A comparative study on the illite crystallinity and the clay mineral reflectance spectral index for subdividing the very low-grade metamorphic belt along the Lizhou-Hekou geological section in the Youjiang sedimentary basin, Guangxi, China

To examine the application potential of hyperspectral remote sensing techniques in classifying very low-grade metamorphic belts, the composition of clay minerals and the cyrstallinity of illite from mudstones were measured using XRD and VIS-SWIR (400-2500 nm) reflectance spectroscopy. Based on the illite cyrstallinity, Kubler Index (KI), the Early Triassic LuoLou Group and the Middle Triassic lower Baifeng Formation were classified as the lower Epizone with KI△2θ° ranging from 0.22 to 0.25, the upper Baifeng Formation as upper anchizone with KI△2θ°ranging from 0.26 to 0.33, and the Hekou Formation as lower anchizone with KI△2θ° ranging from 0.38 to 0.40. According to a KI△2θ° value of 0.43, it is possible that there may exist a local diagenetic zone in the upper strata. The illite cyrstallinity Kubler index and the metamorphic grade increase from the bottom to the top of the stratigraphic sequence. The metamorphic grade boundaries nearly match the stratigraphic boundaries, indicating a burial metamorphism nature for the stratigraphic sequence. From the bottom to the top of the sequence, the spectral absorption band center of clay minerals from fresh rocks is around 2200 nm. The absorption band centers change towards shorter wavelengths: the Luolou Group being at 2220 nm, the Baifeng Formation at 2217-2213 nm, the lower member of the Hekou Formation at 2214-2206 nm, and the upper member of the Hekou Formation at 2205-2197 nm. The spectral absorption band center of illite shows the same change pattern. These results indicate that very low-grade metamorphic belts can be subdivided using spectral indices of clay minerals, which are measured by using field portable spectroradiometers. However, it may not work well with satellite and airborne sensors.     

铜陵地区老鸦岭层状钼矿床铅同位素组成研究

安徽铜陵老鸦岭矿床中二叠系大隆组(P2d)顶部的含矿(钼矿化)黑色页岩以及附近(立新煤矿)同一层位不含矿黑色页岩的实测铅同位素组成分别为：^206Pb/^204Pb20.20～22.37,^207Pb/^204Pb15.67～15.82,^208Pb/^204Pb38.47～38.60和^206Pb/204Pb18.83～20.80,^207Pb/^204Pb15.65～15.76,^208Pb/^204Pb38．84～39．22。对137Ma的放射成因Pb进行校正后的铅同位素组成表明，含矿黑色页岩和不含矿黑色页岩均与燕山晚期火成岩无关，老鸦岭含矿黑色页岩可能具沉积成因。对沉积(约250Ma)以来的放射成因Pb进行校正后的铅同位素组成表明：不含矿黑色页岩的Pb源自上地壳，而含矿黑色页岩的Pb(因而推测其他成矿金属)可能源于上地壳物质(与不含矿黑色页岩的Pb源相似)与下地壳物质的混合。     

南秦岭十里坪锑矿床成矿时代及成因的初步研究

十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%～11.3%,均一温度为109～232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。     

会泽超大型铅锌矿床成矿时代研究

云南会泽超大型铅锌矿床由麒麟厂和矿山厂两个独立的铅锌矿床组成。利用两组同源矿物组合Rb Sr等时线方法测定了麒麟厂6号矿体的成矿时代,测定结果分别为(225 1±2 9)Ma和(225 9±3 1)Ma,根据已知的分布于该矿床北部和西南部分布的峨眉山玄武岩成岩时代为250Ma左右,有多个火山喷发旋回,显示多期次的喷发活动,认为川—滇—黔成矿区内铅锌成矿作用与峨眉山玄武岩岩浆活动存在成因联系。     

个旧锡矿阿西寨矿段化探异常分带及找矿意义

通过对个旧锡矿阿西寨矿段地表基岩的地球化学勘查。发现其成矿元素的地球化学异常表现出明显的环状分带，并以测区内隐伏花岗岩凸起为中心，元素分带序列与元素本身的地球化学性质所决定的侧向迁移活动能力相符合。该现象再次证实个旧锡矿为花岗岩岩浆期后热液成矿，花岗岩是大多数成矿金属元素的物质来源，同时也是成矿热液活动的主要驱动营力。分析认为，阿西寨测区是一个相对较完整和独立的(凸起)成矿场，成矿热液活动以阿西寨凸起为中心。成矿热液活动体系受断裂导流影响，在以花岗岩凸起为中心的分带控制下，可能存在的工业矿体将在主干断裂附近和有利的构造岩性界面产出。     

我国主要金矿类型中黄铁矿"电子-空穴心"特征及影响因素

通过对我国主要金矿类型中黄铁矿导电类型的分析表明，黄铁矿“电子。空穴心”与金矿床的成因类型具有密切的联系，华北地台太古代变基性火山岩中的金矿床(绿岩带型)、热水淋滤型(卡林型)金矿床，黄铁矿多为单一的“电子心”型导电。大多数产于中生代岩体中的中深脉状金矿、火山次火山岩中的金矿床，黄铁矿为“电子心”、“空穴心”混合型导电，个别的为单一的“空穴心”导电。黄铁矿的“电子．空穴心”受杂质成分As、Co、Nl在成矿背景中的丰度，进入黄铁矿品格中的替代能力的差异、补偿类质同象现象、成矿时温度以及．f(S2)等多种因素的耦合制约。     

云南武定迤腊厂铜矿含矿石英脉40 Ar-39Ar年龄及其意义

对武定迤腊厂铜矿成矿期石英进行了40Ar-39Ar同位素年龄测定,得到马鞍形年龄谱,坪年龄为(784.25±0.95)Ma,等时线年龄为(783.93±8.59)Ma.地质特征研究表明该矿床后期改造作用明显,并非同生沉积或成岩作用早期成矿,而与晋宁期Rodina大陆裂解有关.武定迤腊厂铜矿的形成可能是在Rodinia大陆裂解时,从深部带来大量成矿物质,改造成岩时期初始的矿化,形成矿床的叠加富集和最终定位,晋宁-澄江期是该矿床的主成矿期.     

东川桃园式铜矿Ar-Ar同位素年龄及意义

通过对东川桃园铜矿与铜矿共生石英的40Ar/39Ar同位素年龄的测定,得到马鞍形年龄谱,其坪年龄为768.43Ma±0.58Ma,等时线年龄为770.00Ma±5.44Ma。该矿床后期改造作用明显,并非同生沉积或成岩作用早期成矿,而与晋宁期Rodina大陆裂解有关。东川铜矿的形成可能是在Rodinia大陆裂解时,从深部带来大量成矿物质改造成岩时期初始的矿化,形成矿床的叠加富集和最终定位,因此,晋宁-澄江期是东川铜矿的主成矿期。     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.     

Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.