哀牢山山地黄棕壤腐殖质的研究

云南哀牢山徐家坝自然保护区内,森林经不同程度的破坏后形成的各种次生植被下,土壤有机质含量均有所降低,但H/F值则随森林→灌丛→草地有较大幅度的增加。腐殖质聚合物分子结构中的芳构化度、分子量和芳香环的缩合度由木果石栎林、滇山杨林、毛蕨菜灌草丛到沼泽草地逐渐增大,而腐殖酸分子结构上所带的亲水基侧键则按上述顺序由多到少。     

山东省稀土矿产资源特征及找矿方向研究初探

目前山东省已发现稀土矿床（点）7个,查明轻稀土资源储量77余万吨。省内稀土矿床的成因类型主要包括碱性岩系列和花岗岩系列两大类,碱性岩系列稀土矿床的赋矿围岩主要为中生代产出的正长（斑）岩体、碳酸岩及云母岩等,花岗岩系列稀土矿床的赋矿围岩为中生代花岗伟晶岩。本文总结了山东省稀土矿资源现状及开发利用程度,重点论述了碱性岩系列和花岗岩系列两类稀土矿床的典型矿床地质特征,提出在山东省内进行同类型稀土矿床的找矿方向,为稀土矿床勘查提供参考。     

Analytical solution for the response of a flexible retaining structure with an elastic backfill

An extension of an existing analytical solution for the response of a flexible retaining wall subjected to seismic loading is presented. The solution is based on the assumption that the wall and the soil remain elastic and that there are no shear stresses at the wall–soil interface while the contact remains tied. In addition to the wall displacements due to bending, the wall can experience rigid‐body motions due to rotation and horizontal and vertical movements. The solution is verified by comparing its results with those of a finite element method. Results from the analytical solution together with those of the (FEM) are used to identify and quantify the relative importance of key parameters on the seismic response of a wall. The study shows that wall flexibility and horizontal rigid‐body motions of the wall and frequency content of the seismic input have a significant effect on the wall loads. The pressures behind a rigid wall decrease as the wall rotates about its base, whereas for a flexible wall, the soil pressures decrease as the friction between the backfill and the wall increases. The rigid‐body vertical movements of a wall have little impact on the dynamic pressures induced in the wall, except for a flexible wall where, when prevented, the dynamic loads may be reduced. Copyright © 2009 John Wiley & Sons, Ltd.     

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A theory of loosening earth pressure above a shallow tunnel in unsaturated ground

A theory is proposed to evaluate the loosening earth pressure (vertical earth pressure after excavation) acting on a shallow tunnel in unsaturated ground with an arbitrary groundwater level. The theory is developed based on the limit equilibrium theory, combining soil–water characteristic curves, Mohr–Coulomb failure criteria, and effective stress for unsaturated soils. The proposed theory is applied to predict the vertical distribution of loosening earth pressure in unsaturated ground, which shows a significant difference from that in saturated ground. In unsaturated ground, suction contributes to the increase in effective loosening earth pressure and shear resistance. The remarkable effects of groundwater depth, soil type, and scale of overburden height and trapdoor width on loosening earth pressure are also revealed. Based on the soil–water characteristic curve, the degree of saturation decreases, which causes wet density to decrease and the total and effective loosening earth pressures to have contrary tendencies. Moreover, effective loosening earth pressures vary with soil type as the degree of saturation varies. The total loosening earth pressures are, however, very similar regardless of soil type, because wet density and shear resistance have similar tendencies. The proposed theory provides a valid model for loosening earth pressure in unsaturated ground that will be useful for shallow tunnel excavations.     

Simplified analytical solution for point load acting behind a cantilever wall

The analysis of earth pressure resulting from an applied point load behind a retaining wall is to be carried out in three dimensions as the earth pressure distribution varies both in vertical and horizontal directions. In this research, the semi‐empirical expressions developed by Terzaghi [Trans. ASCE 1954; 119 ] for earth pressure due to point load are integrated and a correction factor is introduced to develop equivalent equations for two‐dimensional analyses. A new parameter referred to as the design width, which is the horizontal distance retained by the individual vertical retaining element is introduced. The used procedure and the resulted equations are tested and verified by adopting different design width values covering the practical range. The resulted equations together with the semi‐empirical expressions of earth pressure due to line load developed by Terzaghi [Trans. ASCE 1954; 119 ] can be easily used for two‐dimensional analysis of the effect of point load. Copyright © 2011 John Wiley & Sons, Ltd.     

