Determination of Precise and Accurate 51V/50V Isotope Ratios by Multi‐Collector ICP‐MS,Part 2: Isotopic Composition of Six Reference Materials plus the Allende Chondrite and Verification Tests

We present the first measurements of vanadium (V) stable isotopes for six reference materials – USGS PCC‐1, BHVO‐2, BCR‐2, BIR‐1a, GSP‐2 and AGV‐2 – plus the widely available carbonaceous chondrite Allende. We present standard addition and matrix spiking tests to assess the robustness and reproducibility of our data. Standard addition utilised an enriched ⁵⁰V solution designated VISSOX (Vanadium Isotope Standard Solution OXford). We further assessed the veracity of the method by spiking collected sample matrices with the same amount of a V standard solution, whose isotopic composition was defined as 0‰. Standard addition and matrix spiking tests recorded no appreciable artificial isotope fractionation. We estimate that the best currently attainable long‐term reproducibility of stable ⁵¹V/⁵⁰V isotope measurements in complex matrices is 0.15‰, which is in the same order as the reproducibility achievable with standard solutions. Finally, a large range of ～ 1.2‰ in stable V isotopic composition was documented, with ～ 0.5‰ of that variation in high temperature igneous materials alone. The range and resolving power of V stable isotopes, with respect to igneous material, compared favourably with the magnitude of fractionation reported for other non‐traditional stable isotope systems, which bodes well for the utility of this new system.     

微波消解-分光光度法测定钒钛磁铁矿中的钒

采用硫-磷混合酸微波消解对难溶的钒钛磁铁矿进行前处理,用5-溴-PADAP-过氧化氢分光光度法测定矿样中的钒,优化了微波消解的实验条件.加入浓磷酸和40 g/L氟化钠溶液分别消除了共存常量元素铁和钛的干扰.方法检出限为0.004 μg/mL,线性范围为0.01～1.0 μg/mL . 应用于实际钒钛磁铁矿样品中钒的测定,重现性好,检出限较低,灵敏度较高,能够满足简单、快速、批量分析的要求.     

X射线荧光光谱法测定富含硫砷钒铁矿石中的主次量元素

以钴(钴玻璃粉形式)作内标元素,准确测定全铁含量;加入保护剂硝酸铵和稳定剂碳酸锂,使硫转化为硫酸盐,有效地防止硫的挥发损失。通过条件实验,确立了样品熔融温度和钴玻璃粉的用量。选择经筛选的仪器测定条件,用X射线荧光光谱法同时测定铁矿石中TFe、SiO2、CaO、MgO、Al2O3、TiO2、P、S、Mn、V2O5、As、K2O、Na2O、Cu、Ni等15种主次量元素。采用干扰曲线法对几乎完全重叠的TiΚβ谱线与VΚα谱线进行谱线重叠校正,用理论α系数法校正基体效应。建立的方法可以准确测定全铁和质量分数高达5.29%的S。采用多种标准物质和人工配制标准物质制作工作曲线,可以测定质量分数为5.00%的V2O5及0.1%的As,测定值与标准值符合较好,除低含量钠外方法精密度(RSD)<3.5%,分析误差符合实验质量要求。本法可以快速、准确地测定含砷的钒钛铁矿及含硫高的铁矿石中的主次量元素,满足了日常生产对铁矿石中硫和钒的测定要求。     

微波诱导等离子体原子发射光谱法测定铍铬钼钒锆锗的研究

研究了用微波诱导等离子体原子发射光谱法(MIP-AES)测定Be、Cr、Mo、V、Zr和Ge。确定了最佳实验条件,其检出限分别为:0.038,0.030,0.015,0.030,0.024和0.11μg/ml。对实际样品进行了测定,结果令人满意。     

湖北白果园银钒矿床中银的成岩富集机制探讨

通过对白果园银钒矿床中不同形态和不同期次含银黄铁矿的研究，发现富银矿体在空间上与含银量高的黄铁矿密切相关，反映在时间上，趋向于成岩晚期富集，本文从热水沉积成矿的观点出发，结合流体包裹体的研究和含银黄铁矿的演化特点，探讨了银在不同成岩阶段所处的物理化学环境及其迁移富集条件，从而提出了银在热水沉积－成岩过程中的迁移富集机制。     

湖北兴山白果园黑色页岩型银钒矿床中银钒赋存状态研究

湖北兴山白果园黑色页岩型银钒矿床以其独特的赋矿岩性受到国内外地质学家的重视,其Ａｇ,Ｖ的赋存状态也受到人们的关注。在前人工作的基础上,采用中子活化分析,电子探针分析和质子激发Ｘ射线发射分析等方法对黑色页岩中Ａｇ,Ｖ的赋存状态进行了分析。结果表明,Ａｇ的无机态和有机态各占一定的份额,其中无机态７６．６３％,有机态２３．２７％;无机态中以独立矿物态和类质同象态为主,独立矿物态占总量的２８．８５％,类质     

基于3DMine软件的地质统计学在洋县毕机沟钒钛磁铁矿资源量计算中的应用

毕机构钒钛磁铁矿床是陕南目前正在开发利用的钒钛磁铁矿床,矿体产出于辉长岩中,属岩浆分异—后期热液改造型钒钛磁铁矿床,本文以3DMine软件为操作平台,运用地质统计学法,通过数据整理—建库—半变异函数分析—普通克里格插值—资源储量计算等步骤,对毕机构矿床进行了资源储量计算,论证了合适的圈矿工业指标。充分体现了地质统计学法在复杂矿区资源储量计算过程中较传统资源储量计算方法表现出的优势和便利。     

Evidence of Bio-Organic Mineralization

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Fourier transform infrared kinetic studies of the reaction of HONO with HNO3, NO3 and N2O5 at 295 K

The kinetics of the reaction of nitrous acid (HONO) with nitric acid (HNO₃), nitrate radicals (NO₃) and dinitrogen pentoxide (N₂O₅) have been studied using Fourier transform infrared spectroscopy. Experiments were performed at 700 torr total pressure using synthetic air or argon as diluents. From the observed decay of HONO in the presence of HNO₃ a rate constant of k<7×10^-19 cm³ molecule^-1 s^-1 was derived for the reaction of HONO with HNO₃. From the observed decay of HONO in the presence of mixtures of N₂O₅ and NO₂ we have also derived upper limits for the rate constants of the reactions of HONO with NO₃ and N₂O₅ of 2×10^-15 and 7×10^-19 cm³ molecule^-1 s^-1, respectively. These results are discussed with respect to previous studies and to the atmospheric chemistry of HONO.     

湖北省郧县青木沟钒矿区成矿规律浅析

文章介绍了湖北省郧县青木沟矿区区域地质特征、矿区地层、构造及矿床特征。通过对本区成矿地质特征、矿石的物质成分、化学成分、结构构造的分析研究,简要分析了钒矿的成矿规律,对钒矿的勘查与找矿方向具有一定的意义。