塔北、塔中地区碳酸盐岩及其原油中的二苯并噻吩类化合物

塔里木盆地塔北、塔中地区四口井(库南1井,轮南46井,塔中12井和塔参1井)寒武-奥陶系12个碳酸盐岩烃源岩(泥灰岩,泥质灰岩和云岩)岩芯样品抽提物芳烃组分中的二苯并噻吩类化合物组成和丰度变化特征可分为三种类型:Ⅰ二苯并噻吩、甲基二苯并噻吩型;Ⅱ二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩+三甲基芴混合物型;Ⅲ二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩和三甲基二苯并噻吩型。研究的塔北、塔中隆起11个海相油二苯并噻吩类化合物分布类型均为二苯并噻吩、甲基二苯并噻吩、二甲基二苯并噻吩和三甲基二苯并噻吩型,和海相烃源岩二苯并噻吩类化合物第Ⅲ种分布类型完全相同。据此推断:塔北隆起8个海相油可能主要来源于塔北轮南地区下奥陶统;塔中隆起3个海相油可能来源于塔中地区中-上奥陶统。     

含铀物质对泥岩有机质热模拟生烃产物的影响

有机—无机相互作用是沉积盆地中普遍存在且不可改变的事实。采用加水热模拟实验方法,考察了含铀物质对泥岩样品热解生烃产物的影响。结果发现,含铀物质的加入,极大的提高了泥岩热解产物中气体产物的生成量。对气体组分的分析表明,产物中二氧化碳的含量增加,而甲烷的含量较少,一氧化碳的含量则呈现先增加后减少的趋势,对液态抽提物的分析发现,含铀物质促进了热解过程中产生的高碳数正构烷烃的降解,使得抽提物中饱和烃族组分的轻重比值有所增加,同时,含铀物质对泥岩热解产生的甾、萜烷类生物标志化合物也产生了一定的影响。     

Pesticide-related Food Safety Risks: Farmers’ Self-protective Behavior and Food Safety Social Co-governance

This article investigates the sources of vegetables consumed by farmers, their perception of pesticide-related food safety risks and the behaviors they engage in to protect themselves, and explores the implications for the social co-governance (shehui gongzhi) of food safety emphasized by China’s recent Food Safety Law. The research site is a county in Yunnan Province where vegetable growing is the major source of income and livelihood for local farmers. We surveyed 417 farmers and collected 776 vegetable samples from 377 surveyed farmer households and tested them for organophosphate and carbamate pesticide residues using PR-12N Rapid Detection Instrument for Pesticide Residues. The results showed that farmers know about the risks to food safety caused by pesticides used in vegetable growing and they purposely avoid these risks by mainly consuming vegetables planted in home gardens or private plots that use little or no pesticides. Vegetable samples from these private plots had the lowest positive rate of pesticide residues (6.10%), compared with vegetable samples from commercial farmland (13.73%) and markets (12.66%), and the difference was statistically significant (X²=9.69,0.005相似文献   

高效节能日光温室蔬菜生产气候区划

通过选取影响平凉地区日光温室发展的６ 个因子,运用模糊数学方法对全区的日光温室蔬菜生产进行了气候适应性区划,将全区划分为日光温室最适宜、适宜及次适宜种植区等三种种植区,为各地因地制宜发展日光温室蔬菜生产找到合理的气候依据。     

复杂条件下非开挖铺管的关键技术

地层和地下管网条件复杂是影响非开挖导向钻进质量的重要因素。本文结合工程实践,分析了精确的控向钻进技术、LG植物胶的选择和配制、管材选择、铺管阻力的计算和拉管头设计等影响复杂条件下,非开挖铺管的关键技术。实际应用中取得了好的效果。      

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.     

秦岭造山带多金属矿普查复杂地层护壁堵漏技术

秦岭造山带多金属矿普查项目钻探施工过程中钻遇多种复杂地层,垮塌、缩径、漏失等复杂情况频发,严重影响了施工效率。分别采用了植物胶钙处理钻井液、聚乙烯醇无固相钻井液等进行护壁工作,结合不同漏失情况分别实施了随钻堵漏、凝胶堵漏等技术措施,取得了良好的使用效果。     

农业产业集群创新效率及影响因素——基于山东省寿光蔬菜产业集群的实证分析

创新是当前农业产业集群研究的重要内容,掌握集群创新状况对指导农业产业集群发展具有重要意义。结合实地调研的数据,利用DEA-Tobit两阶段模型,对山东省寿光蔬菜产业集群企业创新效率及其影响因素进行研究。结果表明:寿光蔬菜产业集群规模已接近最优状态,综合创新效率处于中等偏上水平,但仍未达到最优状态,主要原因是集群在科研技术投入、创新资源利用配置等方面不足造成的。进一步Tobit回归的影响因素分析发现:企业知识技术吸收扩散能力、政府财政支持力度、企业家创新精神和企业发展的外向性与农业产业集群企业创新效率存在显著的正相关关系,而企业规模对农业产业集群企业创新效率影响并不显著。最后,根据集群创新影响因素分析,提出发展建议。     

食品安全导向下的都市农业发展模式——以北京蔬菜生产为例

随着人们生活水平和认知能力的不断提高,人们对健康的关注和需求也变得更加强烈,因此伴随着近年来食品问题的频繁曝光,食品安全已成为社会各界最关心的议题,其中,蔬菜和牛奶等易腐食品更成为首要关注点。都市农业拥有“近距离短环节”的优势,应当成为城市蔬菜供应的重要渠道和保证城市居民蔬菜安全的主角。本文以北京为研究案例,针对食品安全导向下的城市蔬菜发展模式进行了研究。首先通过解析北京生鲜蔬菜的供应来源,总结了“长距离多环节”农业存在的蔬菜安全问题及都市农业在保证生鲜蔬菜品质安全方面的诸多优势。接着分析归纳了保证蔬菜品质安全下的几种都市农业发展模式,并以典型案例研究的方式分析了各模式的产生背景、运行管理特点。最后提出了促进都市农业发展的保障机制。     

广州地区蔬菜生产基地有机污染物含量状况及分布

为了解广州地区蔬菜基地有机污染物的分布情况,选取了6个代表性基地进行调查采样,测试分析了表层土壤、蔬菜及灌溉水中15种邻苯二甲酸酯(PAEs)化合物、16种多环芳烃(PAHs)化合物和19种有机氯农药(OCPs)化合物的质量分数及质量浓度.结果表明:在15种PAEs化合物的总质量分数(w(ΣPAEs))中,土壤样品为158.0~4 321.0 ng/g,蔬菜样品为1 134.0~48 576.0 ng/g;水样中15种PAEs化合物的总质量浓度(ρ(ΣPAEs))为632.0~14 271.0 ng/L;就单个化合物而言,以DiBP、DBP、DEHP三种污染物为主,其三项之和占所有PAEs质量分数的97.5%~99.1%;在16种PAHs化合物的总质量分数(w(ΣPAHs))中,土壤样品为28.48~1 121.96 ng/g,蔬菜样品为238.09~1 000.61 ng/g;水样中16种PAHs化合物的总质量浓度(ρ(ΣPAHs))为338.21~1 239.78 ng/L;在19种OCPs化合物的总质量分数(w(ΣOCPs))中,土壤为0.04~71.28 ng/g,蔬菜为1.08~9.18 ng/g.总体上看,各基地土壤中DBP质量分数均超标,多环芳烃类在灵山、花东、黄埔菜地土壤中存在轻微污染,有机氯农药均未出现污染.