安徽滁河断裂带温泉的水化学和同位素特征及成因分析

笔者等以安徽滁河断裂带内的6个温泉为主要研究对象,分析了水样的水化学特征,利用氢氧同位素对温泉的补给高程进行估算,并提出温泉的成因模式。研究区温泉阳离子以Ca2+和Mg2+为主,根据SO2-4和HCO-3的相对含量的不同,可以将水样分为两组,A组水样（富HCO-3）的主要离子的质量浓度均低于B组（富SO2-4）水样,A组水样的水化学类型为HCO-3—Ca2+·Mg2+; B组水样的（除AH14为SO2-4—Ca2+外）水化学类型为SO2-4—Ca2+·Mg2+。A组水样的稀土元素含量高于B组,二者均在NASC标准化图解上表现出平坦型的配分模式,且都表现出轻稀土富集和Eu正异常的特征。水样的氢氧稳定同位素组成表明温泉的补给来源都是大气降水,补给区温度约为13~15 ℃。A组温泉的补给高程为120~160 m低于B组温泉的200~260 m,且A组温泉的热储温度为45~70℃,低于B组温泉的热储温度70~105 ℃。地下水经历深循环获得大地热流加热后沿断裂带上升出地表。     

浸矿开采对离子型稀土基岩力学特性的影响研究

为研究原地浸矿母液对离子型稀土矿收液底板的侵蚀影响,以离子型稀土矿基岩（半/弱风化花岗岩）为研究对象,开展了室内浸矿模拟试验。对比分析了不同浸矿时间岩样的应力−应变曲线、峰值应力、峰值应变和弹性模量,获取了不同浸矿历时岩样的孔隙度和细观形貌特征,并运用盒维法对岩样的非线性裂纹特征进行了定量化描述。结果表明：浸矿侵蚀作用对离子型稀土矿底板基岩力学性质的影响主要表现在前150 d,破坏形式由贯穿破坏转变为贯穿破坏与片状剥落并存;浸矿母液侵蚀作用下,基岩力学特性呈现先大幅减小后大幅回升,其后在小范围波动现象,浸矿约60 d对基岩力学特性的影响程度最大;浸矿母液侵蚀造成基岩内小孔隙增长,导致表面出现腐蚀及孔洞现象;浸矿时间不同将造成岩石不同的微观结构变化。     

离子吸附型稀土矿床形成的矿物表/界面反应机制

华南离子吸附型稀土矿床提供了全球超过90%的重稀土,是我国优势的战略性关键金属矿产资源。掌握这类矿床的成矿机制和禀赋特征,可为增加稀土资源储量和高效利用稀土资源提供理论支撑。离子吸附型稀土矿床主要发育在富稀土花岗岩、浅变质岩及火山岩的风化壳中。基岩中的(含)稀土矿物是风化壳中离子态稀土的主要来源,其矿物组合很大程度上决定了稀土矿床的禀赋和分异特征。在物理-化学风化和微生物作用下,造岩矿物、含稀土矿物和稀土独立矿物逐渐溶解,使稀土元素活化和再富集。一方面,母岩风化形成的黏土矿物和铁锰氧化物具有较大的比表面积和一定的表面电荷密度,是稀土离子的主要载体;另一方面,稀土离子通过离子交换、表面吸附与络合、共沉淀,以及形成次生稀土矿物等途径富集在次生矿物表面,其富集-分异特征和赋存状态受矿物类型、pH、微生物活动等因素所控制。利用高分辨透射电镜结合选区电子衍射和电子能量损失谱,以及同步辐射X射线吸收精细结构谱,有望在原子级尺度查明稀土的微观赋存状态。未来研究需更多关注基岩中(含)稀土矿物组合及其演化路径的制约因素、微生物风化对离子吸附型稀土矿床成矿作用的约束,以及稀土元素的微观赋存状态等问题。     

福建余朋—南口火把山萤石矿地质特征及成因

笔者总结了福建余朋—南口地区火把山萤石矿床的地质特征, 并通过萤石的微量元素及稀土元素地球化学特征, 探讨了矿床的成因及成矿物质、流体来源。萤石矿石的微量元素及稀土元素结果显示: 火把山萤石呈中等Eu负异常及弱Ce异常, 稀土元素配分模式具有轻稀土富集型及轻稀土弱亏损的平缓型等两种曲线型式。根据萤石矿石特征、微量元素、稀土元素等特征及Y/Ho-La/Ho图解, 可知萤石存在至少三期成矿地质作用。依据M?ller的Tb/La-Tb/Ca成因判别图解, 结合常口萤石矿床的萤石及围岩的稀土元素特征, 认为火把山萤石成矿流体一方面与常口大型萤石矿床受同一成矿流体场控制, 并在有利的部位富集成矿; 另一方面, 成矿热液流体流经下峰岩组发生了淋滤、萃取、交换作用, 形成了不同地球化学特征的另一成矿期次的萤石。综合分析认为, 火把山萤石矿床为受断裂控制的大气降水成因的中低温热液充填矿床。