Vanadium in magnetite gabbros and its behaviour during lateritic weathering,Windimurra Complex,Western Australia

Shephards Discordant Zone is a 500–600 m thick interlayered sequence of deformed, altered and metamorphosed magnetite metagabbro and about 50 layers or lenses of magnetitite (> 80–90% magnetite). The sequence shows progressive magmatic fractionation upwards: Ti and Ti/Fe increase, and V, V/Ti and Cr decrease upwards in magnetite and in whole‐rock compositions. The main magnetite‐rich sequence (about 400 m thick) is deeply weathered, with 40 m of saprolite showing vertical zonation of weathering minerals due to progressive weathering. Magnetitites (average 1% V₂O₃) are resistant to weathering and show little chemical change, but magnetite gabbros (average 0.27% V₂O₃) are extensively weathered and show progressive loss of Ca, Na, Mg and S. Plagioclase, magnetite (1.37% V₂O₃), chlorite (up to 0.35% V₂O₃), actinolite, epidote and minor sulfides in unweathered rocks weather to kaolinite, hematite, goethite and minor vermiculite, ilmenite remaining largely unaffected. Vanadium is essentially immobile during weathering and is unaffected during weathering of magnetitites (1% V₂O₃), but is slightly depleted during weathering of magnetite gabbros (0.23% V₂O₃).     

北祁连块状硫化物矿床中矿石和主要矿石矿物地球化学特征

对北祁连山白银矿田和郭密寺矿田中主要矿床的矿石和矿石矿物组分特征研究表明，由于各矿田的成矿条件和地球化学背景存在差异，造成不同矿床的矿石和矿石矿物元素组合各具特色。但作为同一类型矿床，它们之间又有很多共性，特别是同一矿田内各矿床的地球化学特征具有相似性和过渡性，反映了成矿条件变化的趋势。     

广西五圩矿田多金属矿床的成矿特征及物质来源

五圩矿田各多金属矿床均为中—低温热液充填型脉状矿床。研究结果表明，成矿流体是一种低盐度富含ＣＯ＿２的中－低温热液，其物质来源并非单一。其中，热液主要来自动热变质水，有部分岩浆热液掺合；主要成矿元素（Ｐｂ，Ｚｎ，Ｓｂ，Ａｓ等）由赋矿地层提供；硫具混源特征。成矿时存在一个统一热力场，而且成矿作用以“脉动式”充填方式为主，因而，矿田内围绕矿化中心（热源），出现明显的矿床水平分带现象和多阶段矿化特点。     

小秦岭西段驾鹿金矿田矿物地球化学特征及找矿标志

本文在总结驾鹿金矿田有关石英脉主要金属矿物地质产状、物性特征的基础上，系统对比性研究了蚀变岩和石英脉两类金矿床中产状、粒级、晶形、破碎程度不同的各世代黄铁矿中微量元素的含量、组合、比值特征及演化和不同世代撤离铅矿、地表褐铁矿、软锰矿的含金性，建立了两类金矿的找矿矿物学标志。     

不同石墨炉技术对钒原子化信号的影响

研究了钒元素在不同石墨炉技术、不同类型石墨管中的原子吸收曲线，探讨了产生这些差异的根本原因。     

北祁连石居里地区Cu(Zn)-S矿床地质特征及综合成矿模式

文章主要论述了北祁连山西段石居里矿田内Ⅵ号沟、Ⅷ号沟、九个泉等矿床的基本地质特征，并与北祁连山东段老虎山地区银硐沟、猪嘴哑吧等矿床对比。结合其早古生代构造演化历史、古洋脊或弧间、弧后拉张环境确定矿床类型，将上述3个矿床归属为蛇绿岩Cu(Zn）－S型矿床（类塞浦路斯型）。建立综合成矿模式的基本要求：（1）矿床具有一定的时控性，有一定的含矿层位；（2）生长性断裂的积极参与；（3）海底火山喷发、喷气中心与次级盆地双向控制；（4）多元热流体成矿系统。     

Timing and Processes of Ore Formation in the Qingchengzi Polymetallic Orefield, Northeast China: Evidence from 40Ar/39Ar Geochronology

The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral ~(40)Ar/~(39)Ar dating and report reliable ~(40)Ar/~(39)Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.     

