分析结合可以进行储层。特别是高渗透储层预测。 相似文献
120.
以具体实例探讨了ActiveX控件在计算机辅助设计中的应用,给出了部分源代码。对这种新的设计思想作了概念性的剖析与展望。 相似文献