郭米寺-尕大坂多金属矿带地质特征及综合信息找矿模型研究

郭米寺-尕大坂多金属矿田是位于北祁连走廊南山南坡重要的成矿地段,目前发现多个铜铅锌多金属矿床.它们具有相同的地质背景和成矿环境,经过几十年的地质工作,在找矿信息上积累了大量的资料并具有典型意义.笔者试图建立描述式为主的地质-地球化学-地球物理找矿模型,并初步给出优选的物化探工作方法,即在综合研究前人资料的基础上,逐步由面到点、由浅入深,不同工作阶段采用不同种类、不同精度的物(高精度磁测、激电测量、电测深等)、化探(以地气测量为主)和地质工作手段.     

冈底斯东段泽当大型钨铜钼矿新发现及走滑型陆缘成矿新认识

冈底斯成矿带以斑岩型铜矿(伴生钼矿)为主体,通常作为"挤压型"陆缘岩浆弧—"碰撞裂谷带"斑岩成矿的典型代表而被广泛关注,但层矽卡岩型钨铜钼矿和斑岩型独立钼矿的勘查和研究却未能引起足够的重视,尤其是层矽卡岩型白钨矿的发现,填补了区带矿种的空白;在雅鲁藏布江缝合带边部发现的隐伏斑岩型钼矿,突破了"挤压型"陆缘成矿认识的传统误区。中国冶金地质总局新近发现的冈底斯东段则当钨铜钼矿,既是一处大型钨铜钼矿详查开发基地,又是一组统一于陆缘走滑断裂构造成矿体制作用的钨、铜、钼矿床组合,称为"泽当矿田"。在NWW向雅鲁藏布江缝合带陆缘走滑断裂作用下,早期(68～40.3Ma)拉分型转换构造——NEE向剥离断层,控制了层矽卡岩型钨铜钼矿的形成;在NEE向冲木达陆缘走滑断裂作用下,晚期(30.26～23.62Ma)推闭型转换构造——NWW向逆冲断层,控制了隐伏斑岩型钼矿的形成。层矽卡岩型矿床形成和改造于68～66Ma和57～40.3Ma,叠加富集于斑岩型矿床的形成阶段——30.26～23.62Ma。     

南秦岭千家坪钒矿床地质地球化学特征与钒的富集规律

千家坪钒矿床产于南秦岭下寒武统水沟口组(缀1sh)黑色岩系中,该黑色岩系由黑色含炭硅质岩、含炭硅质岩夹泥岩和泥岩等组成。钒矿体呈层状产出,矿石以黑色硅质岩夹泥岩型为主,含钒矿物主要为钒云母。黑色岩系岩石主要成分为SiO2、Al2O3、K2O等,富集TFe、Ba、Zn、P、Cu、Ni、Cr、Sr、Zr、Ag、Ti、Mn、V等多种元素。黑色岩系n(V)/n(Cr)=5.92～30.64、n(V)/n(V+Ni)=0.88～0.99、δU1,判断其为缺氧沉积环境。黑色硅质岩n(SiO2)/n(Al2O3)=238.81,U/Th1以及δ30Si=-0.1‰～0.5‰、δ18O=20.2‰～25.8‰,判断其为半深海滞留沉积盆地热水沉积成因。泥岩n(SiO2)/n(Al2O3)=5.69,n(Al)/n(Al+Fe+Mn)=0.63,n(Si)/n(Si+Al+Fe)=0.74～0.76判断其物源为陆源,但受到热水作用影响。钒矿化受下寒武世古隆起边缘断陷滞留盆地中形成的黑色岩系层位所控制。钒明显趋向在炭硅质岩所夹的泥岩或硅质岩附近的泥岩中富集,在炭硅质岩夹泥岩段向泥岩段过渡层位,常常含结核,钒元素含量达到峰值,其他Cu、Pb、Zn、As、W、Mo等元素富集规律与V元素基本一致。该矿床成矿物质主要来源于深部热水,泥岩的吸附作用对钒的富集具有重要作用。综合地质、地球化学特征,认为该矿床为热水喷流沉积成因。